CHEM:ATOM FOC 2E CL (TEXT)
2nd Edition
ISBN: 9780393284218
Author: Stacey Lowery Bretz, Natalie Foster, Thomas R. Gilbert, Rein V. Kirss
Publisher: WW Norton & Co
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Chapter 11, Problem 11.87QA
Interpretation Introduction
To find:
If CaCl2 could melt ice at
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5) Oxaloacetic Acid is an important intermediate in the biosynthesis of citric acid. Synthesize oxaloacetic acid
using a mixed Claisen Condensation reaction with two different esters and a sodium ethoxide base. Give your
answer as a scheme
Hint 1: Your final acid product is producing using a decarboxylation reaction.
Hint 2: Look up the structure of oxalic acid.
HO
all
OH
oxaloacetic acid
20. The Brusselator. This hypothetical system was first proposed by a group work-
ing in Brussels [see Prigogine and Lefever (1968)] in connection with spatially
nonuniform chemical patterns. Because certain steps involve trimolecular reac
tions, it is not a model of any real chemical system but rather a prototype that
has been studied extensively. The reaction steps are
A-X.
B+X-Y+D.
2X+ Y-3X,
X-E.
305
It is assumed that concentrations of A, B, D, and E are kept artificially con
stant so that only X and Y vary with time.
(a) Show that if all rate constants are chosen appropriately, the equations de
scribing a Brusselator are:
dt
A-(B+ 1)x + x²y,
dy
=Bx-x²y.
di
Problem 3. Provide a mechanism for the following transformation:
H₂SO A
Me.
Me
Me
Me
Me
Chapter 11 Solutions
CHEM:ATOM FOC 2E CL (TEXT)
Ch. 11 - Prob. 11.1VPCh. 11 - Prob. 11.2VPCh. 11 - Prob. 11.3VPCh. 11 - Prob. 11.4VPCh. 11 - Prob. 11.5VPCh. 11 - Prob. 11.6VPCh. 11 - Prob. 11.7VPCh. 11 - Prob. 11.8VPCh. 11 - Prob. 11.9VPCh. 11 - Prob. 11.10VP
Ch. 11 - Prob. 11.11QACh. 11 - Prob. 11.12QACh. 11 - Prob. 11.13QACh. 11 - Prob. 11.14QACh. 11 - Prob. 11.15QACh. 11 - Prob. 11.16QACh. 11 - Prob. 11.17QACh. 11 - Prob. 11.18QACh. 11 - Prob. 11.19QACh. 11 - Prob. 11.20QACh. 11 - Prob. 11.21QACh. 11 - Prob. 11.22QACh. 11 - Prob. 11.23QACh. 11 - Prob. 11.24QACh. 11 - Prob. 11.25QACh. 11 - Prob. 11.26QACh. 11 - Prob. 11.27QACh. 11 - Prob. 11.28QACh. 11 - Prob. 11.29QACh. 11 - Prob. 11.30QACh. 11 - Prob. 11.31QACh. 11 - Prob. 11.32QACh. 11 - Prob. 11.33QACh. 11 - Prob. 11.34QACh. 11 - Prob. 11.35QACh. 11 - Prob. 11.36QACh. 11 - Prob. 11.37QACh. 11 - Prob. 11.38QACh. 11 - Prob. 11.39QACh. 11 - Prob. 11.40QACh. 11 - Prob. 11.41QACh. 11 - Prob. 11.42QACh. 11 - Prob. 11.43QACh. 11 - Prob. 11.44QACh. 11 - Prob. 11.45QACh. 11 - Prob. 11.46QACh. 11 - Prob. 11.47QACh. 11 - Prob. 11.48QACh. 11 - Prob. 11.49QACh. 11 - Prob. 11.50QACh. 11 - Prob. 11.51QACh. 11 - Prob. 11.52QACh. 11 - Prob. 11.53QACh. 11 - Prob. 11.54QACh. 11 - Prob. 11.55QACh. 11 - Prob. 11.56QACh. 11 - Prob. 11.57QACh. 11 - Prob. 11.58QACh. 11 - Prob. 11.59QACh. 11 - Prob. 11.60QACh. 11 - Prob. 11.61QACh. 11 - Prob. 11.62QACh. 11 - Prob. 11.63QACh. 11 - Prob. 11.64QACh. 11 - Prob. 11.65QACh. 11 - Prob. 11.66QACh. 11 - Prob. 11.67QACh. 11 - Prob. 11.68QACh. 11 - Prob. 11.69QACh. 11 - Prob. 11.70QACh. 11 - Prob. 11.71QACh. 11 - Prob. 11.72QACh. 11 - Prob. 11.73QACh. 11 - Prob. 11.74QACh. 11 - Prob. 11.75QACh. 11 - Prob. 11.76QACh. 11 - Prob. 11.77QACh. 11 - Prob. 11.78QACh. 11 - Prob. 11.79QACh. 11 - Prob. 11.80QACh. 11 - Prob. 11.81QACh. 11 - Prob. 11.82QACh. 11 - Prob. 11.83QACh. 11 - Prob. 11.84QACh. 11 - Prob. 11.85QACh. 11 - Prob. 11.86QACh. 11 - Prob. 11.87QACh. 11 - Prob. 11.88QACh. 11 - Prob. 11.89QACh. 11 - Prob. 11.90QACh. 11 - Prob. 11.91QACh. 11 - Prob. 11.92QACh. 11 - Prob. 11.93QACh. 11 - Prob. 11.94QACh. 11 - Prob. 11.95QACh. 11 - Prob. 11.96QA
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- You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: xi 1. ☑ 2. H₂O хе i Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. There is no reagent that will make this synthesis work without complications. : ☐ S ☐arrow_forwardPredict the major products of this organic reaction: H OH 1. LiAlH4 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. G C टेarrow_forwardFor each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 CI MgCl ? Will the first product that forms in this reaction create a new CC bond? Yes No MgBr ? Will the first product that forms in this reaction create a new CC bond? Yes No G टेarrow_forward
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