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Chapter 11, Problem 134E

(a)

Interpretation Introduction

To calculate: The length of the line (labeled c, body diagonal) in terms of r (i.e. the atomic radius).

(b)

Interpretation Introduction

To calculate: The length of the face diagonal (b) in terms of edge length (l).

(c)

Interpretation Introduction

To calculate: The edge length (l) in terms of r.

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?

Chapter 11 Solutions

Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Principles Of Chemistry: A Molecular Approach

Ch. 11 - Q11. How many atoms are in the body-centered cubic...Ch. 11 - Q12. Rhodium crystallizes in a face-centered cubic...Ch. 11 - Prob. 13SAQCh. 11 - Prob. 14SAQCh. 11 - Prob. 15SAQCh. 11 - Prob. 1ECh. 11 - 2. Why are intermolecular forces important? Ch. 11 - 3. What are the main properties of liquids (in...Ch. 11 - 4. What are the main properties of solids (in...Ch. 11 - Prob. 5ECh. 11 - Prob. 6ECh. 11 - Prob. 7ECh. 11 - Prob. 8ECh. 11 - Prob. 9ECh. 11 - Prob. 10ECh. 11 - Prob. 11ECh. 11 - Prob. 12ECh. 11 - 13. What is hydrogen bonding? How can you predict...Ch. 11 - Prob. 14ECh. 11 - Prob. 15ECh. 11 - Prob. 16ECh. 11 - Prob. 17ECh. 11 - Prob. 18ECh. 11 - 19. Why is vaporization endothermic? Why is...Ch. 11 - 20. How is the volatility of a substance related...Ch. 11 - 21. What is the heat of vaporization for a liquid...Ch. 11 - 22. Explain the process of dynamic equilibrium....Ch. 11 - Prob. 23ECh. 11 - Prob. 24ECh. 11 - Prob. 25ECh. 11 - 26. What is the Clausius–Clapeyron equation and...Ch. 11 - Prob. 27ECh. 11 - Prob. 28ECh. 11 - Prob. 29ECh. 11 - Prob. 30ECh. 11 - 31. Examine the heating curve for water in Section...Ch. 11 - Prob. 32ECh. 11 - Prob. 33ECh. 11 - What is the significance of crossing a line in a...Ch. 11 - Prob. 35ECh. 11 - Prob. 36ECh. 11 - 37. What is a crystalline lattice? How is the...Ch. 11 - Make a drawing of each unit cell: simple cubic,...Ch. 11 - Prob. 39ECh. 11 - 40. What is the difference between hexagonal...Ch. 11 - Prob. 41ECh. 11 - Prob. 42ECh. 11 - Prob. 43ECh. 11 - Prob. 44ECh. 11 - What are the three basic types of atomic solids?...Ch. 11 - Prob. 46ECh. 11 - Prob. 47ECh. 11 - Prob. 48ECh. 11 - Prob. 49ECh. 11 - Prob. 50ECh. 11 - Prob. 51ECh. 11 - Prob. 52ECh. 11 - 39. Arrange these compounds in order of increasing...Ch. 11 - Prob. 54ECh. 11 - Prob. 55ECh. 11 - Prob. 56ECh. 11 - Prob. 57ECh. 11 - Prob. 58ECh. 11 - Prob. 59ECh. 11 - Prob. 60ECh. 11 - Prob. 61ECh. 11 - Prob. 62ECh. 11 - Prob. 63ECh. 11 - 50. Explain why the viscosity of multigrade motor...Ch. 11 - 51. Water in a glass tube that contains grease or...Ch. 11 - Prob. 66ECh. 11 - Prob. 67ECh. 11 - Prob. 68ECh. 11 - Prob. 69ECh. 11 - Prob. 70ECh. 11 - 57. The human body obtains 915 kJ of energy from a...Ch. 11 - Prob. 72ECh. 11 - Prob. 73ECh. 11 - Prob. 74ECh. 11 - Prob. 75ECh. 11 - Prob. 76ECh. 11 - Prob. 77ECh. 11 - Prob. 78ECh. 11 - Prob. 79ECh. 11 - Prob. 80ECh. 11 - Prob. 81ECh. 11 - Prob. 82ECh. 11 - Prob. 83ECh. 11 - 72. How much heat (in kJ) is evolved in converting...Ch. 11 - Prob. 85ECh. 11 - 74. Consider the phase diagram for iodine shown...Ch. 11 - Prob. 87ECh. 11 - Prob. 88ECh. 11 - Prob. 89ECh. 11 - Prob. 90ECh. 11 - Prob. 91ECh. 11 - Prob. 92ECh. 11 - Prob. 93ECh. 11 - 82. How is the density of solid water compared to...Ch. 11 - Prob. 95ECh. 11 - Prob. 96ECh. 11 - 97. Determine the number of atoms per unit cell...Ch. 11 - 3098. Determine the coordination number for each...Ch. 11 - Prob. 99ECh. 11 - Prob. 100ECh. 11 - Prob. 101ECh. 11 - Prob. 102ECh. 11 - Prob. 103ECh. 11 - Prob. 104ECh. 11 - Prob. 105ECh. 11 - 106. Identify each solid as molecular, ionic, or...Ch. 11 - 10741. Which solid has the highest melting point?...Ch. 11 - Prob. 108ECh. 11 - Prob. 109ECh. 11 - Prob. 110ECh. 11 - Prob. 111ECh. 11 - Prob. 112ECh. 11 - Prob. 113ECh. 11 - Prob. 114ECh. 11 - Prob. 115ECh. 11 - 62116. How many molecular orbitals are present in...Ch. 11 - Prob. 117ECh. 11 - Prob. 118ECh. 11 - 83119. Explain the observed trend in the melting...Ch. 11 - Prob. 120ECh. 11 - Prob. 121ECh. 11 - Prob. 122ECh. 11 - Prob. 123ECh. 11 - Prob. 124ECh. 11 - Prob. 125ECh. 11 - 90. A sample of steam with a mass of 0.552 g and...Ch. 11 - Prob. 127ECh. 11 - Prob. 128ECh. 11 - Prob. 129ECh. 11 - 94. A sealed flask contains 0.55 g of water at 28...Ch. 11 - Prob. 131ECh. 11 - Prob. 132ECh. 11 - Prob. 133ECh. 11 - Prob. 134ECh. 11 - 135. The unit cell in a crystal of diamond belongs...Ch. 11 - Prob. 136ECh. 11 - Prob. 137ECh. 11 - 96. Consider a planet where the pressure of the...Ch. 11 - 139. An unknown metal is found to have a density...Ch. 11 - 140. When spheres of radius r are packed in a...Ch. 11 - Prob. 141ECh. 11 - Prob. 143ECh. 11 - Prob. 144ECh. 11 - Prob. 145ECh. 11 - 98. Given that the heat of fusion of water is...Ch. 11 - 99. The heat of combustion of CH4 is 890.4 kJ/mol,...Ch. 11 - Prob. 148ECh. 11 - Prob. 149ECh. 11 - 102. Butane (C4H10) has a heat of vaporization of...Ch. 11 - Prob. 159ECh. 11 - 104. One prediction of global warming is the...Ch. 11 - Prob. 151ECh. 11 - Prob. 152ECh. 11 - Prob. 153ECh. 11 - Prob. 154ECh. 11 - Prob. 155ECh. 11 - Prob. 156ECh. 11 - Prob. 157ECh. 11 - Prob. 158E
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