
Concept explainers
(a)
Interpretation:
The derivations of given αM and αM2 expressions should be explained.
Concept Information:
Fraction of free metal ion:
In the metal ligand equilibria the number of moles of metal and ligand are equilibrium with number of mole of complex formed.
M+ L⇌ ML β1=[ML][M][L]M+ 2L⇌ ML2 β2=[ML2][M][L]2M+ nL⇌ MLn βn=[MLn][M][L]n
Where,
βn is cumulative formation constant
Fraction of free metal ion αM is,
αM= [M][Mtot]
αM= [M][M]{1+β1[L]+β2[L]2} =11+β1[L]+β2[L]2
Where,
M is free metal ion
(b)
Interpretation:
The values of αM and αM2 should be calculated.
Concept Information:
Fraction of free metal ion:
In the metal ligand equilibria the number of moles of metal and ligand are equilibrium with number of mole of complex formed.
M+ L⇌ ML β1=[ML][M][L]M+ 2L⇌ ML2 β2=[ML2][M][L]2M+ nL⇌ MLn βn=[MLn][M][L]n
Where,
βn is cumulative formation constant
Fraction of free metal ion αM is,
αM= [M][Mtot]
αM= [M][M]{1+β1[L]+β2[L]2} =11+β1[L]+β2[L]2
Where,
M is free metal ion

Want to see the full answer?
Check out a sample textbook solution
Chapter 12 Solutions
Quantitative Chemical Analysis 9e And Sapling Advanced Single Course For Analytical Chemistry (access Card)
- Please answer the questions and provide detailed explanation. Please also include the Hydrogens that are on the molecule to show how many signals there are.arrow_forwardCapp aktiv.com Part of Speech Table for Assi x Aktiv Learning App K Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Problem 232 of 10 10: Mg Select to Add Arrows Br O H :0 CI:O H Mg THE + dy Undo Reset Done Brarrow_forwardPlease answer the question and provide a detailed drawing of the structure. If there will not be a new C – C bond, then the box under the drawing area will be checked. Will the following reaction make a molecule with a new C – C bond as its major product: Draw the major organic product or products, if the reaction will work. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry.arrow_forward
- Please answer the question and provide a detailed drawing of the structure. If there will not be a new C – C bond, then the box under the drawing area will be checked. Will the following reaction make a molecule with a new C – C bond as its major product: Draw the major organic product or products, if the reaction will work. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry.arrow_forwardPlease do not use AI. AI cannot "see" the molecules properly, and it therefore gives the wrong answer while giving incorrect descriptions of the visual images we're looking at. All of these compounds would be produced (I think). In my book, I don't see any rules about yield in this case, like explaining that one product would be present in less yield for this reason or that reason. Please explain why some of these produce less yield than others.arrow_forwardPlease answer the question and provide detailed explanations.arrow_forward
- All of these compounds would be produced (I think). In my book, I don't see any rules about yield in this case, like explaining that one product would be present in less yield for this reason or that reason. Please explain why some of these produce less yield than others.arrow_forward5. Fill in the missing molecules in the following reaction pathway. TMSO Heat + CI then HF O₂N (1.0 equiv) AICI 3 OMearrow_forwarde. O₂N NO2 1. excess H2, Pd/C 2. excess NaNO2, HCI 3. excess CuCNarrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY





