ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.)
3rd Edition
ISBN: 9781119497479
Author: Klein
Publisher: WILEY
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Chapter 1.10, Problem 29PTS
Interpretation Introduction
Interpretation:
The effect of bond angle when ammonia is converted to ammonium ion has to be explained.
Concept Introduction:
Electron groups around the central atom repel each other.
Electron groups are spaced away to minimize the repulsion-Valance shell electron pair repulsion theory.
VSEPR theory can predict the shape and bond angles in a molecule.
A bond angle is the angle defined by lines joining the centers of two atoms to a third atom to which they are bonded.
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
29.0
41.0
50.0
52.0
55.0
57.0
100
57.5
58.0
58.5
62.0
63.0
64.0
65.0
74.0
40
75.0
76.0
20
20
40
60
80
100
120
140
160
180
200 220
m/z
99.5
68564810898409581251883040
115.0
116.0
77404799
17417M
117.0
12.9
118.0
33.5
119.0
36
133 0
1.2
157.0
2.1
159.0
16
169.0
219
170.0
17
171.0
21.6
172.0
17
181.0
1.3
183.0
197.0
100.0
198.0
200.
784
Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
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4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
Chapter 1 Solutions
ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.)
Ch. 1.2 - Draw all constitutional isomers that have the...Ch. 1.2 - Prob. 1PTSCh. 1.2 - APPLY the skill
Chlorofluorocarbons (CFCs) are...Ch. 1.3 - Prob. 2LTSCh. 1.3 - Prob. 3PTSCh. 1.3 - Prob. 4PTSCh. 1.3 - Prob. 5PTSCh. 1.3 - Prob. 6PTSCh. 1.3 - Lithium salts have been used for decades to treat...Ch. 1.3 - Prob. 3LTS
Ch. 1.3 - Prob. 8PTSCh. 1.3 - Prob. 9PTSCh. 1.3 - Prob. 10PTSCh. 1.3 - Prob. 11ATSCh. 1.4 - Prob. 4LTSCh. 1.4 - Prob. 12PTSCh. 1.4 - Prob. 13PTSCh. 1.4 - Prob. 14ATSCh. 1.5 - Prob. 5LTSCh. 1.5 - Prob. 15PTSCh. 1.5 - Prob. 16ATSCh. 1.5 - Prob. 17ATSCh. 1.6 - Prob. 6LTSCh. 1.6 - Prob. 18PTSCh. 1.6 - Prob. 19PTSCh. 1.6 - Prob. 20ATSCh. 1.9 - Prob. 21CCCh. 1.9 - Prob. 22CCCh. 1.9 - Prob. 23CCCh. 1.9 - Prob. 7LTSCh. 1.9 - PRACTICE the skill
Determine the hybridization...Ch. 1.9 - APPLY the skill
Nemotin is a compound that was...Ch. 1.9 - Prob. 26CCCh. 1.10 - 1.8 PREDICTING GEOMETRY
LEARN the skill
Using...Ch. 1.10 - PRACTICE the skill
Use VSEPR theory to Predict the...Ch. 1.10 - Prob. 28PTSCh. 1.10 - Ammonia (NH3) will react with a strong acid, such...Ch. 1.10 - Volatile organic compounds (VOCs) contribute to...Ch. 1.11 - Prob. 9LTSCh. 1.11 - Prob. 31PTSCh. 1.11 - Volatile organic compounds (VOCs) contribute to...Ch. 1.12 - Prob. 10LTSCh. 1.12 - Prob. 33PTSCh. 1.12 - Epichlorohydrin (1) is an epoxide used in the...Ch. 1 - Prob. 35PPCh. 1 - Prob. 36PPCh. 1 - Prob. 37PPCh. 1 - Prob. 38PPCh. 1 - Prob. 39PPCh. 1 - Prob. 40PPCh. 1 - Prob. 41PPCh. 1 - Prob. 42PPCh. 1 - Prob. 43PPCh. 1 - Prob. 44PPCh. 1 - Prob. 45PPCh. 1 - Prob. 46PPCh. 1 - Prob. 47PPCh. 1 - Prob. 48PPCh. 1 - Prob. 49PPCh. 1 - Prob. 50PPCh. 1 - Prob. 51PPCh. 1 - Prob. 52PPCh. 1 - Prob. 53PPCh. 1 - Prob. 54PPCh. 1 - Prob. 55PPCh. 1 - Prob. 56PPCh. 1 - Prob. 57PPCh. 1 - Prob. 58PPCh. 1 - Prob. 59PPCh. 1 - Prob. 60PPCh. 1 - Prob. 61PPCh. 1 - Prob. 62PPCh. 1 - Prob. 63PPCh. 1 - Prob. 64PPCh. 1 - Prob. 65PPCh. 1 - Prob. 66IPCh. 1 - Propose at least two different structures for a...Ch. 1 - Prob. 68IPCh. 1 - Prob. 69IPCh. 1 - Prob. 70IPCh. 1 - Prob. 71IPCh. 1 - Prob. 72IPCh. 1 - Prob. 73IPCh. 1 - Prob. 74IPCh. 1 - Prob. 75IPCh. 1 - Prob. 76IPCh. 1 - Prob. 77IPCh. 1 - Prob. 78CPCh. 1 - Prob. 79CPCh. 1 - Prob. 80CPCh. 1 - Prob. 81CP
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