Concept explainers
(a)
Interpretation:
The valence level orbital on the central atoms of
(b)
Interpretation:
The shape of
(c)
Interpretation:
The number of lone pairs on the central atoms of
(d)
Interpretation:
The type and number of bonds found in
Concept Introduction:
An electronegativity of an atom gives information about the strength that the atom has for attracting a pair of shared electrons. The greater the attraction for a pair of shared electrons when the electronegativity value is high. Consequently, when two different electronegative atoms share a pair of electrons, one atom becomes partially positive and the other atom becomes partially negative due to the attractive forces for the pair of electrons.
Want to see the full answer?
Check out a sample textbook solutionChapter 11 Solutions
Foundations of College Chemistry, Binder Ready Version
- Cyanogen (CN)2 is known as pseodohalogen because it has some properties like halogens. It is composed of two CN’s joined together.(i) Draw the Lewis structure for all the possible combination for (CN)2.(ii) Calculate the formal charge and determine which one of the structures that you have drawn is most stable.(iii) For the stable structure, determine the geometry around the two central atoms.(iv) For the stable structure, draw the dipole arrows for the bonds.(v) Base on the stable structure, determine the polarity of molecule and state your reason.arrow_forwardWrite an electron configuration for each element and the corresponding Lewis structure. Indicate which electrons in the electron configuration are included in the Lewis structure.(a) N(b) C(c) Cl(d) Ararrow_forwardAnswer the following questions that relate to the chemistry of nitrogen. (a) Two nitrogen atoms combine to form a nitrogen molecule, as represented by the following equation. 2 N(g) ® N2(g) Using the table of average bond energies below, determine the enthalpy change, AH, for the reaction. Average Bond Energy (k) mol-1) Bond N-N 160 N=N 420 N°N 950 (b) The reaction between nitrogen and hydrogen to form ammonia is represented below. N2(g) + 3 H2(g)® 2 NH3(g) AH° = -92.2 kJ Predict the sign of the standard entropy change, AS', for the reaction. Justify your answer. (C) The value of AG° for the reaction represented in part (b) is negative at low temperatures but positive at high temperatures. Explain.arrow_forward
- Which of these molecules has the highest bond energy. (A) F2 (B) Cl2 (C) Br2 (D) I2arrow_forwardIn developing the concept of electronegativity, Pauling used the term excess bond energy for the difference between the actual bond energy of X¬Y and the average bond energies of X¬X and Y¬Y (see text discussion for the case of HF). Based on the values as shown, which of the following substances contains bonds with no excess bond energy?(a) PH3 (b) CS2 (c) BrCl (d) BH3 (e) Se8arrow_forwardConsider the collection of nonmetallic elements O, P, Te,I, and B. (a) Which two would form the most polar singlebond? (b) Which two would form the longest single bond?(c) Which two would be likely to form a compound of formulaXY2? (d) Which combinations of elements would likelyyield a compound of empirical formula X2Y3?arrow_forward
- Draw the Lewis structures and determine which of these molecules is least likely to exist. (A) H3S+ (B) H3O+ (С) НзО- (D) H3S- (E) OH- Draw all 5 structures with 1 central atom. All of the other atoms are attached to the central atom.arrow_forwardA resident expert on electronegativity comes up to visit with you. He makes two claims (seen below) about electronegativity with relation to covalent bonding. Is the expert correct or can you refute him with your knowledge of electronegativity? (a) If a diatomic molecule is made up of atoms X and Y, which have different electronegativities, the molecule must be polar. (b) The farther two atoms are apart in a bond, the larger the dipole moment will be.arrow_forwardSemustine is a chemotherapy drug, and exerts it's anticancer activity by damaging the DNA of the cancer cells. Predict the approximate bond angle, (c) in Semustine and the molecular geometry of the indicated oxygen (a) and nitrogen (b) atoms. (a) NH (c) CH (b) Semustine NINAarrow_forward
- Propylene, C3H6, is a gas that is used to form the importantpolymer called polypropylene. Its Lewis structure is (a) What is the total number of valence electrons in the propylenemolecule? (b) How many valence electrons are usedto make s bonds in the molecule? (c) How many valenceelectrons are used to make p bonds in the molecule? (d) Howmany valence electrons remain in nonbonding pairs in themolecule? (e) What is the hybridization at each carbon atomin the molecule?arrow_forwardConsider the following compounds: CaCl 2 , CaI 2 , and MgCl 2 . Answer the following questions based on expected periodic trends: (a) Which is expected to have t he shortest ionic bonds? (b) Which is expected to have the highest lattice energy? (c) Which is expected to have the lowest melting point?arrow_forwardDraw Lewis diagrams for the following ions. In the formula the symbol of the central atom is given first. (Hint:The valence octet may be expanded for the central atom.)(a) BrO4 - (b) PCl6 - (c) XeF6+arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY