Chemistry In Focus
7th Edition
ISBN: 9781337399692
Author: Tro, Nivaldo J.
Publisher: Cengage Learning,
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Chapter 11, Problem 27E
Interpretation Introduction
Interpretation:
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Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed
a chemical structure shown below:
% Transmittance
4000
3500
3000
2500 2000
Wavenumber (cm-1)
1500
1000
(a) Explain why her proposed structure is inconsistent with the IR spectrum obtained
(b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure
and explain why it is more compatible with the obtained spectrum.
(C) what is the possible source for the fairly intense signal at
1621cm1
AE>AE₁ (Y/N)
AE=AE₁ (Y/N)
AE
Treatment of 2-phenylpropan-2-amine with methyl 2,4-dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive SN2 reactions and
gives compound A.
?
NH2
Br
Br
Propose a structural formula for compound A.
You do not have to explicitly draw H atoms.
You do not have to consider stereochemistry.
In cases where there is more than one answer, just draw one.
R3N
C14H19NO2
+ 2 R3NH*Br
A
Chapter 11 Solutions
Chemistry In Focus
Ch. 11 - Prob. 11.1YTCh. 11 - A balloon has an initial temperature of 30.0C and...Ch. 11 - Prob. 11.3YTCh. 11 - Prob. 1SCCh. 11 - Prob. 2SCCh. 11 - Prob. 3SCCh. 11 - Prob. 1ECh. 11 - Prob. 2ECh. 11 - Prob. 3ECh. 11 - Prob. 4E
Ch. 11 - Prob. 5ECh. 11 - Prob. 6ECh. 11 - Prob. 7ECh. 11 - Prob. 8ECh. 11 - Prob. 9ECh. 11 - Prob. 10ECh. 11 - Prob. 11ECh. 11 - Prob. 12ECh. 11 - Why is oxygen central to the existence of animal...Ch. 11 - Prob. 14ECh. 11 - Prob. 15ECh. 11 - Prob. 16ECh. 11 - Prob. 17ECh. 11 - Prob. 18ECh. 11 - Prob. 19ECh. 11 - What are the adverse health and environmental...Ch. 11 - Prob. 21ECh. 11 - Prob. 22ECh. 11 - Prob. 23ECh. 11 - Prob. 24ECh. 11 - With the help of chemical equations, explain how...Ch. 11 - Prob. 26ECh. 11 - Prob. 27ECh. 11 - Why does ozone deplete severely over Antarctica...Ch. 11 - Has ozone been depleted over other areas of the...Ch. 11 - Prob. 30ECh. 11 - Prob. 31ECh. 11 - Prob. 32ECh. 11 - Prob. 33ECh. 11 - Prob. 34ECh. 11 - Prob. 35ECh. 11 - Prob. 36ECh. 11 - The pressure on Mt. Everest is approximately 0.31...Ch. 11 - Prob. 38ECh. 11 - Prob. 39ECh. 11 - The pressure in Denver, Colorado, is approximately...Ch. 11 - Prob. 41ECh. 11 - Prob. 42ECh. 11 - Jet airplanes often fly in the lower stratosphere,...Ch. 11 - Prob. 44ECh. 11 - Prob. 45ECh. 11 - Prob. 46ECh. 11 - Prob. 47ECh. 11 - A 2.8 L balloon is warmed over a toaster, and its...Ch. 11 - A cylinder with a movable piston has an initial...Ch. 11 - Prob. 50ECh. 11 - Prob. 51ECh. 11 - Prob. 52ECh. 11 - Prob. 53ECh. 11 - Prob. 54ECh. 11 - Explain the difference between the effects of...Ch. 11 - Prob. 58ECh. 11 - Prob. 59ECh. 11 - Prob. 60E
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