(a) Interpretation: 2-methylbutane, pentane and 2,2-dimethylpropane should be arranged in increasing order of boiling point. Concept Introduction: The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point. Moreover, straight chain has large surface area which increases the possibility of area of contact with other chain which results in higher Vander Waal forces between them and thus increases the boiling point. Thus, on increasing branching, due to decrease in surface area, boiling point decreases.

Question

Indicate the products obtained by mixing 2-Propanone and ethyllithium and performing a subsequent acid hydrolysis.

Answer 1

Question

Chapter 11.9, Problem 11.8P

Interpretation Introduction

(a)

Interpretation:

2-methylbutane, pentane and 2,2-dimethylpropane should be arranged in increasing order of boiling point.

Concept Introduction:

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain has large surface area which increases the possibility of area of contact with other chain which results in higher Vander Waal forces between them and thus increases the boiling point.

Thus, on increasing branching, due to decrease in surface area, boiling point decreases.

Interpretation Introduction

(b)

Interpretation:

3,3-dimethylheptane, nonane, 2,2,4-trimethylhexane should be arranged according to increasing boiling point.

Concept Introduction:

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain has large surface area which increases the possibility of area of contact with other chain which results in higher Vander Waal forces between them and thus increases the boiling point. Thus, on increasing branching, due to decrease in surface area, boiling point decreases.

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Indicate the products obtained by mixing 2-Propanone and ethyllithium and performing a subsequent acid hydrolysis.

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Question 3 (4 points), Draw a full arrow-pushing mechanism for the following reaction Please draw all structures clearly. Note that this intramolecular cyclization is analogous to the mechanism for halohydrin formation. COH Br + HBr Br

Answer 2

Question

Chapter 11.9, Problem 11.8P

Interpretation Introduction

(a)

Interpretation:

2-methylbutane, pentane and 2,2-dimethylpropane should be arranged in increasing order of boiling point.

Concept Introduction:

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain has large surface area which increases the possibility of area of contact with other chain which results in higher Vander Waal forces between them and thus increases the boiling point.

Thus, on increasing branching, due to decrease in surface area, boiling point decreases.

Interpretation Introduction

(b)

Interpretation:

3,3-dimethylheptane, nonane, 2,2,4-trimethylhexane should be arranged according to increasing boiling point.

Concept Introduction:

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain has large surface area which increases the possibility of area of contact with other chain which results in higher Vander Waal forces between them and thus increases the boiling point. Thus, on increasing branching, due to decrease in surface area, boiling point decreases.

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Answer 3

Question

Chapter 11.9, Problem 11.8P

Interpretation Introduction

(a)

Interpretation:

2-methylbutane, pentane and 2,2-dimethylpropane should be arranged in increasing order of boiling point.

Concept Introduction:

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain has large surface area which increases the possibility of area of contact with other chain which results in higher Vander Waal forces between them and thus increases the boiling point.

Thus, on increasing branching, due to decrease in surface area, boiling point decreases.

Interpretation Introduction

(b)

Interpretation:

3,3-dimethylheptane, nonane, 2,2,4-trimethylhexane should be arranged according to increasing boiling point.

Concept Introduction:

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain has large surface area which increases the possibility of area of contact with other chain which results in higher Vander Waal forces between them and thus increases the boiling point. Thus, on increasing branching, due to decrease in surface area, boiling point decreases.

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Answer 4

Question

Chapter 11.9, Problem 11.8P

Interpretation Introduction

(a)

Interpretation:

2-methylbutane, pentane and 2,2-dimethylpropane should be arranged in increasing order of boiling point.

Concept Introduction:

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain has large surface area which increases the possibility of area of contact with other chain which results in higher Vander Waal forces between them and thus increases the boiling point.

Thus, on increasing branching, due to decrease in surface area, boiling point decreases.

Interpretation Introduction

(b)

Interpretation:

3,3-dimethylheptane, nonane, 2,2,4-trimethylhexane should be arranged according to increasing boiling point.

Concept Introduction:

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain has large surface area which increases the possibility of area of contact with other chain which results in higher Vander Waal forces between them and thus increases the boiling point. Thus, on increasing branching, due to decrease in surface area, boiling point decreases.

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Answer 5

Chapter 11.9, Problem 11.8P

Interpretation Introduction

(a)

Interpretation:

2-methylbutane, pentane and 2,2-dimethylpropane should be arranged in increasing order of boiling point.

Concept Introduction:

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain has large surface area which increases the possibility of area of contact with other chain which results in higher Vander Waal forces between them and thus increases the boiling point.

Thus, on increasing branching, due to decrease in surface area, boiling point decreases.

Interpretation Introduction

(b)

Interpretation:

3,3-dimethylheptane, nonane, 2,2,4-trimethylhexane should be arranged according to increasing boiling point.

Concept Introduction:

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain has large surface area which increases the possibility of area of contact with other chain which results in higher Vander Waal forces between them and thus increases the boiling point. Thus, on increasing branching, due to decrease in surface area, boiling point decreases.

Answer 6

Chapter 11.9, Problem 11.8P

Interpretation Introduction

(a)

Interpretation:

2-methylbutane, pentane and 2,2-dimethylpropane should be arranged in increasing order of boiling point.

Concept Introduction:

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain has large surface area which increases the possibility of area of contact with other chain which results in higher Vander Waal forces between them and thus increases the boiling point.

Thus, on increasing branching, due to decrease in surface area, boiling point decreases.

Answer 7

Chapter 11.9, Problem 11.8P

Interpretation Introduction

(a)

Interpretation:

2-methylbutane, pentane and 2,2-dimethylpropane should be arranged in increasing order of boiling point.

Concept Introduction:

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain has large surface area which increases the possibility of area of contact with other chain which results in higher Vander Waal forces between them and thus increases the boiling point.

Thus, on increasing branching, due to decrease in surface area, boiling point decreases.

Answer 8

Interpretation Introduction

(b)

Interpretation:

3,3-dimethylheptane, nonane, 2,2,4-trimethylhexane should be arranged according to increasing boiling point.

Concept Introduction:

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain has large surface area which increases the possibility of area of contact with other chain which results in higher Vander Waal forces between them and thus increases the boiling point. Thus, on increasing branching, due to decrease in surface area, boiling point decreases.

Answer 9

Interpretation Introduction

(b)

Interpretation:

3,3-dimethylheptane, nonane, 2,2,4-trimethylhexane should be arranged according to increasing boiling point.

Concept Introduction:

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain has large surface area which increases the possibility of area of contact with other chain which results in higher Vander Waal forces between them and thus increases the boiling point. Thus, on increasing branching, due to decrease in surface area, boiling point decreases.

Answer 10

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Ch. 11.2 - Prob. 11.1P Ch. 11.3 - Prob. 11.2P Ch. 11.3 - Prob. 11.3P Ch. 11.4 - Problem 11-4 Write the molecular formula and IUPAC...Ch. 11.6 - Problem 11-5 Write the molecular formula and IUPAC...Ch. 11.7 - Prob. 11.6P Ch. 11.8 - Prob. 11.7P Ch. 11.9 - Prob. 11.8P Ch. 11.10 - Prob. 11.9P Ch. 11 - Answer true or false. A hydrocarbon is composed...

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