The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol. Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated. Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E 1 mechanism.

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Answer 1

Question

Chapter 11.10A, Problem 11.22P

(a)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(b)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yield mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(c)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(d)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(e)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

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Part I. Draw the stepwise reaction mechanism of each product (a, b, c, d, e, f) HO HO OH НОН,С HO OH Sucrose HO CH₂OH H N N HO -H H -OH KMnO4, Heat H OH CH₂OH (d) Phenyl Osatriazole OH НОН,С HO HO + Glacial HOAC HO- HO CH₂OH OH HO Fructose (a) Glucose OH (b) H₂N HN‍ (c) CuSO4-5H2O, ethanol H N N N HO ·H H OH H OH N CH₂OH OH (f) Phenyl Osazone H (e) Carboxy phenyl osatriazole Figure 2.1. Reaction Scheme for the Total Synthesis of Fine Chemicals

Answer 2

Question

Chapter 11.10A, Problem 11.22P

(a)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(b)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yield mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(c)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(d)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(e)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

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Answer 3

Question

Chapter 11.10A, Problem 11.22P

(a)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(b)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yield mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(c)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(d)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(e)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

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Answer 4

Question

Chapter 11.10A, Problem 11.22P

(a)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(b)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yield mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(c)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(d)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(e)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

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Answer 5

Chapter 11.10A, Problem 11.22P

(a)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(b)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yield mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(c)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(d)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

(e)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

Answer 6

Chapter 11.10A, Problem 11.22P

(a)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

Answer 7

Chapter 11.10A, Problem 11.22P

(a)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

Answer 8

(b)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yield mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

Answer 9

(b)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yield mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

Answer 10

(c)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

Answer 11

(c)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

Answer 12

(d)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

Answer 13

(d)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

Answer 14

(e)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

Answer 15

(e)

Interpretation Introduction

To determine: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol.

Interpretation: The products (major and minor) of the sulphuric acid-catalyzed dehydration of the given alcohol are to be stated.

Concept introduction: The sulphuric acid-catalyzed dehydration of alcohols yields mixture of products (major and minor). The major product is high substituted and minor product is less substituted. The dehydration of alcohols generally goes through E1 mechanism.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 11.1 - Prob. 11.1P Ch. 11.2C - Prob. 11.2P Ch. 11.3 - Prob. 11.3P Ch. 11.3 - Prob. 11.4P Ch. 11.3 - Prob. 11.5P Ch. 11.3 - Suggest the most appropriate method for each of...Ch. 11.4 - A chronic alcoholic requires a much larger dose of...Ch. 11.4 - Unlike ethylene glycol, propylene glycol...Ch. 11.5 - Predict the major products of the following...Ch. 11.5 - Show how you would convert propan-1-ol to the...

Solution Summary: The author explains that the sulphuric acid-catalyzed dehydration of alcohol yields mixture of products (major and minor).

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Chapter 11 Solutions