Study Guide And Selected Solutions Manual For Chemistry Format: Paperback
13th Edition
ISBN: 9780134553986
Author: Timberlake, Karen C
Publisher: Prentice Hall
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Textbook Question
Chapter 11.8, Problem 11.40PP
Write the balanced chemical equation for the complete combustion of each of the following hydrocarbons found in gasoline:
a. decane
b. cyclohexane
C. toluene
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Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
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Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
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-0.12
-0.11
-0.10
-0.08
8
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Jane
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5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Chapter 11 Solutions
Study Guide And Selected Solutions Manual For Chemistry Format: Paperback
Ch. 11.1 - Identify each of the following as a formula of an...Ch. 11.1 - Identify each of the following as a formula of an...Ch. 11.1 - Identify each of the following properties as more...Ch. 11.1 - Identify each of the following properties as more...Ch. 11.1 - Prob. 11.5PPCh. 11.1 - Prob. 11.6PPCh. 11.2 - Give the IUPAC name for each of the following...Ch. 11.2 - Give the IUPAC name for each of the following...Ch. 11.2 - Draw the condensed structural formula for alkanes...Ch. 11.2 - Draw the condensed structural formula for alkanes...
Ch. 11.3 - Indicate whether each of the following pairs...Ch. 11.3 - Indicate whether each of the following pairs...Ch. 11.3 - Give the IUPAC name for each of the following a....Ch. 11.3 - Give the TUPAC name for each of the following: a....Ch. 11.3 - Draw the condensed structural formula for each of...Ch. 11.3 - Draw the condensed structural formula for each of...Ch. 11.3 - Draw the line-angle formula for each of the...Ch. 11.3 - Prob. 11.18PPCh. 11.4 - Heptane, used as a solvent for rubber cement, has...Ch. 11.4 - Nonane has a density of 0.79 g/mL and boils at 151...Ch. 11.4 - Write the balanced chemical equation for the...Ch. 11.4 - Write the balanced chemical equation for the...Ch. 11.5 - Identify the following as alkanes, alkenes,...Ch. 11.5 - Identify the following as alkanes, alkenes,...Ch. 11.5 - Give the IUPAC name for each of the following: a....Ch. 11.5 - Give the IUPAC name for each of the following: a....Ch. 11.5 - Draw the condensed structural formula, or...Ch. 11.5 - Prob. 11.28PPCh. 11.6 - Give the IUPAC name for each of the following,...Ch. 11.6 - Give the IUPAC name for each of the following,...Ch. 11.6 - Draw the condensed structural formula for each of...Ch. 11.6 - Prob. 11.32PPCh. 11.7 - Draw the structural formula for the product in...Ch. 11.7 - Draw the structural formula for the product in...Ch. 11.8 - Give the IUPAC name for each of the following: a....Ch. 11.8 - Give the IUPAC name for each of the following: a....Ch. 11.8 - Draw the line-angle formula for each of the...Ch. 11.8 - Draw the line-angle formula for each of the...Ch. 11.8 - Write the balanced chemical equation for the...Ch. 11.8 - Write the balanced chemical equation for the...Ch. 11 - Prob. 11.41UTCCh. 11 - Prob. 11.42UTCCh. 11 - Prob. 11.43UTCCh. 11 - Prob. 11.44UTCCh. 11 - Convert each of the following line-angle formulas...Ch. 11 - Convert each of the following line-angle formulas...Ch. 11 - Give the IUPAC name for each of the following:...Ch. 11 - Give the IUPAC name for each of the following:...Ch. 11 - Give the IUPAC name (including cis or trans, if...Ch. 11 - Give the LUPAC name (including cis or trans, if...Ch. 11 - Prob. 11.51APPCh. 11 - Prob. 11.52APPCh. 11 - Name each of the following aromatic compounds:...Ch. 11 - Prob. 11.54APPCh. 11 - Draw the condensed structural or line-angle...Ch. 11 - Draw the condensed structural or line-angle...Ch. 11 - Draw the cis and trans isomers for each of the...Ch. 11 - Draw the cis and trans isomers for each of the...Ch. 11 - Prob. 11.59APPCh. 11 - Draw the line-angle formula for each of the...Ch. 11 - Write a balanced chemical equation for the...Ch. 11 - Write a balanced chemical equation for the...Ch. 11 - Give the name for the product from the...Ch. 11 - Give the name for the product from the...Ch. 11 - Draw the condensed structural or line-angle...Ch. 11 - Draw the condensed structural or line-angle...Ch. 11 - Prob. 11.67CPCh. 11 - Prob. 11.68CPCh. 11 - Prob. 11.69CPCh. 11 - Prob. 11.70CPCh. 11 - Prob. 11.71CPCh. 11 - Prob. 11.72CPCh. 11 - Prob. 11.73CPCh. 11 - Margarines are produced from the hydrogenation of...
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- n Feb 3 A T + 4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how you confirmed the structure. 5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of Limonene. 6. (1 pts) Predict the 1H NMR spectral data of R-Limonene. Proton NMR: 5.3 pon multiplet (H Ringarrow_forwardPart VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forward
- Part VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward
- 13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward6 D 2. (1 pt) Limonene can be isolated by performing steam distillation of orange peel. Could you have performed this experiment using hexane instead of water? Explain. 3. (2 pts) Using GCMS results, analyze and discuss the purity of the Limonene obtained from the steam distillation of orange peel.arrow_forwardPart III. Arrange the following carbons (in blue) in order of increasing chemical shift. HO B NH 2 A CIarrow_forward
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