(a)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound CHCl3
(b)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (b)
(c)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (c)
(d)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (d)
(e)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (e)
(f)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (f)
(g)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (g)
(h)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (h)
(i)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (i)
(j)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (j)
(k)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (k)
(l)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (l)
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Chapter 1 Solutions
KLEIN'S ORGANIC CHEMISTRY
- Which representation(s) show polymer structures that are likely to result in rigid, hard materials and those that are likely to result in flexible, stretchable, soft materials?arrow_forward3. Enter the molecular weight of the product obtained from the Williamson Ether Synthesis? OH OH & OH excess CH3l Ag₂Oarrow_forwardPlease answer 1, 2 and 3 on the endarrow_forward
- In the box below, specify which of the given compounds are very soluble in polar aprotic solvents. You may select more than one compound. Choose one or more: NaCl NH4Cl CH3CH2CH2CH2CH2CN CH3CH2OH hexan-2-one NaOH CH3SCH3arrow_forwardOn the following structure, select all of the atoms that could ACCEPT a hydrogen bond. Ignore possible complications of aromaticity. When selecting be sure to click on the center of the atom.arrow_forwardRank the compounds below from lowest to highest melting point.arrow_forward
- 18 Question (1 point) Draw the line structure form of the given partially condensed structure in the box provided. :ÖH HC HC H2 ΙΩ Н2 CH2 CH3 CH3 partially condensed formarrow_forwardsomeone else has already submitted the same question on here and it was the incorrect answer.arrow_forwardThe reaction: 2NO2(g) ⇌ N2O4(g) is an exothermic reaction, ΔH=-58.0 kJ/molrxn at 0°C the KP is 58.If the initial partial pressures of both NO2(g) and N2O4(g) are 2.00 atm:A) Is the reaction at equilibrium? If not, what is the value of Q? B) Which direction will the reaction go to reach equilibrium? C) Use an ICE table to find the equilibrium pressures.arrow_forward
- The dissociation of the weak acid, nitrous acid, HNO2, takes place according to the reaction: HNO2 (aq) ⇌ H+(aq) + NO2–(aq) K=7.2 X 10-4 When 1.00 mole of HNO2 is added to 1.00 L of water, the H+ concentration at equilibrium is 0.0265 M.A) Calculate the value of Q if 1.00 L of water is added? B) How will reaction shift if 1.00 L of water is added?arrow_forwardSuppose a certain copolymer elastomeric material “styrene-butadiene rubber”) contains styrene ("S") monomers –(C8H8)– and butadiene ("B") monomers –(C4H6)– and that their numerical ratio S:B = 1:8. What is the mass ratio mS:mB of the two monomers in the material? What is the molecular mass M of a macromolecule of this copolymer with degree of polymerization n = 60,000? Data: AC = 12.01 u, AH = 1.008 u.arrow_forwardLab Questions from Lab: Gravimetric Determination of Calcium as CaC2O4•H2O What is the purpose of the methyl red indicator? Why does a color change to yellow tell you that the reaction is complete? Why is the precipitate rinsed with ice-cold water in step 4? Why not room temperature or hot water? Why is it important that the funnels be placed in a desiccator before weighing (steps 1 and 5)?arrow_forward
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