Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781285969770
Author: Ball
Publisher: Cengage
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Chapter 11, Problem 11.89E
Interpretation Introduction

Interpretation:

The given equation for the complete Schrӧdinger equation for a hydrogen-like atom is to be verified.

Concept introduction:

The wavefunction for 3-D rotational motion involves spherical polar coordinates to explain the motion in three dimensions. It is given by the expression as follows.

Ψm,l=12πeimϕθl,ml

Where, Ψm represents the wavefunction dependent on quantum number m and l. The values of m and l start from 0. Also, they can take up both negative and positive integral values.According to Euler’s identity, eimϕ can be written as cosϕ+isinϕ.

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Chapter 11 Solutions

Physical Chemistry

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