Introductory Chemistry (5th Edition) (Standalone Book)
5th Edition
ISBN: 9780321910295
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 12, Problem 101E
Interpretation Introduction
Interpretation:
The trend of melting point for the given
Concept Introduction:
The magnitude of dispersion forces depends upon how easily electron in the atom or molecule polarized in response to a dipole. Due to a larger size of the electron cloud, greater dispersion force is observed as electron are less tightly held by the nucleus. If other factors is same dispersion forces increases with molar mass.
The polar molecule containing a hydrogen atom that is directly bonded to high electronegative atom fluorine, nitrogen or oxygen exhibit additional interaction called hydrogen bonding.
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Students have asked these similar questions
Compounds 1 and 2 have the same molecular weight. Identify and discuss all intermolecular forces for each molecule and clearly explain in terms of intermolecular forces why one of the compounds has a higher boiling point than the other. In your writing be sure to indicate which boiling point (3 °C and 25 °C) belongs to which compound. Please be sure to write in clear, well-written sentences that clearly illustrate your understanding and correctly uses appropriate terminology.
Q10
Consider the data in the table.
Compound Melting point (°C) AHfus (kJ/mol) Boiling point (°C)
AHvap (kJ/mol)
HF
-83.11
4.577
19.54
25.18
HC1
-114.3
1.991
-84.9
17.53
HBr
-86.96
2.406
-67.0
19.27
HI
-50.91
2.871
-35.38
21.16
Using the data in the table, calculate ASfus and ASvap for HF.
ASfus =
J/(K · mol)
ASvap
J/(K · mol)
Determine the entropy change when 7.60 mol HF(g) condenses at atmospheric pressure.
AS =
J/K
Chapter 12 Solutions
Introductory Chemistry (5th Edition) (Standalone Book)
Ch. 12 - The first diagram shown here represents liquid...Ch. 12 - Prob. 2SAQCh. 12 - Prob. 3SAQCh. 12 - How many 20.0-g ice cubes are required to absorb...Ch. 12 - Prob. 5SAQCh. 12 - Prob. 6SAQCh. 12 - Prob. 7SAQCh. 12 - Prob. 8SAQCh. 12 - Prob. 9SAQCh. 12 - Prob. 10SAQ
Ch. 12 - Prob. 1ECh. 12 - Prob. 2ECh. 12 - Prob. 3ECh. 12 - 4. What are the properties of liquids? Explain the...Ch. 12 - 5. What are the properties of solids? Explain the...Ch. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Why does a glass of water evaporate more slowly in...Ch. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - 13. Acetone evaporates more quickly than water at...Ch. 12 - Prob. 14ECh. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - 17. Explain why a steam burn from gaseous water at...Ch. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Is the melting of ice endothermic or exothermic?...Ch. 12 - 22. Is the boiling of water endothermic or...Ch. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - 25. What is hydrogen bonding? How can you tell...Ch. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - Prob. 30ECh. 12 - Prob. 31ECh. 12 - 32. What is an atomic solid? What are the...Ch. 12 - Prob. 33ECh. 12 - Prob. 34ECh. 12 - Prob. 35ECh. 12 - Two samples of pure water of equal volume are put...Ch. 12 - Prob. 37ECh. 12 - Spilling water over your skin on a hot day will...Ch. 12 - Prob. 39ECh. 12 - Water is put into a beaker and heated with a...Ch. 12 - 41. Which causes a more severe burn: spilling 0.50...Ch. 12 - 42. The nightly winter temperature drop in a...Ch. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Why does 50 g of water initially at 0 C warm more...Ch. 12 - In Denver, Colorado, water boils at 95. C....Ch. 12 - Prob. 48ECh. 12 - 49. How much heat is required to vaporize 33.8 g...Ch. 12 - Prob. 50ECh. 12 - How much heat does your body lose when 2.8 g of...Ch. 12 - How much heat does your body lose when 4.86 g of...Ch. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - 55. The human body obtains 835 kJ of energy from a...Ch. 12 - 56. The human body obtains 1078 kJ from a candy...Ch. 12 - How much heat is required to melt 37.4 g of ice at...Ch. 12 - 58. How much heat is required to melt 23.9 g of...Ch. 12 - How much energy is released when 34.2 g of water...Ch. 12 - How much energy is released when 2.55 kg of...Ch. 12 - 61. How much heat is required to convert 2.55 g of...Ch. 12 - 62. How much heat is required to convert 5.88 g of...Ch. 12 - INTERMOLECULAR FORCES
63. What kinds of...Ch. 12 - Prob. 64ECh. 12 - 65. What kinds of intermolecular forces are...Ch. 12 - Prob. 66ECh. 12 - Prob. 67ECh. 12 - What kinds of intermolecular forces are present in...Ch. 12 - Prob. 69ECh. 12 - Prob. 70ECh. 12 - One of these two substances is a liquid at room...Ch. 12 - Prob. 72ECh. 12 - 73. A flask containing a mixture of and is...Ch. 12 - 74. Explain why is a liquid at room temperature...Ch. 12 - Are CH3CH2CH2CH2CH3 and H2O miscible?Ch. 12 - Prob. 76ECh. 12 - Prob. 77ECh. 12 - 78. Determine whether a homogeneous solution forms...Ch. 12 - 79. Identify each solid as molecular, ionic, or...Ch. 12 - Prob. 80ECh. 12 - Identify each solid as molecular, ionic, or...Ch. 12 - Identify each solid as molecular, ionic, or...Ch. 12 - 83. Which solid has the highest melting point?...Ch. 12 - Prob. 84ECh. 12 - 85. For each pair of solids, determine which solid...Ch. 12 - For each pair of solids, determine which solid has...Ch. 12 - 87. List these substances in order of increasing...Ch. 12 - Prob. 88ECh. 12 - 89. Ice actually has negative caloric content. How...Ch. 12 - Prob. 90ECh. 12 - An 8.5-g ice cube is placed into 255 g of water....Ch. 12 - Prob. 95ECh. 12 - Prob. 96ECh. 12 - Draw a Lewis structure for each molecule and...Ch. 12 - Draw a Lewis structure for each molecule and...Ch. 12 - 99. The melting point of ionic solids depends on...Ch. 12 - Draw ionic Lewis structures for KF and CaO. Use...Ch. 12 - Prob. 101ECh. 12 - Prob. 102ECh. 12 - An ice cube at 0.00 C with a mass of 23.5 g is...Ch. 12 - Prob. 105ECh. 12 - Prob. 106ECh. 12 - Prob. 107ECh. 12 - Prob. 108ECh. 12 - Prob. 109ECh. 12 - Prob. 110ECh. 12 - Prob. 111ECh. 12 - Prob. 112E
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- Methane, CH4, reacts with chlorine, Cl2, to produce a series of chlorinated hydrocarbons: methyl chloride (CH3Cl), methylene chloride (CH2Cl3), chloroform (CHCl3), and carbon tetrachloride (CCl4). Which compound has the highest vapor pressure at room temperature? Explain.arrow_forwardA 0.439 mol sample of liquid propanol (60.09 g/mol) is heated from 25.6°C to 328.3PC. The boiling point of propanol is 206.6°C. The specific heat of liquid propanol is 2.40 J/g°C. The specific heat of propanol vapor is 1.42 J/g°C. The enthalpy of vaporization for propanol is 47.5 kJ/mol. What is the energy change of this process, in kJ?arrow_forwardConsider the data in the table. Compound Melting point (°C) AHfus (kJ/mol) Boiling point (°C) AHvap (kJ/mol) HF -83.11 4.577 19.54 25.18 HCI -114.3 1.991 -84.9 17.53 HBr -86.96 2.406 -67.0 19.27 HI -50.91 2.871 35.38 21.16 Using the data in the table, calculate ASfus and A.Svap for HBr. ASfus= 13 ASvap 93 Determine the entropy change when 6.90 mol HBr(1) freezes at atmospheric pressure. 355 AS= J/(K-mol) J/(K - mol) J/K Question Source: McQuarrie, Rock, And Gallogly 4e General Chemistry | Publisher Universitarrow_forward
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