Principles of General Organic & Biological Chemistry
Principles of General Organic & Biological Chemistry
2nd Edition
ISBN: 9780077633721
Author: Janice Smith
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 11, Problem 11.71AP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the given compound has to be assigned.

    Principles of General Organic & Biological Chemistry, Chapter 11, Problem 11.71AP , additional homework tip  1

Concept Introduction:

Nomenclature of Benzene derivatives:

  • First identify the number of substituent present in the benzene ring.
  • If benzene ring has only one substituent, then name the substituent and add this word to benzene.
  • If benzene ring has two substituent, then prefix ortho(1,2), meta(1,3), para(1,4) are used to locate the position of the substituent and ortho, meta, para are generally represented as o, m, p respectively.
  • If benzene ring has three or more substituent, then the numbering should be given as the lowest possible number around the ring.
  • Substituent names should be assigned in alphabetical order.
  • If substituent is part of common roots, then the name should be assigned as their derivatives.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the given compound has to be assigned.

    Principles of General Organic & Biological Chemistry, Chapter 11, Problem 11.71AP , additional homework tip  2

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the given compound has to be assigned.

    Principles of General Organic & Biological Chemistry, Chapter 11, Problem 11.71AP , additional homework tip  3

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the given compound has to be assigned.

    Principles of General Organic & Biological Chemistry, Chapter 11, Problem 11.71AP , additional homework tip  4

Concept Introduction:

Refer to part (a).

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a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)? b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
a. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here?  b. What is the purpose of the Na2SO4?  c. What equipment would you use to “concentrate [a solution] under reduced pressure”?

Chapter 11 Solutions

Principles of General Organic & Biological Chemistry

Ch. 11.3 - Prob. 11.11PCh. 11.5 - Prob. 11.12PCh. 11.5 - Prob. 11.13PCh. 11.6 - Prob. 11.14PCh. 11.6 - Prob. 11.15PCh. 11.7 - Prob. 11.16PCh. 11.7 - Prob. 11.17PCh. 11.9 - Prob. 11.18PCh. 11.9 - Draw the structure corresponding to each name. a....Ch. 11.10 - Prob. 11.20PCh. 11.10 - Prob. 11.21PCh. 11.10 - Prob. 11.22PCh. 11 - Prob. 11.23UKCCh. 11 - Prob. 11.24UKCCh. 11 - Prob. 11.25UKCCh. 11 - Prob. 11.26UKCCh. 11 - Answer the following questions about compound A,...Ch. 11 - Prob. 11.28UKCCh. 11 - Prob. 11.29UKCCh. 11 - Prob. 11.30UKCCh. 11 - Prob. 11.31UKCCh. 11 - Prob. 11.32UKCCh. 11 - Prob. 11.33APCh. 11 - Prob. 11.34APCh. 11 - Prob. 11.35APCh. 11 - Prob. 11.36APCh. 11 - Prob. 11.37APCh. 11 - Falcarinol is a natural pesticide found in carrots...Ch. 11 - Prob. 11.39APCh. 11 - Prob. 11.40APCh. 11 - Prob. 11.41APCh. 11 - Prob. 11.42APCh. 11 - Prob. 11.43APCh. 11 - Give the structure corresponding to each IUPAC...Ch. 11 - Leukotriene C4 is a key compound that causes the...Ch. 11 - Prob. 11.46APCh. 11 - Prob. 11.47APCh. 11 - Prob. 11.48APCh. 11 - Prob. 11.49APCh. 11 - Prob. 11.50APCh. 11 - Prob. 11.51APCh. 11 - Prob. 11.52APCh. 11 - Prob. 11.53APCh. 11 - Prob. 11.54APCh. 11 - Prob. 11.55APCh. 11 - Prob. 11.56APCh. 11 - Prob. 11.57APCh. 11 - Draw the products formed in each reaction.Ch. 11 - Prob. 11.59APCh. 11 - Prob. 11.60APCh. 11 - Prob. 11.61APCh. 11 - Prob. 11.62APCh. 11 - Prob. 11.63APCh. 11 - Prob. 11.64APCh. 11 - Prob. 11.65APCh. 11 - Prob. 11.66APCh. 11 - Prob. 11.67APCh. 11 - Prob. 11.68APCh. 11 - Prob. 11.69APCh. 11 - Prob. 11.70APCh. 11 - Prob. 11.71APCh. 11 - Prob. 11.72APCh. 11 - Prob. 11.73APCh. 11 - Prob. 11.74APCh. 11 - Prob. 11.75APCh. 11 - Prob. 11.76APCh. 11 - Prob. 11.77APCh. 11 - Prob. 11.78APCh. 11 - Prob. 11.79APCh. 11 - Prob. 11.80APCh. 11 - Prob. 11.81APCh. 11 - Prob. 11.82APCh. 11 - Prob. 11.83APCh. 11 - Prob. 11.84APCh. 11 - Prob. 11.85APCh. 11 - Prob. 11.86APCh. 11 - Are cis-2-hexene and trans-3-hexene constitutional...Ch. 11 - Prob. 11.88CP
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