The member of the given pair which is expected to have high boiling point has to be identified. Concept Introduction: The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens. Physical properties of halogenated alkanes : Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions. General trend considering the boiling point and melting point of halogenated hydrocarbon are, Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases. As the size of halogen atom increases, the melting point and boiling point also increases. Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Question

Want to see the full answer?

Answer 1

Question

Chapter 12, Problem 12.144EP

(a)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(b)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(c)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(d)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

If the molar conductivity at infinite dilution of HAC is A0 = 390.5 S cm² mol¹. Calculate the Arrhenius conductivity of a 9.3% by weight solution of HAc with a pH of 3.3. Data: molecular weight of HAC is 60.05 g/mol and the density of the solution is 1 g/cm³.

Determine the distance between the metal and the OHP layer using the Helm- holtz model when the electrode's differential capacitance is 145 μF cm². DATA: dielectric constant of the medium for the interfacial zone &r= lectric constant of the vacuum &0 = 8.85-10-12 F m-1 = 50, die-

Answer 2

Question

Chapter 12, Problem 12.144EP

(a)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(b)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(c)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(d)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 12, Problem 12.144EP

(a)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(b)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(c)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(d)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 12, Problem 12.144EP

(a)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(b)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(c)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(d)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 12, Problem 12.144EP

(a)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(b)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(c)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(d)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 6

Chapter 12, Problem 12.144EP

(a)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 7

Chapter 12, Problem 12.144EP

(a)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interactions.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 17

Ch. 12.1 - Prob. 1QQ Ch. 12.1 - Prob. 2QQ Ch. 12.2 - Prob. 1QQ Ch. 12.2 - Prob. 2QQ Ch. 12.3 - Prob. 1QQ Ch. 12.3 - Prob. 2QQ Ch. 12.4 - Prob. 1QQ Ch. 12.4 - Prob. 2QQ Ch. 12.4 - Prob. 3QQ Ch. 12.5 - Prob. 1QQ

Solution Summary: The author explains the physical properties of halogenated hydrocarbons. The melting and boiling points increase with the increase in alkyl groups.

Concept explainers

Videos

Want to see the full answer?

Chapter 12 Solutions