Bundle: Chemistry For Today: General, Organic, And Biochemistry, 9th + Owlv2 With Mindtap Reader, 1 Term (6 Months) Printed Access Card
9th Edition
ISBN: 9781337580632
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Question
Chapter 11, Problem 11.64E
Interpretation Introduction
Interpretation:
The reason as to why most cycloalkanes have higher boiling points than normal
Concept introduction:
The atoms present in most of the organic compounds is
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
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The following liquid-liquid extraction is different from the one you performed in Experiment
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encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
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b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 11 Solutions
Bundle: Chemistry For Today: General, Organic, And Biochemistry, 9th + Owlv2 With Mindtap Reader, 1 Term (6 Months) Printed Access Card
Ch. 11 - Prob. 11.1ECh. 11 - Prob. 11.2ECh. 11 - Prob. 11.3ECh. 11 - Prob. 11.4ECh. 11 - Prob. 11.5ECh. 11 - Prob. 11.6ECh. 11 - Prob. 11.7ECh. 11 - Prob. 11.8ECh. 11 - Prob. 11.9ECh. 11 - Prob. 11.10E
Ch. 11 - Prob. 11.11ECh. 11 - Prob. 11.12ECh. 11 - Prob. 11.13ECh. 11 - Prob. 11.14ECh. 11 - What molecular geometry exists when a central...Ch. 11 - Compare the shapes of unhybridized p and...Ch. 11 - Use Example 11.1 and Tables 11.2 and 11.6 to...Ch. 11 - Prob. 11.18ECh. 11 - Prob. 11.19ECh. 11 - Prob. 11.20ECh. 11 - Prob. 11.21ECh. 11 - Prob. 11.22ECh. 11 - Prob. 11.23ECh. 11 - Write a condensed structural formula for the...Ch. 11 - Write a condensed structural formula for the...Ch. 11 - Write an expanded structural formula for the...Ch. 11 - Prob. 11.27ECh. 11 - Classify each of the following compounds as a...Ch. 11 - Why are different conformations of an alkane not...Ch. 11 - Which of the following pairs represent structural...Ch. 11 - Prob. 11.31ECh. 11 - Prob. 11.32ECh. 11 - Identify the following alkyl groups: a. b....Ch. 11 - Prob. 11.34ECh. 11 - Prob. 11.35ECh. 11 - Draw a condensed structural formula for each of...Ch. 11 - Prob. 11.37ECh. 11 - Prob. 11.38ECh. 11 - Prob. 11.39ECh. 11 - Prob. 11.40ECh. 11 - The following names are incorrect, according to...Ch. 11 - The following names are incorrect, according to...Ch. 11 - Prob. 11.43ECh. 11 - Write the correct IUPAC name for each of the...Ch. 11 - Write the correct IUPAC name for each of the...Ch. 11 - Draw the structural formulas corresponding to each...Ch. 11 - Prob. 11.47ECh. 11 - Which of the following pairs of cycloalkanes...Ch. 11 - Prob. 11.49ECh. 11 - Prob. 11.50ECh. 11 - Prob. 11.51ECh. 11 - Which of the following cycloalkanes could show...Ch. 11 - Prob. 11.53ECh. 11 - Using the prefix cis- or trans-, name each of the...Ch. 11 - Prob. 11.55ECh. 11 - The compound decane is a straight-chain alkane....Ch. 11 - Explain why alkanes of low molecular weight have...Ch. 11 - Suppose you have a sample of 2-methylhexane and a...Ch. 11 - Identify circle the alkanelike portions of the...Ch. 11 - Prob. 11.60ECh. 11 - Prob. 11.61ECh. 11 - Write a balanced equation for the incomplete...Ch. 11 - Prob. 11.63ECh. 11 - Prob. 11.64ECh. 11 - Prob. 11.65ECh. 11 - Prob. 11.66ECh. 11 - Prob. 11.67ECh. 11 - Prob. 11.68ECh. 11 - Would you expect a molecule of urea produced in...Ch. 11 - Prob. 11.70ECh. 11 - Prob. 11.71ECh. 11 - Prob. 11.72ECh. 11 - Prob. 11.73ECh. 11 - Prob. 11.74ECh. 11 - Prob. 11.75ECh. 11 - A semi-truck loaded with cyclohexane overturns...Ch. 11 - Prob. 11.77ECh. 11 - Oil spills along coastal shores can be disastrous...Ch. 11 - Prob. 11.79ECh. 11 - Prob. 11.80ECh. 11 - Use the generic formula for alkanes (CnH2n+2) to...Ch. 11 - Prob. 11.82ECh. 11 - Which of the following is an example of an alkane?...Ch. 11 - Prob. 11.84ECh. 11 - Prob. 11.85ECh. 11 - Prob. 11.86ECh. 11 - The deadly property of carbon monoxide, if...
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
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