Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305545014
Author: CRACOLICE
Publisher: Cengage
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Chapter 11, Problem 33E
Interpretation Introduction
Interpretation:
The reason behind the overlapping of energies of the principal energy levels of an atom is to be stated.
Concept introduction:
The
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Synthesis of ZybanⓇ:
1. Write a mechanism for the bromination of m-chloropropiophenone.
Br₂
CH2Cl2
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3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
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Synthesis of Ibuprofen-Part 2:
1. Some pain relievers including ibuprofen (MotrinⓇ) and naproxen (Aleve®) are "α-arylpropanoic acids." Look up the structure
of naproxen (AleveⓇ), another a-arylpropionic acid. Using the same reactions that we used for making ibuprofen, show how
to make naproxen from the compound below. Show all intermediates and reagents in your synthesis.
Show how you would prepare ibuprofen starting from p-isobutylbenzene rather than p-isobutylacetophenenone. What reaction
steps would need to change/add?
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Acid Catalyzed Aromatization of Carvone:
1. Starting with the ketone, below, draw a mechanism for the reaction to give the phenol as shown.
H2SO4
HO-
H₂O
2. Why do we use CDCl instead of CHCl, for acquiring our NMR spectra?
3. Why does it not matter which enantiomer of carvone is used for this reaction?
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What other impurities are present in your product and how do you know?
Chapter 11 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 11 - Prob. 1ECh. 11 - Prob. 2ECh. 11 - Identify measurable wave properties that are used...Ch. 11 - Prob. 4ECh. 11 - Which among the following are not quantized? a...Ch. 11 - Which of the following are quantized? a canned...Ch. 11 - Prob. 7ECh. 11 - In the Bohr model of the hydrogen atom, the...Ch. 11 - Prob. 9ECh. 11 - Prob. 10E
Ch. 11 - Prob. 11ECh. 11 - Prob. 12ECh. 11 - Prob. 13ECh. 11 - Prob. 14ECh. 11 - Prob. 15ECh. 11 - Prob. 16ECh. 11 - Prob. 17ECh. 11 - Prob. 18ECh. 11 - Prob. 19ECh. 11 - How many sublevels are there in an atom with n=4?Ch. 11 - Prob. 21ECh. 11 - Prob. 22ECh. 11 - Prob. 23ECh. 11 - Prob. 24ECh. 11 - The principal energy level with n=6 contains six...Ch. 11 - Although we may draw the 4s orbital with the shape...Ch. 11 - Prob. 27ECh. 11 - Prob. 28ECh. 11 - Prob. 29ECh. 11 - Prob. 30ECh. 11 - Prob. 31ECh. 11 - Prob. 32ECh. 11 - Prob. 33ECh. 11 - Prob. 34ECh. 11 - Prob. 35ECh. 11 - Is the quantum mechanical model of the atom...Ch. 11 - Prob. 37ECh. 11 - Prob. 38ECh. 11 - What element has the electron configuration...Ch. 11 - Prob. 40ECh. 11 - Prob. 41ECh. 11 - What is meant by [Ne] in [Ne]3s23p1?Ch. 11 - Prob. 43ECh. 11 - Prob. 44ECh. 11 - Prob. 45ECh. 11 - Prob. 46ECh. 11 - Prob. 47ECh. 11 - Prob. 48ECh. 11 - Prob. 49ECh. 11 - Prob. 50ECh. 11 - Prob. 51ECh. 11 - Prob. 52ECh. 11 - Use a noble gas core to write the electron...Ch. 11 - a Write the complete ground state electron...Ch. 11 - 55. Why are valence electrons important?Ch. 11 - Prob. 56ECh. 11 - Prob. 57ECh. 11 - Prob. 58ECh. 11 - Prob. 59ECh. 11 - Prob. 60ECh. 11 - Prob. 61ECh. 11 - . Using only the periodic table, arrange the...Ch. 11 - Prob. 63ECh. 11 - Prob. 64ECh. 11 - Prob. 65ECh. 11 - Prob. 66ECh. 11 - Prob. 67ECh. 11 - Using only the periodic table, arrange the...Ch. 11 - Prob. 69ECh. 11 - Using only the periodic table, arrange the...Ch. 11 - Prob. 71ECh. 11 - Give the symbol for an element that is: a a...Ch. 11 - Prob. 73ECh. 11 - a What is the name of the alkali metal that is in...Ch. 11 - Prob. 75ECh. 11 - Which of the following describes the element Ba?...Ch. 11 - Prob. 77ECh. 11 - Which of the following describes the element Br?...Ch. 11 - Prob. 79ECh. 11 - Prob. 80ECh. 11 - Prob. 81ECh. 11 - Prob. 82ECh. 11 - Prob. 83ECh. 11 - Prob. 84ECh. 11 - Prob. 85ECh. 11 - Prob. 86ECh. 11 - Prob. 87ECh. 11 - Prob. 88ECh. 11 - Prob. 89ECh. 11 - Prob. 90ECh. 11 - Prob. 91ECh. 11 - Determine whether each statement that follows is...Ch. 11 - Prob. 93ECh. 11 - Prob. 94ECh. 11 - Prob. 95ECh. 11 - Prob. 96ECh. 11 - Prob. 97ECh. 11 - Prob. 98ECh. 11 - Prob. 99ECh. 11 - Prob. 100ECh. 11 - Prob. 101ECh. 11 - Prob. 102ECh. 11 - Prob. 103ECh. 11 - Prob. 104ECh. 11 - Prob. 105ECh. 11 - Prob. 106ECh. 11 - Prob. 107ECh. 11 - Prob. 108ECh. 11 - Prob. 109ECh. 11 - Prob. 11.1TCCh. 11 - Prob. 11.2TCCh. 11 - Prob. 11.3TCCh. 11 - Prob. 11.4TCCh. 11 - Prob. 11.5TCCh. 11 - Prob. 1CLECh. 11 - Prob. 2CLECh. 11 - Prob. 3CLECh. 11 - Prob. 4CLECh. 11 - Prob. 5CLECh. 11 - Prob. 6CLECh. 11 - Prob. 7CLECh. 11 - Prob. 8CLECh. 11 - Prob. 9CLECh. 11 - Write the electron configuration of the highest...Ch. 11 - Prob. 2PECh. 11 - Prob. 3PECh. 11 - Prob. 4PECh. 11 - Prob. 5PECh. 11 - Prob. 6PECh. 11 - Prob. 7PE
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