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Concept explainers
Interpretation:
Among the given
Concept Introduction:
Geometric isomers are obtained for compounds containing carbon‑carbon double bond due to restricted rotation of the double bond. If the groups or atoms that are attached to the carbon atoms present in the double bond are different means, then the molecule is said to have geometric isomerism. Orientation of the group or the atoms that is bonded to the carbon atom will be different resulting in geometric isomers.
If the groups that are attached to the carbon atoms are present on same side of the double bond, then it is known as cis- isomer. If the groups are on opposite side of the double bond means it is known as trans- isomer.
Example:
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Chapter 11 Solutions
GENERAL,ORGANIC,+BIOCHEM.(LL) >CUSTOM<
- 2. Use Hess's law to calculate the AH (in kJ) for: rxn CIF(g) + F2(g) → CIF 3 (1) using the following information: 2CIF(g) + O2(g) → Cl₂O(g) + OF 2(g) AH = 167.5 kJ ΔΗ 2F2 (g) + O2(g) → 2 OF 2(g) 2C1F3 (1) + 202(g) → Cl₂O(g) + 3 OF 2(g) о = = -43.5 kJ AH = 394.1kJarrow_forwardci Draw the major product(s) of the following reactions: (3 pts) CH3 HNO3/H2SO4 HNO3/ H2SO4 OCH3 (1 pts)arrow_forwardProvide the product for the reactionarrow_forward
- What is the net ionic equation for the reaction between tin(IV) sulfide and nitric acid?arrow_forwardThe combustion of 28.8 g of NH3 consumes exactly _____ g of O2. 4 NH3 + 7 O2 ----> 4 NO2 + 6 H2Oarrow_forwardWhat is the molecular formula of the bond-line structure shown below OH HO ○ C14H12O2 ○ C16H14O2 ○ C16H12O2 O C14H14O2arrow_forward
- Check all molecules that are acids on the list below. H2CO3 HC2H3O2 C6H5NH2 HNO3 NH3arrow_forwardFrom the given compound, choose the proton that best fits each given description. a CH2 CH 2 Cl b с CH2 F Most shielded: (Choose one) Least shielded: (Choose one) Highest chemical shift: (Choose one) Lowest chemical shift: (Choose one) ×arrow_forwardConsider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 1H NMR spectrum? Note: A multiplet is considered one signal.arrow_forward
- For each of the given mass spectrum data, identify whether the compound contains chlorine, bromine, or neither. Compound m/z of M* peak m/z of M + 2 peak ratio of M+ : M + 2 peak Which element is present? A 122 no M + 2 peak not applicable (Choose one) B 78 80 3:1 (Choose one) C 227 229 1:1 (Choose one)arrow_forwardShow transformation from reactant to product, step by step. *see imagearrow_forwardCheck the box if the molecule contains the listed item. *See imagearrow_forward
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