The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found. Concept Introduction: Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups. Example: The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

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Answer 1

Question

Chapter 11.14, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

(b)

Interpretation Introduction

Interpretation:

The other reagents that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

Any anhydride can be obtained using the following two pairs of reagents:

1. Acetyl chloride and a carboxylate ion.

2. Two different carboxylic acids if mixed or unsymmetrical anhydride has to be formed or two same carboxylic acids if symmetrical anhydride has to be formed.

For any simple anhydride, the two carboxylic acids from which it has been formed can be found by the simple retro analysis as shown here:

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Part VI. (a) calculate the λ max of the compound using woodward - Fieser rules. (b) what types of electronic transitions are present in the compound? (c) what are the prominent peaks in the IR spectrum of the compound?

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Answer 2

Question

Chapter 11.14, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

(b)

Interpretation Introduction

Interpretation:

The other reagents that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

Any anhydride can be obtained using the following two pairs of reagents:

1. Acetyl chloride and a carboxylate ion.

2. Two different carboxylic acids if mixed or unsymmetrical anhydride has to be formed or two same carboxylic acids if symmetrical anhydride has to be formed.

For any simple anhydride, the two carboxylic acids from which it has been formed can be found by the simple retro analysis as shown here:

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Answer 3

Question

Chapter 11.14, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

(b)

Interpretation Introduction

Interpretation:

The other reagents that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

Any anhydride can be obtained using the following two pairs of reagents:

1. Acetyl chloride and a carboxylate ion.

2. Two different carboxylic acids if mixed or unsymmetrical anhydride has to be formed or two same carboxylic acids if symmetrical anhydride has to be formed.

For any simple anhydride, the two carboxylic acids from which it has been formed can be found by the simple retro analysis as shown here:

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Answer 4

Question

Chapter 11.14, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

(b)

Interpretation Introduction

Interpretation:

The other reagents that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

Any anhydride can be obtained using the following two pairs of reagents:

1. Acetyl chloride and a carboxylate ion.

2. Two different carboxylic acids if mixed or unsymmetrical anhydride has to be formed or two same carboxylic acids if symmetrical anhydride has to be formed.

For any simple anhydride, the two carboxylic acids from which it has been formed can be found by the simple retro analysis as shown here:

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Answer 5

Chapter 11.14, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

(b)

Interpretation Introduction

Interpretation:

The other reagents that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

Any anhydride can be obtained using the following two pairs of reagents:

1. Acetyl chloride and a carboxylate ion.

2. Two different carboxylic acids if mixed or unsymmetrical anhydride has to be formed or two same carboxylic acids if symmetrical anhydride has to be formed.

For any simple anhydride, the two carboxylic acids from which it has been formed can be found by the simple retro analysis as shown here:

Answer 6

Chapter 11.14, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

Answer 7

Chapter 11.14, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

Answer 8

(b)

Interpretation Introduction

Interpretation:

The other reagents that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

Any anhydride can be obtained using the following two pairs of reagents:

1. Acetyl chloride and a carboxylate ion.

2. Two different carboxylic acids if mixed or unsymmetrical anhydride has to be formed or two same carboxylic acids if symmetrical anhydride has to be formed.

For any simple anhydride, the two carboxylic acids from which it has been formed can be found by the simple retro analysis as shown here:

Answer 9

(b)

Interpretation Introduction

Interpretation:

The other reagents that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

Any anhydride can be obtained using the following two pairs of reagents:

1. Acetyl chloride and a carboxylate ion.

2. Two different carboxylic acids if mixed or unsymmetrical anhydride has to be formed or two same carboxylic acids if symmetrical anhydride has to be formed.

For any simple anhydride, the two carboxylic acids from which it has been formed can be found by the simple retro analysis as shown here:

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11.1 - The aromas of many flowers and fruits are due to...Ch. 11.1 - Name the following compounds:Ch. 11.1 - Prob. 3P Ch. 11.2 - Prob. 4P Ch. 11.2 - Prob. 5P Ch. 11.4 - a. What is the product of the reaction of acetyl...Ch. 11.4 - Prob. 7P Ch. 11.5 - Using the pKa values listed in Table 11.1, predict...Ch. 11.6 - Starting with acetyl chloride, what neutral...Ch. 11.6 - Prob. 10P

Solution Summary: The author explains how acetyl chloride and carboxylate ion can be used to form a mixed anhydride.

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Chapter 11 Solutions