Using the given retrosynthetic analysis, the synthesis method of achieving target compound has to be shown. Concept introduction: Formation of epoxide : The alkene can be converted to epoxide when alkene is treated with MCPBA (m-Chloro per benzoic acid)

Question

bre The reaction sequence shown in Scheme 5 demonstrates the synthesis of a substituted benzene derivative Q. wolsd works 2 NH2 NaNO2, HCI (apexe) 13× (1 HNO3, H2SO4 C6H5CIN2 0°C HOTE CHINO₂ N O *O₂H ( PO Q Я Scheme 5 2 bag abouoqmics to sounde odi WEIC (i) Draw the structure of intermediate O. [2 marks] to noitsmot od: tot meinedogm, noit so oft listsb ni zaupaib bas wa (ii) Draw the mechanism for the transformation of aniline N to intermediate O. Spoilage (b) [6 marks] (iii) Identify the reagent X used to convert compound O to the iodinated compound [tom E P. vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx (iv) Identify the possible structures of compound Q. [2 marks] [2 marks] [shom 2] (v) bus noires goiribbeolovo xnivollot adj to subora sidab Draw the mechanism for the transformation of intermediate P to compound Q. [5 marks] vi (vi) Account for the regiochemical outcome observed in the reaction forming compound Q. [3 marks]

Answer 1

Question

Chapter 11, Problem 11.35P

Interpretation Introduction

Interpretation:

Using the given retrosynthetic analysis, the synthesis method of achieving target compound has to be shown.

Concept introduction:

Formation of epoxide: The alkene can be converted to epoxide when alkene is treated with MCPBA (m-Chloro per benzoic acid)

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bre The reaction sequence shown in Scheme 5 demonstrates the synthesis of a substituted benzene derivative Q. wolsd works 2 NH2 NaNO2, HCI (apexe) 13× (1 HNO3, H2SO4 C6H5CIN2 0°C HOTE CHINO₂ N O *O₂H ( PO Q Я Scheme 5 2 bag abouoqmics to sounde odi WEIC (i) Draw the structure of intermediate O. [2 marks] to noitsmot od: tot meinedogm, noit so oft listsb ni zaupaib bas wa (ii) Draw the mechanism for the transformation of aniline N to intermediate O. Spoilage (b) [6 marks] (iii) Identify the reagent X used to convert compound O to the iodinated compound [tom E P. vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx (iv) Identify the possible structures of compound Q. [2 marks] [2 marks] [shom 2] (v) bus noires goiribbeolovo xnivollot adj to subora sidab Draw the mechanism for the transformation of intermediate P to compound Q. [5 marks] vi (vi) Account for the regiochemical outcome observed in the reaction forming compound Q. [3 marks]

PROBLEM 4 Solved Show how 1-butanol can be converted into the following compounds: a. PROBLEM 5+ b. d. -C= N

Which alkene is the major product of this dehydration? OH H2SO4 heat

Answer 2

Question

Chapter 11, Problem 11.35P

Interpretation Introduction

Interpretation:

Using the given retrosynthetic analysis, the synthesis method of achieving target compound has to be shown.

Concept introduction:

Formation of epoxide: The alkene can be converted to epoxide when alkene is treated with MCPBA (m-Chloro per benzoic acid)

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Answer 3

Question

Chapter 11, Problem 11.35P

Interpretation Introduction

Interpretation:

Using the given retrosynthetic analysis, the synthesis method of achieving target compound has to be shown.

Concept introduction:

Formation of epoxide: The alkene can be converted to epoxide when alkene is treated with MCPBA (m-Chloro per benzoic acid)

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Answer 4

Question

Chapter 11, Problem 11.35P

Interpretation Introduction

Interpretation:

Using the given retrosynthetic analysis, the synthesis method of achieving target compound has to be shown.

Concept introduction:

Formation of epoxide: The alkene can be converted to epoxide when alkene is treated with MCPBA (m-Chloro per benzoic acid)

Expert Solution & Answer

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Answer 5

Chapter 11, Problem 11.35P

Interpretation Introduction

Interpretation:

Using the given retrosynthetic analysis, the synthesis method of achieving target compound has to be shown.

Concept introduction:

Formation of epoxide: The alkene can be converted to epoxide when alkene is treated with MCPBA (m-Chloro per benzoic acid)

Answer 6

Chapter 11, Problem 11.35P

Interpretation Introduction

Interpretation:

Using the given retrosynthetic analysis, the synthesis method of achieving target compound has to be shown.

Concept introduction:

Formation of epoxide: The alkene can be converted to epoxide when alkene is treated with MCPBA (m-Chloro per benzoic acid)

Answer 7

Chapter 11, Problem 11.35P

Interpretation Introduction

Interpretation:

Using the given retrosynthetic analysis, the synthesis method of achieving target compound has to be shown.

Concept introduction:

Formation of epoxide: The alkene can be converted to epoxide when alkene is treated with MCPBA (m-Chloro per benzoic acid)

Answer 8

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Answer 19

Ch. 11.2 - Write IUPAC and common names for these ethers. (a)...Ch. 11.3 - Arrange these compounds in order of increasing...Ch. 11.4 - Show how you might use the Williamson ether...Ch. 11.4 - Show how ethyl hexyl ether might be prepared by a...Ch. 11.5 - Account for the fact that treatment of tert-butyl...Ch. 11.5 - Draw structural formulas for the major products of...Ch. 11.6 - Prob. 11.7P Ch. 11.8 - Draw the expected products of Sharpless...Ch. 11.9 - Prob. AQ Ch. 11.9 - Prob. BQ

Using the given retrosynthetic analysis, the synthesis method of achieving target compound has to be shown. Concept introduction: Formation of epoxide : The alkene can be converted to epoxide when alkene is treated with MCPBA (m-Chloro per benzoic acid)

Solution Summary: The author explains the synthesis method of achieving target compound using retrosynthetic analysis.

Concept explainers

Interpretation:

Using the given retrosynthetic analysis, the synthesis method of achieving target compound has to be shown.

Concept introduction:

Formation of epoxide: The alkene can be converted to epoxide when alkene is treated with MCPBA (m-Chloro per benzoic acid)

Chapter 11 Solutions

Using the given retrosynthetic analysis, the synthesis method of achieving target compound has to be shown. Concept introduction: Formation of epoxide : The alkene can be converted to epoxide when alkene is treated with MCPBA (m-Chloro per benzoic acid)

Solution Summary: The author explains the synthesis method of achieving target compound using retrosynthetic analysis.

Concept explainers

Interpretation: Using the given retrosynthetic analysis, the synthesis method of achieving target compound has to be shown. Concept introduction: Formation of epoxide: The alkene can be converted to epoxide when alkene is treated with MCPBA (m-Chloro per benzoic acid)

Chapter 11 Solutions

Interpretation:

Using the given retrosynthetic analysis, the synthesis method of achieving target compound has to be shown.

Concept introduction:

Formation of epoxide: The alkene can be converted to epoxide when alkene is treated with MCPBA (m-Chloro per benzoic acid)