ORGANIC CHEM +SG +SAPLING >IP<
6th Edition
ISBN: 9781319171179
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 12, Problem 12.30AP
Interpretation Introduction
Interpretation:
The bonds in the order of increasing stretching frequencies are to be arranged and explained.
Concept introduction:
The energy that is required to break a bond is known as
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break down both reactions shown and explain it correctly using the bromonium ion mechanism, instead of the (disproven) carbocation-based mechanism.
Indicate how from 1,2-diaminobenzene to obtain 1-metilbenzotriazol.
-C = C - C - + Br₂ + I" -> -C-C-c
-C = C -C- + Br² + I₂
-C=C
Br I
+ Brū + Iz -7- C - C-C-
I Br
Mechanism;
- C = c - c - + Br - Br > - C-c-c-
Br
-C-C-C- + 1 - - -Ċ-Ċ'-c' -
Br
Br I
Chapter 12 Solutions
ORGANIC CHEM +SG +SAPLING >IP<
Ch. 12 - Prob. 12.1PCh. 12 - Prob. 12.2PCh. 12 - Prob. 12.3PCh. 12 - Prob. 12.4PCh. 12 - Prob. 12.5PCh. 12 - Prob. 12.6PCh. 12 - Prob. 12.7PCh. 12 - Prob. 12.8PCh. 12 - Prob. 12.9PCh. 12 - Prob. 12.10P
Ch. 12 - Prob. 12.11PCh. 12 - Prob. 12.12PCh. 12 - Prob. 12.13PCh. 12 - Prob. 12.14PCh. 12 - Prob. 12.15PCh. 12 - Prob. 12.16PCh. 12 - Prob. 12.17PCh. 12 - Prob. 12.18PCh. 12 - Prob. 12.19PCh. 12 - Prob. 12.20PCh. 12 - Prob. 12.21PCh. 12 - Prob. 12.22PCh. 12 - Prob. 12.23APCh. 12 - Prob. 12.24APCh. 12 - Prob. 12.25APCh. 12 - Prob. 12.26APCh. 12 - Prob. 12.27APCh. 12 - Prob. 12.28APCh. 12 - Prob. 12.29APCh. 12 - Prob. 12.30APCh. 12 - Prob. 12.31APCh. 12 - Prob. 12.32APCh. 12 - Prob. 12.33APCh. 12 - Prob. 12.34APCh. 12 - Prob. 12.35APCh. 12 - Prob. 12.36APCh. 12 - Prob. 12.37APCh. 12 - Prob. 12.38APCh. 12 - Prob. 12.39APCh. 12 - Prob. 12.40APCh. 12 - Prob. 12.41APCh. 12 - Prob. 12.42APCh. 12 - Prob. 12.43APCh. 12 - Prob. 12.44AP
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