Chemistry: An Introduction to General, Organic, and Biological Chemistry, Books a la Carte Edition (13th Edition)
13th Edition
ISBN: 9780134554631
Author: Karen C. Timberlake
Publisher: PEARSON
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Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture
Chapter 11 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry, Books a la Carte Edition (13th Edition)
Ch. 11.1 - Identify each of the following as a formula of an...Ch. 11.1 - Identify each of the following as a formula of an...Ch. 11.1 - Identify each of the following properties as more...Ch. 11.1 - Identify each of the following properties as more...Ch. 11.1 - Prob. 11.5PPCh. 11.1 - Prob. 11.6PPCh. 11.2 - Give the IUPAC name for each of the following...Ch. 11.2 - Give the IUPAC name for each of the following...Ch. 11.2 - Draw the condensed structural formula for alkanes...Ch. 11.2 - Draw the condensed structural formula for alkanes...
Ch. 11.3 - Indicate whether each of the following pairs...Ch. 11.3 - Indicate whether each of the following pairs...Ch. 11.3 - Give the IUPAC name for each of the following a....Ch. 11.3 - Give the TUPAC name for each of the following: a....Ch. 11.3 - Draw the condensed structural formula for each of...Ch. 11.3 - Draw the condensed structural formula for each of...Ch. 11.3 - Draw the line-angle formula for each of the...Ch. 11.3 - Prob. 11.18PPCh. 11.4 - Heptane, used as a solvent for rubber cement, has...Ch. 11.4 - Nonane has a density of 0.79 g/mL and boils at 151...Ch. 11.4 - Write the balanced chemical equation for the...Ch. 11.4 - Write the balanced chemical equation for the...Ch. 11.5 - Identify the following as alkanes, alkenes,...Ch. 11.5 - Identify the following as alkanes, alkenes,...Ch. 11.5 - Give the IUPAC name for each of the following: a....Ch. 11.5 - Give the IUPAC name for each of the following: a....Ch. 11.5 - Draw the condensed structural formula, or...Ch. 11.5 - Prob. 11.28PPCh. 11.6 - Give the IUPAC name for each of the following,...Ch. 11.6 - Give the IUPAC name for each of the following,...Ch. 11.6 - Draw the condensed structural formula for each of...Ch. 11.6 - Prob. 11.32PPCh. 11.7 - Draw the structural formula for the product in...Ch. 11.7 - Draw the structural formula for the product in...Ch. 11.8 - Give the IUPAC name for each of the following: a....Ch. 11.8 - Give the IUPAC name for each of the following: a....Ch. 11.8 - Draw the line-angle formula for each of the...Ch. 11.8 - Draw the line-angle formula for each of the...Ch. 11.8 - Write the balanced chemical equation for the...Ch. 11.8 - Write the balanced chemical equation for the...Ch. 11 - Prob. 11.41UTCCh. 11 - Prob. 11.42UTCCh. 11 - Prob. 11.43UTCCh. 11 - Prob. 11.44UTCCh. 11 - Convert each of the following line-angle formulas...Ch. 11 - Convert each of the following line-angle formulas...Ch. 11 - Give the IUPAC name for each of the following:...Ch. 11 - Give the IUPAC name for each of the following:...Ch. 11 - Give the IUPAC name (including cis or trans, if...Ch. 11 - Give the LUPAC name (including cis or trans, if...Ch. 11 - Prob. 11.51APPCh. 11 - Prob. 11.52APPCh. 11 - Name each of the following aromatic compounds:...Ch. 11 - Prob. 11.54APPCh. 11 - Draw the condensed structural or line-angle...Ch. 11 - Draw the condensed structural or line-angle...Ch. 11 - Draw the cis and trans isomers for each of the...Ch. 11 - Draw the cis and trans isomers for each of the...Ch. 11 - Prob. 11.59APPCh. 11 - Draw the line-angle formula for each of the...Ch. 11 - Write a balanced chemical equation for the...Ch. 11 - Write a balanced chemical equation for the...Ch. 11 - Give the name for the product from the...Ch. 11 - Give the name for the product from the...Ch. 11 - Draw the condensed structural or line-angle...Ch. 11 - Draw the condensed structural or line-angle...Ch. 11 - Prob. 11.67CPCh. 11 - Prob. 11.68CPCh. 11 - Prob. 11.69CPCh. 11 - Prob. 11.70CPCh. 11 - Prob. 11.71CPCh. 11 - Prob. 11.72CPCh. 11 - Prob. 11.73CPCh. 11 - Margarines are produced from the hydrogenation of...
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- Q5: Label each chiral carbon in the following molecules as R or S. Make sure the stereocenter to which each of your R/S assignments belong is perfectly clear to the grader. (8pts) R OCH 3 CI H S 2pts for each R/S HO R H !!! I OH CI HN CI R Harrow_forwardCalculate the proton and carbon chemical shifts for this structurearrow_forwardA. B. b. Now consider the two bicyclic molecules A. and B. Note that A. is a dianion and B. is a neutral molecule. One of these molecules is a highly reactive compound first characterized in frozen noble gas matrices, that self-reacts rapidly at temperatures above liquid nitrogen temperature. The other compound was isolated at room temperature in the early 1960s, and is a stable ligand used in organometallic chemistry. Which molecule is the more stable molecule, and why?arrow_forward
- A mixture of C7H12O2, C9H9OCl, biphenyl and acetone was put together in a gas chromatography tube. Please decide from the GC resutls which correspond to the peak for C7,C9 and biphenyl and explain the reasoning based on GC results. Eliminate unnecessary peaks from Gas Chromatography results.arrow_forwardIs the molecule chiral, meso, or achiral? CI .CH3 H₂C CIarrow_forwardPLEASE HELP ! URGENT!arrow_forward
- Identify priority of the substituents: CH3arrow_forwardHow many chiral carbons are in the molecule? OH F CI Brarrow_forwardA mixture of three compounds Phen-A, Acet-B and Rin-C was analyzed using TLC with 1:9 ethanol: hexane as the mobile phase. The TLC plate showed three spots of R, 0.1 and 0.2 and 0.3. Which of the three compounds (Phen-A; Acet-B or Rin-C) would have the highest (Blank 1), middle (Blank 2) and lowest (Blank 3) spot respectively? 0 CH: 0 CH, 0 H.C OH H.CN OH Acet-B Rin-C phen-A A A <arrow_forward
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