CHEMICAL PRINCIPLES PKG W/SAPLING
CHEMICAL PRINCIPLES PKG W/SAPLING
7th Edition
ISBN: 9781319086411
Author: ATKINS
Publisher: MAC HIGHER
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Chapter 11, Problem 11D.26E
Interpretation Introduction

Interpretation:

The molecules or ions that can acts as nucleophile in nucleophilic substitution reactions have to be given.

Concept Introduction:

Nucleophile: A chemical species that donates an electron pair to form a chemical bond is called as nucleophile.  All molecules or ions with lone pair of electrons or atleast one pi bond acts as nucleophile.  Since nucleophiles donate electrons, they are Lewis bases.  Nucleophiles may take part in a nucleophilic substitution reaction, whereby a nucleophile becomes attracted to a full or partial positive charge.

Electrophiles: A chemical species that accepts an electron pair are called as electrophiles.  Electrophiles are positively charged or neutral species having vacant orbitals that are attracted to an electron rich center.  It takes part in chemical reaction by accepting an electron pair in order to bond to a nucleophile.

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Draw the organic product formed when the following compounds undergo a substitution reaction: (a) acetic acid and methyl-amine; (b) butanoic acid and 2-propanol; (c) Formica acid and 2-methyl-1-propanol.
Ester formation and ester hydrolysis are exactly the same reaction only written in reverse. General reaction of ester formation: H*, heat R—с—он + Н—о—R' R—с—о-R' + H,O carboxylic acid alcohol carboxylic or phenol ester General reaction of ester hydrolysis: || R—с—OR' + H—оН R—с—оН +R—ОH ester carboxylic acid alcohol or phenol What determines which direction the reaction proceeds and what actually forms? o the boiling point of the carboxylic acid o the presence (or absence) of heat as well as the concentration of reactants and products o the molecular weight of reactants and products o the presence (or absence) of heat as well as the catalyst
Draw the organic product formed when the following compounds undergo a substitution reaction: (a) acetic acid and methylamine; (b) butanoic acid and 2-propanol; (c) formic acid and 2-methyl-1-propanol.

Chapter 11 Solutions

CHEMICAL PRINCIPLES PKG W/SAPLING

Ch. 11 - Prob. 11A.6ASTCh. 11 - Prob. 11A.6BSTCh. 11 - Prob. 11A.1ECh. 11 - Prob. 11A.2ECh. 11 - Prob. 11A.3ECh. 11 - Prob. 11A.4ECh. 11 - Prob. 11A.5ECh. 11 - Prob. 11A.6ECh. 11 - Prob. 11A.7ECh. 11 - Prob. 11A.8ECh. 11 - Prob. 11A.9ECh. 11 - Prob. 11A.10ECh. 11 - Prob. 11A.11ECh. 11 - Prob. 11A.12ECh. 11 - Prob. 11A.13ECh. 11 - Prob. 11A.14ECh. 11 - Prob. 11A.15ECh. 11 - Prob. 11A.16ECh. 11 - Prob. 11A.17ECh. 11 - Prob. 11A.18ECh. 11 - Prob. 11A.19ECh. 11 - Prob. 11A.20ECh. 11 - Prob. 11A.21ECh. 11 - Prob. 11A.22ECh. 11 - Prob. 11A.23ECh. 11 - Prob. 11A.24ECh. 11 - Prob. 11A.25ECh. 11 - Prob. 11A.26ECh. 11 - Prob. 11A.27ECh. 11 - Prob. 11A.28ECh. 11 - Prob. 11B.1ASTCh. 11 - Prob. 11B.1BSTCh. 11 - Prob. 11B.1ECh. 11 - Prob. 11B.3ECh. 11 - Prob. 11B.4ECh. 11 - Prob. 11B.5ECh. 11 - Prob. 11B.6ECh. 11 - Prob. 11B.7ECh. 11 - Prob. 11B.8ECh. 11 - Prob. 11C.1ASTCh. 11 - Prob. 11C.1BSTCh. 11 - Prob. 11C.1ECh. 11 - Prob. 11C.2ECh. 11 - Prob. 11C.3ECh. 11 - Prob. 11C.4ECh. 11 - Prob. 11C.5ECh. 11 - Prob. 11C.6ECh. 11 - Prob. 11C.7ECh. 11 - Prob. 11C.8ECh. 11 - Prob. 11C.9ECh. 11 - Prob. 11C.10ECh. 11 - Prob. 11C.11ECh. 11 - Prob. 11C.12ECh. 11 - Prob. 11C.13ECh. 11 - Prob. 11C.14ECh. 11 - Prob. 11D.1ASTCh. 11 - Prob. 11D.1BSTCh. 11 - Prob. 11D.2ASTCh. 11 - Prob. 11D.2BSTCh. 11 - Prob. 11D.3ASTCh. 11 - Prob. 11D.3BSTCh. 11 - Prob. 11D.1ECh. 11 - Prob. 11D.2ECh. 11 - Prob. 11D.3ECh. 11 - Prob. 11D.4ECh. 11 - Prob. 11D.5ECh. 11 - Prob. 11D.6ECh. 11 - Prob. 11D.7ECh. 11 - Prob. 11D.8ECh. 11 - Prob. 11D.9ECh. 11 - Prob. 11D.10ECh. 11 - Prob. 11D.11ECh. 11 - Prob. 11D.12ECh. 11 - Prob. 11D.13ECh. 11 - Prob. 11D.14ECh. 11 - Prob. 11D.15ECh. 11 - Prob. 11D.16ECh. 11 - Prob. 11D.17ECh. 11 - Prob. 11D.18ECh. 11 - Prob. 11D.19ECh. 11 - Prob. 11D.20ECh. 11 - Prob. 11D.21ECh. 11 - Prob. 11D.22ECh. 11 - Prob. 11D.23ECh. 11 - Prob. 11D.24ECh. 11 - Prob. 11D.25ECh. 11 - Prob. 11D.26ECh. 11 - Prob. 11D.27ECh. 11 - Prob. 11D.28ECh. 11 - Prob. 11D.29ECh. 11 - Prob. 11D.30ECh. 11 - Prob. 11D.31ECh. 11 - Prob. 11D.32ECh. 11 - Prob. 11D.33ECh. 11 - Prob. 11D.34ECh. 11 - Prob. 11D.35ECh. 11 - Prob. 11D.36ECh. 11 - Prob. 11E.1ASTCh. 11 - Prob. 11E.1BSTCh. 11 - Prob. 11E.2ASTCh. 11 - Prob. 11E.2BSTCh. 11 - Prob. 11E.1ECh. 11 - Prob. 11E.3ECh. 11 - Prob. 11E.4ECh. 11 - Prob. 11E.5ECh. 11 - Prob. 11E.7ECh. 11 - Prob. 11E.8ECh. 11 - Prob. 11E.9ECh. 11 - Prob. 11E.10ECh. 11 - Prob. 11E.11ECh. 11 - Prob. 11E.12ECh. 11 - Prob. 11E.13ECh. 11 - Prob. 11E.14ECh. 11 - Prob. 11E.15ECh. 11 - Prob. 11E.16ECh. 11 - Prob. 11E.17ECh. 11 - Prob. 11E.18ECh. 11 - Prob. 11E.19ECh. 11 - Prob. 11E.20ECh. 11 - Prob. 11E.21ECh. 11 - Prob. 11E.22ECh. 11 - Prob. 11E.23ECh. 11 - Prob. 11E.24ECh. 11 - Prob. 11E.25ECh. 11 - Prob. 11E.26ECh. 11 - Prob. 11E.27ECh. 11 - Prob. 11E.28ECh. 11 - Prob. 11.1ECh. 11 - Prob. 11.2ECh. 11 - Prob. 11.3ECh. 11 - Prob. 11.4ECh. 11 - Prob. 11.5ECh. 11 - Prob. 11.6ECh. 11 - Prob. 11.7ECh. 11 - Prob. 11.8ECh. 11 - Prob. 11.9ECh. 11 - Prob. 11.10ECh. 11 - Prob. 11.11ECh. 11 - Prob. 11.12ECh. 11 - Prob. 11.13ECh. 11 - Prob. 11.14ECh. 11 - Prob. 11.15ECh. 11 - Prob. 11.16ECh. 11 - Prob. 11.17ECh. 11 - Prob. 11.18ECh. 11 - Prob. 11.19ECh. 11 - Prob. 11.20ECh. 11 - Prob. 11.21ECh. 11 - Prob. 11.23ECh. 11 - Prob. 11.24ECh. 11 - Prob. 11.25ECh. 11 - Prob. 11.26ECh. 11 - Prob. 11.27ECh. 11 - Prob. 11.28ECh. 11 - Prob. 11.29ECh. 11 - Prob. 11.30ECh. 11 - Prob. 11.31ECh. 11 - Prob. 11.32ECh. 11 - Prob. 11.33ECh. 11 - Prob. 11.34ECh. 11 - Prob. 11.35ECh. 11 - Prob. 11.36ECh. 11 - Prob. 11.37ECh. 11 - Prob. 11.38ECh. 11 - Prob. 11.41ECh. 11 - Prob. 11.42ECh. 11 - Prob. 11.43ECh. 11 - Prob. 11.44ECh. 11 - Prob. 11.45ECh. 11 - Prob. 11.47ECh. 11 - Prob. 11.49ECh. 11 - Prob. 11.50ECh. 11 - Prob. 11.51ECh. 11 - Prob. 11.52ECh. 11 - Prob. 11.53ECh. 11 - Prob. 11.54ECh. 11 - Prob. 11.55ECh. 11 - Prob. 11.56ECh. 11 - Prob. 11.57E
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