(a) Interpretation: Give the reaction why the IUPAC name of the compound 1,3-Dimethylbutane is incorrect and give the correct IUPAC name for it. Concept Introduction: While naming the branched alkanes , first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Question

2. Propose an efficient synthesis for each of the following transformations. Pay careful attention to both the regio and stereochemical outcomes. ¡ H H racemic

Answer 1

Question

Chapter 11, Problem 11.66P

Interpretation Introduction

(a)

Interpretation:

Give the reaction why the IUPAC name of the compound 1,3-Dimethylbutane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(b)

Interpretation:

Give the reaction why the IUPAC name of the compound 4-Methylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(c)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Diethylbutane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

If there are two different substituents, then these are listed in alphabetical order and numbering of the chain is done from the end that gives the lower number to the substituent encountered first.

Interpretation Introduction

(d)

Interpretation:

Give the reaction why the IUPAC name of the compound 2-Ethyl-3-methylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(e)

Interpretation:

Give the reaction why the IUPAC name of the compound 2-Propylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(f)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylheptane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

If there are two different substituents, then these are listed in alphabetical order and numbering of the chain is done from the end that gives the lower number to the substituent encountered first.

Interpretation Introduction

(g)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylcyclopropane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the alkanes having same substituents, numbering is done from the end that gives the lower number.

Interpretation Introduction

(h)

Interpretation:

Give the reaction why the IUPAC name of the compound 1-Ethyl-5-methylcyclohexane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

The numbering of the parent chain starts from the end that gives the lower number to the substituent encountered first.

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2. Propose an efficient synthesis for each of the following transformations. Pay careful attention to both the regio and stereochemical outcomes. ¡ H H racemic

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Answer 2

Question

Chapter 11, Problem 11.66P

Interpretation Introduction

(a)

Interpretation:

Give the reaction why the IUPAC name of the compound 1,3-Dimethylbutane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(b)

Interpretation:

Give the reaction why the IUPAC name of the compound 4-Methylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(c)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Diethylbutane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

If there are two different substituents, then these are listed in alphabetical order and numbering of the chain is done from the end that gives the lower number to the substituent encountered first.

Interpretation Introduction

(d)

Interpretation:

Give the reaction why the IUPAC name of the compound 2-Ethyl-3-methylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(e)

Interpretation:

Give the reaction why the IUPAC name of the compound 2-Propylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(f)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylheptane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

If there are two different substituents, then these are listed in alphabetical order and numbering of the chain is done from the end that gives the lower number to the substituent encountered first.

Interpretation Introduction

(g)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylcyclopropane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the alkanes having same substituents, numbering is done from the end that gives the lower number.

Interpretation Introduction

(h)

Interpretation:

Give the reaction why the IUPAC name of the compound 1-Ethyl-5-methylcyclohexane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

The numbering of the parent chain starts from the end that gives the lower number to the substituent encountered first.

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Answer 3

Question

Chapter 11, Problem 11.66P

Interpretation Introduction

(a)

Interpretation:

Give the reaction why the IUPAC name of the compound 1,3-Dimethylbutane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(b)

Interpretation:

Give the reaction why the IUPAC name of the compound 4-Methylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(c)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Diethylbutane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

If there are two different substituents, then these are listed in alphabetical order and numbering of the chain is done from the end that gives the lower number to the substituent encountered first.

Interpretation Introduction

(d)

Interpretation:

Give the reaction why the IUPAC name of the compound 2-Ethyl-3-methylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(e)

Interpretation:

Give the reaction why the IUPAC name of the compound 2-Propylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(f)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylheptane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

If there are two different substituents, then these are listed in alphabetical order and numbering of the chain is done from the end that gives the lower number to the substituent encountered first.

Interpretation Introduction

(g)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylcyclopropane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the alkanes having same substituents, numbering is done from the end that gives the lower number.

Interpretation Introduction

(h)

Interpretation:

Give the reaction why the IUPAC name of the compound 1-Ethyl-5-methylcyclohexane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

The numbering of the parent chain starts from the end that gives the lower number to the substituent encountered first.

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Answer 4

Question

Chapter 11, Problem 11.66P

Interpretation Introduction

(a)

Interpretation:

Give the reaction why the IUPAC name of the compound 1,3-Dimethylbutane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(b)

Interpretation:

Give the reaction why the IUPAC name of the compound 4-Methylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(c)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Diethylbutane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

If there are two different substituents, then these are listed in alphabetical order and numbering of the chain is done from the end that gives the lower number to the substituent encountered first.

Interpretation Introduction

(d)

Interpretation:

Give the reaction why the IUPAC name of the compound 2-Ethyl-3-methylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(e)

Interpretation:

Give the reaction why the IUPAC name of the compound 2-Propylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(f)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylheptane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

If there are two different substituents, then these are listed in alphabetical order and numbering of the chain is done from the end that gives the lower number to the substituent encountered first.

Interpretation Introduction

(g)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylcyclopropane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the alkanes having same substituents, numbering is done from the end that gives the lower number.

Interpretation Introduction

(h)

Interpretation:

Give the reaction why the IUPAC name of the compound 1-Ethyl-5-methylcyclohexane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

The numbering of the parent chain starts from the end that gives the lower number to the substituent encountered first.

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Answer 5

Chapter 11, Problem 11.66P

Interpretation Introduction

(a)

Interpretation:

Give the reaction why the IUPAC name of the compound 1,3-Dimethylbutane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(b)

Interpretation:

Give the reaction why the IUPAC name of the compound 4-Methylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(c)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Diethylbutane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

If there are two different substituents, then these are listed in alphabetical order and numbering of the chain is done from the end that gives the lower number to the substituent encountered first.

Interpretation Introduction

(d)

Interpretation:

Give the reaction why the IUPAC name of the compound 2-Ethyl-3-methylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(e)

Interpretation:

Give the reaction why the IUPAC name of the compound 2-Propylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Interpretation Introduction

(f)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylheptane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

If there are two different substituents, then these are listed in alphabetical order and numbering of the chain is done from the end that gives the lower number to the substituent encountered first.

Interpretation Introduction

(g)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylcyclopropane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the alkanes having same substituents, numbering is done from the end that gives the lower number.

Interpretation Introduction

(h)

Interpretation:

Give the reaction why the IUPAC name of the compound 1-Ethyl-5-methylcyclohexane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

The numbering of the parent chain starts from the end that gives the lower number to the substituent encountered first.

Answer 6

Chapter 11, Problem 11.66P

Interpretation Introduction

(a)

Interpretation:

Give the reaction why the IUPAC name of the compound 1,3-Dimethylbutane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Answer 7

Chapter 11, Problem 11.66P

Interpretation Introduction

(a)

Interpretation:

Give the reaction why the IUPAC name of the compound 1,3-Dimethylbutane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Give the reaction why the IUPAC name of the compound 4-Methylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Give the reaction why the IUPAC name of the compound 4-Methylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Diethylbutane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

If there are two different substituents, then these are listed in alphabetical order and numbering of the chain is done from the end that gives the lower number to the substituent encountered first.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Diethylbutane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

If there are two different substituents, then these are listed in alphabetical order and numbering of the chain is done from the end that gives the lower number to the substituent encountered first.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Give the reaction why the IUPAC name of the compound 2-Ethyl-3-methylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Give the reaction why the IUPAC name of the compound 2-Ethyl-3-methylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Answer 14

Interpretation Introduction

(e)

Interpretation:

Give the reaction why the IUPAC name of the compound 2-Propylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Answer 15

Interpretation Introduction

(e)

Interpretation:

Give the reaction why the IUPAC name of the compound 2-Propylpentane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

Answer 16

Interpretation Introduction

(f)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylheptane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

If there are two different substituents, then these are listed in alphabetical order and numbering of the chain is done from the end that gives the lower number to the substituent encountered first.

Answer 17

Interpretation Introduction

(f)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylheptane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

If there are two different substituents, then these are listed in alphabetical order and numbering of the chain is done from the end that gives the lower number to the substituent encountered first.

Answer 18

Interpretation Introduction

(g)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylcyclopropane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the alkanes having same substituents, numbering is done from the end that gives the lower number.

Answer 19

Interpretation Introduction

(g)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylcyclopropane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the alkanes having same substituents, numbering is done from the end that gives the lower number.

Answer 20

Interpretation Introduction

(h)

Interpretation:

Give the reaction why the IUPAC name of the compound 1-Ethyl-5-methylcyclohexane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

The numbering of the parent chain starts from the end that gives the lower number to the substituent encountered first.

Answer 21

Interpretation Introduction

(h)

Interpretation:

Give the reaction why the IUPAC name of the compound 1-Ethyl-5-methylcyclohexane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the branched alkanes, first step is to identify the longest chain of carbon atoms and it is considered as the parent chain. The name of this parent chain becomes the root name of the compound.

The numbering of the parent chain starts from the end that gives the lower number to the substituent encountered first.

Answer 22

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Ch. 11.2 - Prob. 11.1P Ch. 11.3 - Prob. 11.2P Ch. 11.3 - Prob. 11.3P Ch. 11.4 - Problem 11-4 Write the molecular formula and IUPAC...Ch. 11.6 - Problem 11-5 Write the molecular formula and IUPAC...Ch. 11.7 - Prob. 11.6P Ch. 11.8 - Prob. 11.7P Ch. 11.9 - Prob. 11.8P Ch. 11.10 - Prob. 11.9P Ch. 11 - Answer true or false. A hydrocarbon is composed...

Concept explainers

(g)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylcyclopropane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the alkanes having same substituents, numbering is done from the end that gives the lower number.

Chapter 11 Solutions

Concept explainers

(g) Interpretation: Give the reaction why the IUPAC name of the compound 2,2-Dimethylcyclopropane is incorrect and give the correct IUPAC name for it. Concept Introduction: While naming the alkanes having same substituents, numbering is done from the end that gives the lower number.

Chapter 11 Solutions

(g)

Interpretation:

Give the reaction why the IUPAC name of the compound 2,2-Dimethylcyclopropane is incorrect and give the correct IUPAC name for it.

Concept Introduction:

While naming the alkanes having same substituents, numbering is done from the end that gives the lower number.