INTRODUCTORY CHEMISTRY
8th Edition
ISBN: 2818000163285
Author: CORWIN
Publisher: PEARSON CO
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Chapter 11, Problem 7E
Interpretation Introduction
Interpretation:
The concept of vapor pressure is to be described and illustrated by using water as an example.
Concept introduction:
The process of conversion of particles of a substance from a liquid state to gaseous state below the boiling point of the substance is known as evaporation. At a temperature lower than the boiling point of a liquid, the particles are in equilibrium with liquid state and gaseous state. The particles in the gas state exert vapor pressure.
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Can you please help me and explain how I would find a mechanism consistent, using my results. Help with number 5.
The conversion of (CH3)3CI to (CH3)2C=CH2 can occur by either a one-step or a two-step mechanism, as shown in
Equations [1] and [2].
[1]
+ I +
H₂Ö:
:OH
[2]
q
slow
:OH
+ I¯
H₂Ö:
a. What rate equation would be observed for the mechanism in Equation [1]?
b. What rate equation would be observed for the mechanism in Equation [2]?
c. What is the order of each rate equation (i.e., first, second, and so forth)?
d. How can these rate equations be used to show which mechanism is the right one for this reaction?
e. Assume Equation [1] represents an endothermic reaction and draw an energy diagram for the reaction. Label the
axes, reactants, products, Ea, and AH°. Draw the structure for the transition state.
f. Assume Equation [2] represents an endothermic reaction and that the product of the rate-determining step is higher
in energy than the reactants or products. Draw an energy diagram for this two-step reaction. Label the axes,
reactants and products for each step, and the Ea and AH° for each…
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
Chapter 11 Solutions
INTRODUCTORY CHEMISTRY
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- Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardFor a complex reaction with the rate equation v = k1[A] + k2[A]2, we can say(A) that it is of order 1.(B) that it is of order 1.5.(C) that it is of order 2.(D) that for certain values of [A] it can behave as if it were of order 1, and for other values as if it were of order 2.arrow_forward
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