Organic Chemistry: Principles And Mechanisms (second Edition)
Organic Chemistry: Principles And Mechanisms (second Edition)
2nd Edition
ISBN: 9780393630749
Author: KARTY, Joel
Publisher: W. W. Norton & Company
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Chapter 12, Problem 12.32P
Interpretation Introduction

Interpretation:

The mechanism for given reaction is to be drawn.

Concept introduction:

Heat or light causes a weak C-N2 bond to break. In Step 1, the C-N2 bond breaks when energy is absorbed from light and carbene is produced. Carbene species have a lone pair on electrophilic carbon. In Step 2, carbene reacts with CC to generate the three-membered ring.

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Why doesn't this carry on to form a ring by deprotonating the alpha carbon and the negatively-charged carbon attacking the C=O?
6. A solution (0.0004 M) of Fe(S2CNEt2)3 (see the structural drawing below) in chloroform has absorption bands at: 350 nm (absorbance A = 2.34); 514 nm(absorbance A = 0.0532); Calculate the molar absorptivity values for these bands. Comment on their possible nature (charge transfer transitions or d-d S N- transitions?). (4 points)
What is the mechanism for this?

Chapter 12 Solutions

Organic Chemistry: Principles And Mechanisms (second Edition)

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