(a)
To determine: The Lewis structure of the given atom, before and after the oxidation of an alcohol to an
Interpretation: The Lewis structure of the given atom, before and after the oxidation of an alcohol to an aldehyde or ketone; and the number of bonds to oxygen that each atom has before and after the oxidation is to be stated.
Concept introduction: Chromic acid is an oxidizing agent in which chromium acts as a multivalent atom. The formation of active species of chromic acid occurs by going through higher oxidation state before the oxidation to a lower oxidation state after the oxidation of alcohol.
(b)
To determine: The Lewis structure of the given atom, before and after the oxidation of an alcohol to an aldehyde or ketone; and the number of bonds to oxygen that each atom has before and after the oxidation.
Interpretation: The Lewis structure of the given atom, before and after the oxidation of an alcohol to an aldehyde or ketone and the number of bonds to oxygen does each atom before and after the oxidation is to be stated.
Concept introduction: Sodium hypochlorite is an oxidizing agent in which chlorine acts as a multivalent atom. The formation of active species of sodium hypochlorite occurs by going through higher oxidation state before the oxidation to a lower oxidation state after the oxidation of alcohol.
(c)
To determine: The Lewis structure of the given atom, before and after the oxidation of an alcohol to an aldehyde or ketone; and the number of bonds to oxygen that each atom has before and after the oxidation.
Interpretation: The Lewis structure of the given atom, before and after the oxidation of an alcohol to an aldehyde or ketone and the number of bonds to oxygen does each atom before and after the oxidation is to be stated.
Concept introduction: Sulphur in the Swern oxidation acts as a multivalent atom. The Swern oxidation comprises use of
(d)
To determine: The Lewis structure of the given atom, before and after the oxidation of an alcohol to an aldehyde or ketone; and the number of bonds to oxygen that each has atom before and after the oxidation.
Interpretation: The Lewis structure of the given atom, before and after the oxidation of an alcohol to an aldehyde or ketone; and the number of bonds to oxygen that each atom has before and after the oxidation is to be stated.
Concept introduction: Iodine in the DMP reagent acts as a multivalent atom. The formation of active species in the DMP reagent occurs by going through higher oxidation state before the oxidation to a lower oxidation state after the oxidation of alcohol.
(e)
To determine: The Lewis structure of the given atom, before and after the oxidation of an alcohol to an aldehyde or ketone, and the number of bonds to oxygen that each atom has before and after the oxidation.
Interpretation: The Lewis structure of the given atom, before and after the oxidation of an alcohol to an aldehyde or ketone and the number of bonds to oxygen that each atom has, before and after the oxidation is to be stated.
Concept introduction: The carbinol
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Chapter 11 Solutions
Pearson eText Organic Chemistry -- Instant Access (Pearson+)
- Predict the product of this organic reaction: IZ + HO i P+H₂O Specifically, in the drawing area below draw the skeletal ("line") structure of P. If there is no reasonable possibility for P, check the No answer box under the drawing area. No Answer Click and drag to start drawing a structure. ☐ :arrow_forwardPredict the products of this organic reaction: 0 O ----- A + KOH ? CH3-CH2-C-O-CH2-C-CH3 Specifically, in the drawing area below draw the condensed structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No reaction Click anywhere to draw the first atom of your structure. X ⑤ èarrow_forwardPredict the products of this organic reaction: O CH3 + H2O + HCI A A? CH3-CH2-C-N-CH3 Specifically, in the drawing area below draw the condensed structure of the product, or products, of this reaction. If there's more than one product, draw them in any arrangement you like, so long as they aren't touching. If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No Reaction Click anywhere to draw the first atom of your structure.arrow_forward
- What is the missing reactant in this organic reaction? R+ HO-C-CH2-CH3 0= CH3 CH3 —CH, C−NH—CH CH3 + H₂O Specifically, in the drawing area below draw the condensed structure of R. If there is more than one reasonable answer, you can draw any one of them. If there is no reasonable answer, check the No answer box under the drawing area. Note for advanced students: you may assume no products other than those shown above are formed. No Answer Click anywhere to draw the first atom of your structure. €arrow_forward个 CHEM&131 9267 - $25 - Intro to Mail - Hutchison, Allison (Student x Aktiv Learnin https://app.aktiv.com Draw the product of the reaction shown below. Ignore inorganic byproducts. + Na2Cr2O7 Acetone, H2SO4 Type here to search Dryng OH W Prarrow_forwardPredict the products of this organic reaction: OH + NaOH A? Specifically, in the drawing area below draw the skeletal ("line") structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No reaction Click and drag to start drawing a structure. ✓ Sarrow_forward
- Predict the products of this organic reaction: CH3-C-O-CH2-CH2-C-CH3 + H₂O ? A Specifically, in the drawing area below draw the condensed structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No reaction Click anywhere to draw the first atom of your structure. :☐ darrow_forwardDE d. Draw an arrow pushing mechanism for the following IN O CI N fo 人 P Polle DELL prt sc home end ins F5 F6 F7 F8 F9 F10 F11 F12arrow_forwardPredict the products of this organic reaction: + H₂O H* ? A Specifically, in the drawing area below draw the skeletal ("line") structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No Reaction Click and drag to start drawing a structure.arrow_forward
- Predict the major organic products of the reaction below and draw them on right side of the arrow. If there will be no significant reaction, check the box below the drawing area instead. C Cl CH, OH There will be no significant reaction. + pyridine G Click and drag to start drawing a structure.arrow_forwardWhat is the missing reactant in this organic reaction? H R+ H2O Δ OH 0= CH3-CH-O-CH3 + CH3-C-OH Specifically, in the drawing area below draw the condensed structure of R. If there is more than one reasonable answer, you can draw any one of them. If there is no reasonable answer, check the No answer box under the drawing area. No Answer Click anywhere to draw the first atom of your structure. dyarrow_forwardYou are trying to determine whether the following organic reaction can be done in a single synthesis step. If so, add any missing reagents or conditions in the drawing area below. If it isn't possible to do this reaction in a single synthesis step, check the box below the drawing area instead. Note for advanced students: if you have a choice of reagents to add, you should choose the least reactive and most economical reagents possible. Cl It isn't possible to do this reaction in a single synthesis step. + T OHarrow_forward
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