Chemistry: A Molecular Approach
3rd Edition
ISBN: 9780321809247
Author: Nivaldo J. Tro
Publisher: Prentice Hall
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Chapter 11, Problem 38E
Make a drawing of each unit cell: simple cubic, body-centered cubic, and face-centered cubic.
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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of
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(a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride
(b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added
to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the
reaction?
(c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
Chapter 11 Solutions
Chemistry: A Molecular Approach
Ch. 11 - Prob. 1SAQCh. 11 - Q2. Liquid nitrogen boils at 77 K. The image shown...Ch. 11 - Q3. Based on the expected intermolecular forces,...Ch. 11 - Q4. Which substance experiences dipole–dipole...Ch. 11 - Q5. One of these substances is a liquid at room...Ch. 11 - Prob. 6SAQCh. 11 - Q7. Determine the amount of heat (in kJ) required...Ch. 11 - Prob. 8SAQCh. 11 - Prob. 9SAQCh. 11 - Prob. 10SAQ
Ch. 11 - Q11. How many atoms are in the body-centered cubic...Ch. 11 - Q12. Rhodium crystallizes in a face-centered cubic...Ch. 11 - Prob. 13SAQCh. 11 - Prob. 14SAQCh. 11 - Prob. 15SAQCh. 11 - Prob. 1ECh. 11 - 2. Why are intermolecular forces important?
Ch. 11 - 3. What are the main properties of liquids (in...Ch. 11 - 4. What are the main properties of solids (in...Ch. 11 - Prob. 5ECh. 11 - Prob. 6ECh. 11 - Prob. 7ECh. 11 - Prob. 8ECh. 11 - Prob. 9ECh. 11 - Prob. 10ECh. 11 - Prob. 11ECh. 11 - Prob. 12ECh. 11 - 13. What is hydrogen bonding? How can you predict...Ch. 11 - Prob. 14ECh. 11 - Prob. 15ECh. 11 - Prob. 16ECh. 11 - Prob. 17ECh. 11 - Prob. 18ECh. 11 - 19. Why is vaporization endothermic? Why is...Ch. 11 - 20. How is the volatility of a substance related...Ch. 11 - 21. What is the heat of vaporization for a liquid...Ch. 11 - 22. Explain the process of dynamic equilibrium....Ch. 11 - Prob. 23ECh. 11 - Prob. 24ECh. 11 - Prob. 25ECh. 11 - 26. What is the Clausius–Clapeyron equation and...Ch. 11 - Prob. 27ECh. 11 - Prob. 28ECh. 11 - Prob. 29ECh. 11 - Prob. 30ECh. 11 - 31. Examine the heating curve for water in Section...Ch. 11 - Prob. 32ECh. 11 - Prob. 33ECh. 11 - What is the significance of crossing a line in a...Ch. 11 - Prob. 35ECh. 11 - Prob. 36ECh. 11 - 37. What is a crystalline lattice? How is the...Ch. 11 - Make a drawing of each unit cell: simple cubic,...Ch. 11 - Prob. 39ECh. 11 - 40. What is the difference between hexagonal...Ch. 11 - Prob. 41ECh. 11 - Prob. 42ECh. 11 - Prob. 43ECh. 11 - Prob. 44ECh. 11 - What are the three basic types of atomic solids?...Ch. 11 - Prob. 46ECh. 11 - Prob. 47ECh. 11 - Prob. 48ECh. 11 - Prob. 49ECh. 11 - Prob. 50ECh. 11 - Prob. 51ECh. 11 - Prob. 52ECh. 11 - 39. Arrange these compounds in order of increasing...Ch. 11 - Prob. 54ECh. 11 - Prob. 55ECh. 11 - Prob. 56ECh. 11 - Prob. 57ECh. 11 - Prob. 58ECh. 11 - Prob. 59ECh. 11 - Prob. 60ECh. 11 - Prob. 61ECh. 11 - Prob. 62ECh. 11 - Prob. 63ECh. 11 - 50. Explain why the viscosity of multigrade motor...Ch. 11 - 51. Water in a glass tube that contains grease or...Ch. 11 - Prob. 66ECh. 11 - Prob. 67ECh. 11 - Prob. 68ECh. 11 - Prob. 69ECh. 11 - Prob. 70ECh. 11 - 57. The human body obtains 915 kJ of energy from a...Ch. 11 - Prob. 72ECh. 11 - Prob. 73ECh. 11 - Prob. 74ECh. 11 - Prob. 75ECh. 11 - Prob. 76ECh. 11 - Prob. 77ECh. 11 - Prob. 78ECh. 11 - Prob. 79ECh. 11 - Prob. 80ECh. 11 - Prob. 81ECh. 11 - Prob. 82ECh. 11 - Prob. 83ECh. 11 - 72. How much heat (in kJ) is evolved in converting...Ch. 11 - Prob. 85ECh. 11 - 74. Consider the phase diagram for iodine shown...Ch. 11 - Prob. 87ECh. 11 - Prob. 88ECh. 11 - Prob. 89ECh. 11 - Prob. 90ECh. 11 - Prob. 91ECh. 11 - Prob. 92ECh. 11 - Prob. 93ECh. 11 - 82. How is the density of solid water compared to...Ch. 11 - Prob. 95ECh. 11 - Prob. 96ECh. 11 - 97. Determine the number of atoms per unit cell...Ch. 11 - 3098. Determine the coordination number for each...Ch. 11 - Prob. 99ECh. 11 - Prob. 100ECh. 11 - Prob. 101ECh. 11 - Prob. 102ECh. 11 - Prob. 103ECh. 11 - Prob. 104ECh. 11 - Prob. 105ECh. 11 - 106. Identify each solid as molecular, ionic, or...Ch. 11 - 10741. Which solid has the highest melting point?...Ch. 11 - Prob. 108ECh. 11 - Prob. 109ECh. 11 - Prob. 110ECh. 11 - Prob. 111ECh. 11 - Prob. 112ECh. 11 - Prob. 113ECh. 11 - Prob. 114ECh. 11 - Prob. 115ECh. 11 - 62116. How many molecular orbitals are present in...Ch. 11 - Prob. 117ECh. 11 - Prob. 118ECh. 11 - 83119. Explain the observed trend in the melting...Ch. 11 - Prob. 120ECh. 11 - Prob. 121ECh. 11 - Prob. 122ECh. 11 - Prob. 123ECh. 11 - Prob. 124ECh. 11 - Prob. 125ECh. 11 - 90. A sample of steam with a mass of 0.552 g and...Ch. 11 - Prob. 127ECh. 11 - Prob. 128ECh. 11 - Prob. 129ECh. 11 - 94. A sealed flask contains 0.55 g of water at 28...Ch. 11 - Prob. 131ECh. 11 - Prob. 132ECh. 11 - Prob. 133ECh. 11 - Prob. 134ECh. 11 - 135. The unit cell in a crystal of diamond belongs...Ch. 11 - Prob. 136ECh. 11 - Prob. 137ECh. 11 - 96. Consider a planet where the pressure of the...Ch. 11 - 139. An unknown metal is found to have a density...Ch. 11 - 140. When spheres of radius r are packed in a...Ch. 11 - Prob. 141ECh. 11 - Prob. 143ECh. 11 - Prob. 144ECh. 11 - Prob. 145ECh. 11 - 98. Given that the heat of fusion of water is...Ch. 11 - 99. The heat of combustion of CH4 is 890.4 kJ/mol,...Ch. 11 - Prob. 148ECh. 11 - Prob. 149ECh. 11 - 102. Butane (C4H10) has a heat of vaporization of...Ch. 11 - Prob. 159ECh. 11 - 104. One prediction of global warming is the...Ch. 11 - Prob. 151ECh. 11 - Prob. 152ECh. 11 - Prob. 153ECh. 11 - Prob. 154ECh. 11 - Prob. 155ECh. 11 - Prob. 156ECh. 11 - Prob. 157ECh. 11 - Prob. 158E
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- 1. Sodium azide (NaN3) is the primary chemical substance used in automobile air bags. Upon impact, the decomposition of sodium azide is initiated to produce sodium metal and nitrogen gas which then inflates the bag. How many liters of nitrogen gas are produced at 1.15 atm and 30.0°C when 145.0 grams of sodium azide decomposes? 2. Calcium carbonate (such as that in limestone) reacts with aqueous hydrochloric acid to produce carbon dioxide, aqueous calcium chloride and water. How many liters of carbon dioxide are produced at 20°C and 745 torr when 3.583 grams of calcium carbonate is dissolved in solution containing 1.550 grams of hydrochloric acid?arrow_forwardShow all work (where appropriate) for full credit. 1. Describe (steps, equipment and quantities) how to accurately prepare 250.0 mL of a 0.0075 M solution of NaCl (aq) from a 500 mL, 0.0500 M stock solution. 2. Describe (steps, equipment and quantities) how to accurately prepare 250.0 mL of a 0.0075 M solution of NaCl (aq) from 100 g of solid NaCl.arrow_forward5. An unlabeled gas cylinder was recently found in the laboratory. A sample of the gas was removed and analyzed. A 500.0 mL sample of the gas at 15°C and a pressure of 736 mmHg was found to weigh 2.688 g. Determine the molar mass of the gas. What element is the gas?arrow_forward
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