CHEMISTRY
2nd Edition
ISBN: 9781593995782
Author: OpenStax
Publisher: XANEDU PUBLISHING
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Textbook Question
Chapter 11, Problem 12E
Compare the processes that occur when methanol (CH3OH), hydrogen chloride (HCI), and sodium hydroxide (NaOH) dissolve in water. Write equations and prepare sketches showing the form in which each of these compounds is present in its respective solution.
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Consider the "C NMR spectrum below.
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The spectrum belongs to which one of the following constitutional isomers of the compound C,H12? Select the single best answer.
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The structure of compound 1,3,5-trimethylbenzene (mesitylene) is given below.
How many signals would you expect to find in the 'H NMR spectrum of 1,3,5-trimethylbenzene (mesitylene)?
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1
How many signals do you expect in the 'H NMR spectrum for this molecule?
CI CI
Cl
Write the answer in the table below.
Also, in each of the drawing areas below is a copy of the molecule, with H atoms shown. In each copy, one of the H atoms is highlighted red. Highlight in red all
other H atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: Remember, a multiplet is considered one signal in the 'H NMR spectrum.
1
Number of signals in the 'H NMR spectrum.
☐
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same
signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional H atoms to highlight in
top molecule
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the
same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at…
Chapter 11 Solutions
CHEMISTRY
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Ch. 11 - Consider the solutions presented: (a) Which of the...Ch. 11 - Compare the processes that occur when methanol...Ch. 11 - What is the expected electrical conductivity of...Ch. 11 - Why are most solid ionic compounds electrically...Ch. 11 - Indicate the most important type of intermolecular...Ch. 11 - Suppose you are presented with a clear solution of...Ch. 11 - Supersaturated solutions of most solids in water...Ch. 11 - Suggest an explanation for the observations that...Ch. 11 - Calculate the percent by mass of KBr in a...Ch. 11 - Which of the following gases is expected to be...Ch. 11 - At 0 C and 1.00 atm, as much as 0.70 g of O2 can...Ch. 11 - Refer to Figure 11.11. (a) How did the...Ch. 11 - The Henry's law constant for CO2 is 3.4102 M/atm...Ch. 11 - The Henry's law constant for O2 is 1.3103M /atm at...Ch. 11 - How many liters of HCI gas, measured at 30.0 C and...Ch. 11 - Which is are part of the macroscopic domain of...Ch. 11 - What is the microscopic explanation for the...Ch. 11 - Sketch a qualitative graph of the pressure versus...Ch. 11 - A solution of potassium nitrate, an electrolyte,...Ch. 11 - What are the mole fractions of H3PO4 and water in...Ch. 11 - What are the mole fractions of HNO3 and water in a...Ch. 11 - Calculate the mole fraction of each solute and...Ch. 11 - Calculate the mole fraction of each solute and...Ch. 11 - Calculate the mole fractions of methanol, CH3OH;...Ch. 11 - What is the difference between a 1 M solution and...Ch. 11 - What is the molality of phosphoric acid, H3PO4, in...Ch. 11 - What is the molality of nitric acid in a...Ch. 11 - Calculate the molality of each of the following...Ch. 11 - Calculate the molality of each of the following...Ch. 11 - The concentration of glucose, C6H12O6, in normal...Ch. 11 - A 13.0% solution of K2CO3 by mass has a density of...Ch. 11 - Why does 1 mol of sodium chloride depress the...Ch. 11 - What is the boiling point of a solution of 115.0 g...Ch. 11 - What is the boiling point of a solution of 9.04 g...Ch. 11 - What is the freezing temperature of a solution of...Ch. 11 - What is the freezing point of a solution of 9.04 g...Ch. 11 - What is the osmotic pressure of an aqueous...Ch. 11 - What is osmotic pressure of a solution of bovine...Ch. 11 - What is the molar mass of a solution of 5.00 g of...Ch. 11 - A sample of an organic compound (a nonelectrolyte)...Ch. 11 - A 1.0 m solution of HCI in benzene has a freezing...Ch. 11 - A solution contains 5.00 g of urea, CO(NH2)2, a...Ch. 11 - A 12.0-g sample of a nonelectrolyte is dissolved...Ch. 11 - Arrange the following solutions in order by their...Ch. 11 - Calculate the boiling point elevation of 0.100 kg...Ch. 11 - How could you prepare a 3.08 m aqueous solution of...Ch. 11 - A sample of sulfur weighing 0.210 g was dissolved...Ch. 11 - In a significant experiment performed many years...Ch. 11 - Lysozyme is an enzyme that cleaves cell walls. A...Ch. 11 - The osmotic pressure of a solution containing 7.0...Ch. 11 - The osmotic pressure of human blood is 7.6 atm at...Ch. 11 - What is the freezing point of a solution of...Ch. 11 - What is the boiling point of a solution of NaCI in...Ch. 11 - The sugar fructose contains 40.0% C, 6.7% H, and...Ch. 11 - The vapor pressure of methanol, CH3OH, is 94 torr...Ch. 11 - The triple point of air-free water is defined as...Ch. 11 - Meat can be classified as fresh (not frozen) even...Ch. 11 - An organic compound has a composition of 93.46% C...Ch. 11 - A sample of HgCI2 weighing 9.41 g is dissolved in...Ch. 11 - A salt is known to be an alkali metal fluoride. A...Ch. 11 - Identify the dispersed phase and the dispersion...Ch. 11 - Distinguish between dispersion methods and...Ch. 11 - How do colloids differ from solutions with regard...Ch. 11 - Explain the cleansing action of soap.Ch. 11 - How can it be demonstrated that colloidal...
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- wrtie the balanced equation and find the E° when the following half- reactions are combined Zn2+(aq) + 2e---> Zn(s) E°= -0.763V Ag+(aq) + e---> Ag (s) E°=+0.799Varrow_forwardConsider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 'H NMR spectrum? Note: A multiplet is considered one signal. ☐arrow_forwardStudy this 'H NMR spectrum, and then answer the questions about it in the table below. Check 1.0- 0.5- 0.0 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 What unit symbol should be written on the horizontal axis? What is the chemical shift & of the doublet? If there is no doublet, just check the box instead. Give your answer to 2 significant digits. What is the chemical shift of the signal immediately upfield of the doublet? If there is no doublet, or no signal upfield of it, check the box instead. What is the chemical shift & of the least deshielded proton? If you can't tell without more information, check the box instead. 血 8 = ☐ There is no doublet. 8 = ☐ No such signal. 8 = 0 Need more information.arrow_forward
- how many moles of H2O2 are required to react with 11g of N2H4 according to the following reaction? (atomic weights: N=14.01, H=1.008, O= 16.00) 7H2O2 + N2H4 -> 2HNO3 + 8H20arrow_forwardcalculate the number of moles of H2 produced from 0.78 moles of Ga and 1.92 moles HCL? 2Ga+6HCL->2GaCl3+3H2arrow_forwardan adult human breathes 0.50L of air at 1 atm with each breath. If a 50L air tank at 200 atm is available, how man y breaths will the tank providearrow_forward
- Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO2 (g) = N2O4(g) AGº = -5.4 kJ Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system: Under these conditions, will the pressure of N2O4 tend to rise or fall? Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to '2' rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. 00 rise ☐ x10 fall yes no ☐ atm G Ar 1arrow_forwardWhy do we analyse salt?arrow_forwardCurved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. H H CH3OH, H+ H Select to Add Arrows H° 0:0 'H + Q HH ■ Select to Add Arrows CH3OH, H* H. H CH3OH, H+ HH ■ Select to Add Arrows i Please select a drawing or reagent from the question areaarrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY