Atkins' Physical chemistry
11th Edition
ISBN: 9780198814740
Author: ATKINS, P. W. (peter William), 1940- (author.)
Publisher: Oxford University Press,
expand_more
expand_more
format_list_bulleted
Question
Chapter 11, Problem 11B.5BE
Interpretation Introduction
Interpretation:
The centrifugal distortion constant for the
Concept introduction:
The molecules on rotation tend to experience a centrifugal force. This centrifugal force brings about a change in the molecular geometry and the moment of inertia of molecule. The centrifugal force stretches the bond and increases the moment of inertia. This further decreases the rotational constant.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Q4: Write organic product(s) of the following reactions and show the curved-arrow mechanism
of the reactions.
Br
MeOH
OSO2CH3
MeOH
Provide the correct IUPAC name
for the compound shown here.
Reset
cis-
5-
trans-
☑
4-6- 2- 1- 3-
di iso tert- tri cyclo sec-
oct but hept prop hex pent
yl yne
ene
ane
Q6: Predict the major product(s) for the following reactions. Note the mechanism (SN1, SN2, E1
or E2) the reaction proceeds through. If no reaction takes place, indicate why. Pay attention to
stereochemistry.
NaCN
DMF
Br
σ
Ilm...
Br H
Br H
H
NaCN
CH3OH
KOtBu
tBuOH
NaBr
H₂O
LDA
Et2O
(CH3)2CHOH
KCN
DMSO
NaOH
H₂O, A
LDA
LDA
System
Chapter 11 Solutions
Atkins' Physical chemistry
Ch. 11 - Prob. 11A.1STCh. 11 - Prob. 11A.2STCh. 11 - Prob. 11B.1STCh. 11 - Prob. 11B.2STCh. 11 - Prob. 11B.3STCh. 11 - Prob. 11B.4STCh. 11 - Prob. 11C.1STCh. 11 - Prob. 11C.2STCh. 11 - Prob. 11D.1STCh. 11 - Prob. 11E.1ST
Ch. 11 - Prob. 11E.2STCh. 11 - Prob. 11F.2STCh. 11 - Prob. 11A.1DQCh. 11 - Prob. 11A.2DQCh. 11 - Prob. 11A.3DQCh. 11 - Prob. 11A.1AECh. 11 - Prob. 11A.1BECh. 11 - Prob. 11A.2AECh. 11 - Prob. 11A.2BECh. 11 - Prob. 11A.3AECh. 11 - Prob. 11A.3BECh. 11 - Prob. 11A.4AECh. 11 - Prob. 11A.4BECh. 11 - Prob. 11A.5AECh. 11 - Prob. 11A.5BECh. 11 - Prob. 11A.6AECh. 11 - Prob. 11A.6BECh. 11 - Prob. 11A.7AECh. 11 - Prob. 11A.7BECh. 11 - Prob. 11A.8AECh. 11 - Prob. 11A.8BECh. 11 - Prob. 11A.9AECh. 11 - Prob. 11A.9BECh. 11 - Prob. 11A.10AECh. 11 - Prob. 11A.10BECh. 11 - Prob. 11A.11AECh. 11 - Prob. 11A.11BECh. 11 - Prob. 11A.12AECh. 11 - Prob. 11A.12BECh. 11 - Prob. 11A.1PCh. 11 - Prob. 11A.2PCh. 11 - Prob. 11A.3PCh. 11 - Prob. 11A.4PCh. 11 - Prob. 11A.5PCh. 11 - Prob. 11A.7PCh. 11 - Prob. 11A.8PCh. 11 - Prob. 11A.9PCh. 11 - Prob. 11A.11PCh. 11 - Prob. 11B.1DQCh. 11 - Prob. 11B.2DQCh. 11 - Prob. 11B.3DQCh. 11 - Prob. 11B.4DQCh. 11 - Prob. 11B.5DQCh. 11 - Prob. 11B.6DQCh. 11 - Prob. 11B.7DQCh. 11 - Prob. 11B.8DQCh. 11 - Prob. 11B.1AECh. 11 - Prob. 11B.1BECh. 11 - Prob. 11B.3AECh. 11 - Prob. 11B.3BECh. 11 - Prob. 11B.4BECh. 11 - Prob. 11B.5AECh. 11 - Prob. 11B.5BECh. 11 - Prob. 11B.6AECh. 11 - Prob. 11B.6BECh. 11 - Prob. 11B.7AECh. 11 - Prob. 11B.7BECh. 11 - Prob. 11B.8AECh. 11 - Prob. 11B.8BECh. 11 - Prob. 11B.9AECh. 11 - Prob. 11B.9BECh. 11 - Prob. 11B.10AECh. 11 - Prob. 11B.10BECh. 11 - Prob. 11B.11AECh. 11 - Prob. 11B.11BECh. 11 - Prob. 11B.12AECh. 11 - Prob. 11B.12BECh. 11 - Prob. 11B.13AECh. 11 - Prob. 11B.13BECh. 11 - Prob. 11B.14AECh. 11 - Prob. 11B.14BECh. 11 - Prob. 11B.1PCh. 11 - Prob. 11B.2PCh. 11 - Prob. 11B.3PCh. 11 - Prob. 11B.4PCh. 11 - Prob. 11B.5PCh. 11 - Prob. 11B.6PCh. 11 - Prob. 11B.7PCh. 11 - Prob. 11B.8PCh. 11 - Prob. 11B.9PCh. 11 - Prob. 11B.10PCh. 11 - Prob. 11B.11PCh. 11 - Prob. 11B.12PCh. 11 - Prob. 11B.13PCh. 11 - Prob. 11B.14PCh. 11 - Prob. 11C.1DQCh. 11 - Prob. 11C.2DQCh. 11 - Prob. 11C.3DQCh. 11 - Prob. 11C.4DQCh. 11 - Prob. 11C.1AECh. 11 - Prob. 11C.1BECh. 11 - Prob. 11C.2AECh. 11 - Prob. 11C.2BECh. 11 - Prob. 11C.3AECh. 11 - Prob. 11C.3BECh. 11 - Prob. 11C.4AECh. 11 - Prob. 11C.4BECh. 11 - Prob. 11C.5AECh. 11 - Prob. 11C.5BECh. 11 - Prob. 11C.6AECh. 11 - Prob. 11C.6BECh. 11 - Prob. 11C.7AECh. 11 - Prob. 11C.7BECh. 11 - Prob. 11C.8AECh. 11 - Prob. 11C.8BECh. 11 - Prob. 11C.2PCh. 11 - Prob. 11C.3PCh. 11 - Prob. 11C.4PCh. 11 - Prob. 11C.5PCh. 11 - Prob. 11C.6PCh. 11 - Prob. 11C.7PCh. 11 - Prob. 11C.8PCh. 11 - Prob. 11C.9PCh. 11 - Prob. 11C.10PCh. 11 - Prob. 11C.11PCh. 11 - Prob. 11C.12PCh. 11 - Prob. 11C.13PCh. 11 - Prob. 11C.15PCh. 11 - Prob. 11C.17PCh. 11 - Prob. 11C.18PCh. 11 - Prob. 11C.19PCh. 11 - Prob. 11D.1DQCh. 11 - Prob. 11D.2DQCh. 11 - Prob. 11D.3DQCh. 11 - Prob. 11D.1AECh. 11 - Prob. 11D.1BECh. 11 - Prob. 11D.2AECh. 11 - Prob. 11D.2BECh. 11 - Prob. 11D.3AECh. 11 - Prob. 11D.3BECh. 11 - Prob. 11D.4AECh. 11 - Prob. 11D.4BECh. 11 - Prob. 11D.5AECh. 11 - Prob. 11D.5BECh. 11 - Prob. 11D.6AECh. 11 - Prob. 11D.6BECh. 11 - Prob. 11D.7AECh. 11 - Prob. 11D.7BECh. 11 - Prob. 11D.2PCh. 11 - Prob. 11E.1DQCh. 11 - Prob. 11E.1AECh. 11 - Prob. 11E.1BECh. 11 - Prob. 11E.2AECh. 11 - Prob. 11E.2BECh. 11 - Prob. 11E.3AECh. 11 - Prob. 11E.3BECh. 11 - Prob. 11E.1PCh. 11 - Prob. 11E.2PCh. 11 - Prob. 11F.1DQCh. 11 - Prob. 11F.2DQCh. 11 - Prob. 11F.3DQCh. 11 - Prob. 11F.4DQCh. 11 - Prob. 11F.5DQCh. 11 - Prob. 11F.6DQCh. 11 - Prob. 11F.1AECh. 11 - Prob. 11F.1BECh. 11 - Prob. 11F.2AECh. 11 - Prob. 11F.2BECh. 11 - Prob. 11F.3AECh. 11 - Prob. 11F.3BECh. 11 - Prob. 11F.4AECh. 11 - Prob. 11F.4BECh. 11 - Prob. 11F.5AECh. 11 - Prob. 11F.5BECh. 11 - Prob. 11F.6AECh. 11 - Prob. 11F.6BECh. 11 - Prob. 11F.7AECh. 11 - Prob. 11F.7BECh. 11 - Prob. 11F.8AECh. 11 - Prob. 11F.8BECh. 11 - Prob. 11F.9AECh. 11 - Prob. 11F.9BECh. 11 - Prob. 11F.10AECh. 11 - Prob. 11F.10BECh. 11 - Prob. 11F.11AECh. 11 - Prob. 11F.11BECh. 11 - Prob. 11F.12AECh. 11 - Prob. 11F.12BECh. 11 - Prob. 11F.13AECh. 11 - Prob. 11F.13BECh. 11 - Prob. 11F.1PCh. 11 - Prob. 11F.2PCh. 11 - Prob. 11F.3PCh. 11 - Prob. 11F.4PCh. 11 - Prob. 11F.5PCh. 11 - Prob. 11F.6PCh. 11 - Prob. 11F.7PCh. 11 - Prob. 11F.8PCh. 11 - Prob. 11F.9PCh. 11 - Prob. 11F.10PCh. 11 - Prob. 11F.11PCh. 11 - Prob. 11F.12PCh. 11 - Prob. 11G.1DQCh. 11 - Prob. 11G.2DQCh. 11 - Prob. 11G.3DQCh. 11 - Prob. 11G.4DQCh. 11 - Prob. 11G.5DQCh. 11 - Prob. 11G.1AECh. 11 - Prob. 11G.1BECh. 11 - Prob. 11G.2AECh. 11 - Prob. 11G.2BECh. 11 - Prob. 11G.1PCh. 11 - Prob. 11G.2PCh. 11 - Prob. 11G.3PCh. 11 - Prob. 11G.4PCh. 11 - Prob. 11G.5PCh. 11 - Prob. 11G.6PCh. 11 - Prob. 11.1IACh. 11 - Prob. 11.5IACh. 11 - Prob. 11.8IA
Knowledge Booster
Similar questions
- Q7: For the following reactions, indicate the reaction conditions that would provide the indicated product in a high yield. Note the major reaction pathway that would take place (SN1, SN2, E1, or E2) Note: There may be other products that are not shown. There maybe more than one plausible pathway. Br H3C OH H3C CI ... H3C SCH2CH3 CI i SCH2CH3 ཨ་ Br System Settarrow_forwardQ2: Rank the compounds in each of the following groups in order of decreasing rate of solvolysis in aqueous acetone. OSO2CF3 OSO2CH3 OH a. b. CI Brarrow_forwardох 4-tert-butyl oxy cyclohex-1-ene Incorrect, 1 attempt remaining The systematic name of this compound classifies the -OR group as a substituent of the hydrocarbon, which is considered the principal functional group. The ether substituent is named with the suffix 'oxy'. The general format for the systematic name of a hydrocarbon is: [prefix/substituent] + [parent] + [functional group suffix] Substituents are listed in alphabetical order. Molecules with a chiral center will indicate the absolute configuration at the beginning of its name with the R and S notation.arrow_forward
- 5. Compressibility (6 points total). The isothermal compressibility is a measure of how hard/easy it is to compress an object (how squishy is it?) at constant temperature. It is др defined as Br=-()=-(200²)T' (a) You might wonder why there is a negative sign in this formula. What does it mean when this quantity is positive and what does it mean when this quantity is negative? (b) Derive the formula for the isothermal compressibility of an ideal gas (it is very simple!) (c) Explain under what conditions for the ideal gas the compressibility is higher or lower, and why that makes sense.arrow_forward19. (3 pts) in Chapter 7 we will see a reaction of halocyclohexanes that requires that the halogen occupy an axial position with this in mind, would you expect cis-1-bromo-3-methylcyclohexane or trans-1-bromo-3-methylcyclohexane to be more reactive in this reaction? Briefly explain your choice using structures to support your answer. Mere-eries-cecleone) The tran-i-browse-3-methylcyclohexionearrow_forwardPlease help me calculate the undiluted samples ppm concentration. My calculations were 280.11 ppm. Please see if I did my math correctly using the following standard curve. Link: https://mnscu-my.sharepoint.com/:x:/g/personal/vi2163ss_go_minnstate_edu/EVSJL_W0qrxMkUjK2J3xMUEBHDu0UM1vPKQ-bc9HTcYXDQ?e=hVuPC4arrow_forward
- Provide an IUPAC name for each of the compounds shown. (Specify (E)/(Z) stereochemistry, if relevant, for straight chain alkenes only. Pay attention to commas, dashes, etc.) H₁₂C C(CH3)3 C=C H3C CH3 CH3CH2CH CI CH3 Submit Answer Retry Entire Group 2 more group attempts remaining Previous Nextarrow_forwardArrange the following compounds / ions in increasing nucleophilicity (least to most nucleophilic) CH3NH2 CH3C=C: CH3COO 1 2 3 5 Multiple Choice 1 point 1, 2, 3 2, 1, 3 3, 1, 2 2, 3, 1 The other answers are not correct 0000arrow_forwardcurved arrows are used to illustrate the flow of electrons. using the provided starting and product structures, draw the cured electron-pushing arrows for thw following reaction or mechanistic steps. be sure to account for all bond-breaking and bond making stepsarrow_forward
- Using the graphs could you help me explain the answers. I assumed that both graphs are proportional to the inverse of time, I think. Could you please help me.arrow_forwardSynthesis of Dibenzalacetone [References] Draw structures for the carbonyl electrophile and enolate nucleophile that react to give the enone below. Question 1 1 pt Question 2 1 pt Question 3 1 pt H Question 4 1 pt Question 5 1 pt Question 6 1 pt Question 7 1pt Question 8 1 pt Progress: 7/8 items Que Feb 24 at You do not have to consider stereochemistry. . Draw the enolate ion in its carbanion form. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. ⚫ Separate multiple reactants using the + sign from the drop-down menu. ? 4arrow_forwardShown below is the mechanism presented for the formation of biasplatin in reference 1 from the Background and Experiment document. The amounts used of each reactant are shown. Either draw or describe a better alternative to this mechanism. (Note that the first step represents two steps combined and the proton loss is not even shown; fixing these is not the desired improvement.) (Hints: The first step is correct, the second step is not; and the amount of the anhydride is in large excess to serve a purpose.)arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY