Introductory Chemistry (6th Edition)
6th Edition
ISBN: 9780134302386
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 12, Problem 105E
Interpretation Introduction
Interpretation: Amolecule in the interior as well as near the edge is to be picked and a line is to be drawn to each of its direct neighbors. The molecule with most neighbors is to be identified. The molecule which is susceptible to evaporation is to be determined.
Concept Introduction: Hydrogen bonding is present between the water molecules.
The molecule present at the surface has less number of neighboring atoms in comparison to the molecule in the interior.
The molecule present at the surface tends to evaporate easily.
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You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products:
xi
1. ☑
2. H₂O
хе
i
Draw the missing reagent X you think will make this synthesis work in the drawing area below.
If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank.
Click and drag to start drawing a
structure.
There is no reagent that will make this synthesis work without complications.
: ☐
S
☐
Predict the major products of this organic reaction:
H
OH
1. LiAlH4
2. H₂O
?
Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry.
Click and drag to start drawing a
structure.
G
C
टे
For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first
stable product you expect to form in solution.
NH2
CI
MgCl
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
G
टे
Chapter 12 Solutions
Introductory Chemistry (6th Edition)
Ch. 12 - The first diagram shown here represents liquid...Ch. 12 - Prob. 2SAQCh. 12 - Prob. 3SAQCh. 12 - How many 20.0-g ice cubes are required to absorb...Ch. 12 - Prob. 5SAQCh. 12 - Prob. 6SAQCh. 12 - Prob. 7SAQCh. 12 - Prob. 8SAQCh. 12 - Prob. 9SAQCh. 12 - Prob. 10SAQ
Ch. 12 - Prob. 1ECh. 12 - Prob. 2ECh. 12 - What determines whether a substance is a solid,...Ch. 12 - 4. What are the properties of liquids? Explain the...Ch. 12 - 5. What are the properties of solids? Explain the...Ch. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Why does a glass of water evaporate more slowly in...Ch. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - 13. Acetone evaporates more quickly than water at...Ch. 12 - Prob. 14ECh. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - 17. Explain why a steam burn from gaseous water at...Ch. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Is the melting of ice endothermic or exothermic?...Ch. 12 - 22. Is the boiling of water endothermic or...Ch. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - 25. What is hydrogen bonding? How can you tell...Ch. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - Prob. 30ECh. 12 - Prob. 31ECh. 12 - 32. What is an atomic solid? What are the...Ch. 12 - Prob. 33ECh. 12 - Prob. 34ECh. 12 - Prob. 35ECh. 12 - Two samples of pure water of equal volume are put...Ch. 12 - Prob. 37ECh. 12 - Spilling water over your skin on a hot day will...Ch. 12 - Prob. 39ECh. 12 - Water is put into a beaker and heated with a...Ch. 12 - 41. Which causes a more severe burn: spilling 0.50...Ch. 12 - 42. The nightly winter temperature drop in a...Ch. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - 45. An ice chest is filled with 3.5 kg of ice at...Ch. 12 - Why does 50 g of water initially at 0 C warm more...Ch. 12 - In Denver, Colorado, water boils at 95. C....Ch. 12 - Prob. 48ECh. 12 - 49. How much heat is required to vaporize 33.8 g...Ch. 12 - How much heat is required to vaporize 43.9 g of...Ch. 12 - How much heat does your body lose when 2.8 g of...Ch. 12 - How much heat does your body lose when 4.86 g of...Ch. 12 - How much heat is emitted when 4.25 g of water...Ch. 12 - Prob. 54ECh. 12 - 55. The human body obtains 835 kJ of energy from a...Ch. 12 - 56. The human body obtains 1078 kJ from a candy...Ch. 12 - How much heat is required to melt 37.4 g of ice at...Ch. 12 - 58. How much heat is required to melt 23.9 g of...Ch. 12 - How much energy is released when 34.2 g of water...Ch. 12 - How much energy is released when 2.55 kg of...Ch. 12 - 61. How much heat is required to convert 2.55 g of...Ch. 12 - 62. How much heat is required to convert 5.88 g of...Ch. 12 - Prob. 63ECh. 12 - Prob. 64ECh. 12 - 65. What kinds of intermolecular forces are...Ch. 12 - Prob. 66ECh. 12 - Prob. 67ECh. 12 - What kinds of intermolecular forces are present in...Ch. 12 - Which substance has the highest boiling point?...Ch. 12 - Prob. 70ECh. 12 - One of these two substances is a liquid at room...Ch. 12 - Prob. 72ECh. 12 - 73. A flask containing a mixture of and is...Ch. 12 - 74. Explain why is a liquid at room temperature...Ch. 12 - Are CH3CH2CH2CH2CH3 and H2O miscible?Ch. 12 - Prob. 76ECh. 12 - Prob. 77ECh. 12 - 78. Determine whether a homogeneous solution forms...Ch. 12 - 79. Identify each solid as molecular, ionic, or...Ch. 12 - Prob. 80ECh. 12 - Identify each solid as molecular, ionic, or...Ch. 12 - Identify each solid as molecular, ionic, or...Ch. 12 - 83. Which solid has the highest melting point?...Ch. 12 - 84. Which solid has the highest melting point?...Ch. 12 - 85. For each pair of solids, determine which solid...Ch. 12 - For each pair of solids, determine which solid has...Ch. 12 - 87. List these substances in order of increasing...Ch. 12 - 88. List these substances in order of decreasing...Ch. 12 - 89. Ice actually has negative caloric content. How...Ch. 12 - Prob. 90ECh. 12 - An 8.5-g ice cube is placed into 255 g of water....Ch. 12 - A 14.7-g ice cube is placed into 324 g of water....Ch. 12 - 93. How much ice in grams would have to melt to...Ch. 12 - Prob. 94ECh. 12 - Prob. 95ECh. 12 - Prob. 96ECh. 12 - Draw a Lewis structure for each molecule and...Ch. 12 - Draw a Lewis structure for each molecule and...Ch. 12 - 99. The melting point of ionic solids depends on...Ch. 12 - Draw ionic Lewis structures for KF and CaO. Use...Ch. 12 - Prob. 101ECh. 12 - Prob. 102ECh. 12 - An ice cube at 0.00 C with a mass of 23.5 g is...Ch. 12 - Prob. 104ECh. 12 - Prob. 105ECh. 12 - Prob. 106ECh. 12 - Prob. 107ECh. 12 - Prob. 108ECh. 12 - Prob. 109QGWCh. 12 - Prob. 110QGWCh. 12 - Prob. 111QGWCh. 12 - Prob. 112QGWCh. 12 - Prob. 113DIA
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- For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. དྲ。 ✗MgBr ? O CI Will the first product that forms in this reaction create a new C-C bond? Yes No • ? Will the first product that forms in this reaction create a new CC bond? Yes No × : ☐ Xarrow_forwardPredict the major products of this organic reaction: OH NaBH4 H ? CH3OH Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. ☐ : Sarrow_forwardPredict the major products of this organic reaction: 1. LIAIHA 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. X : ☐arrow_forward
- For each reaction below, decide if the first stable organic product that forms in solution will create a new C - C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 tu ? ? OH Will the first product that forms in this reaction create a new CC bond? Yes No Will the first product that forms in this reaction create a new CC bond? Yes No C $ ©arrow_forwardAs the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C-C bond as its major product: 1. MgCl ? 2. H₂O* If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new CC bond. G marrow_forwardIncluding activity coefficients, find [Hg22+] in saturated Hg2Br2 in 0.00100 M NH4 Ksp Hg2Br2 = 5.6×10-23.arrow_forward
- give example for the following(by equation) a. Converting a water insoluble compound to a soluble one. b. Diazotization reaction form diazonium salt c. coupling reaction of a diazonium salt d. indacator properties of MO e. Diazotization ( diazonium salt of bromobenzene)arrow_forward2-Propanone and ethyllithium are mixed and subsequently acid hydrolyzed. Draw and name the structures of the products.arrow_forward(Methanesulfinyl)methane is reacted with NaH, and then with acetophenone. Draw and name the structures of the products.arrow_forward
- 3-Oxo-butanenitrile and (E)-2-butenal are mixed with sodium ethoxide in ethanol. Draw and name the structures of the products.arrow_forwardWhat is the reason of the following(use equations if possible) a.) In MO preperation through diazotization: Addition of sodium nitrite in acidfied solution in order to form diazonium salt b.) in MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at low pH c.) In MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at pH 4.5 d.) Avoiding not cooling down the reaction mixture when preparing the diazonium salt e.) Cbvcarrow_forwardA 0.552-g sample of an unknown acid was dissolved in water to a total volume of 20.0 mL. This sample was titrated with 0.1103 M KOH. The equivalence point occurred at 29.42 mL base added. The pH of the solution at 10.0 mL base added was 3.72. Determine the molar mass of the acid. Determine the Ka of the acid.arrow_forward
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