ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY
ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY
3rd Edition
ISBN: 9781119477617
Author: Klein
Publisher: WILEY
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Chapter 11, Problem 34IP
Interpretation Introduction

Interpretation:

A multi-step synthesis of 1-penten-3-ol using acetylene as only source of carbon atoms has to be given.

Concept Introduction:

Catalytic hydrogenation:  It is the addition of molecular hydrogen across triple bond in presence of Lindlar’s catalyst.  This catalyst stops hydrogenation to alkene.

ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 11, Problem 34IP , additional homework tip  1

Ozonolysis:  It involves breaking of alkene double bond and addition of oxygen atoms to form carbonyl compounds.

ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 11, Problem 34IP , additional homework tip  2

Hydro-halogenation reaction: In this reaction, hydrogen halide added across the unsaturated bond (alkene).

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 11, Problem 34IP , additional homework tip  3

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3
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