Concept explainers
(a)
Interpretation:
Balanced
Concept Introduction:
If the reaction occurs in the nucleus of an atom then it is known as nuclear reaction. These reactions are not considered as ordinary
This nuclear reaction can be represented by nuclear equation. This is not a normal chemical equation. Nuclear equation considers the mass number and atomic number of the reactants and products. Unstable nucleus tends to emit radiation spontaneously. During this process the nuclide is transformed into nuclide of another element. Parent nuclide is the one which undergoes the radioactive decay. Daughter nuclide is the one that is formed from parent nuclide after radioactive decay.
The radioactive decay can take place by emission of alpha particle, beta particle or gamma ray emission. Alpha particle decay is a process in which an alpha particle is emitted. This results in the formation of nuclide of different element that has atomic number that is 2 less and mass number that is 4 less than the original nucleus. Beta particle decay is a process in which a beta particle is emitted. This produces a nuclide of different element similar to that of alpha particle decay. The mass number is same as that of parent nuclide while the atomic number increases by 1 unit. Gamma ray emission is a process in which the unstable nucleus emits gamma ray. This occurs along with alpha or beta particle emission. The gamma rays are not shown in the nuclear equation because they do not affect balancing the nuclear equation.
(a)

Answer to Problem 11.22EP
Balanced nuclear equation is,
Explanation of Solution
Given decay reaction is potassium-40 to calcium-40. The atomic number of potassium is 19. Atomic number of calcium is 20. Therefore, the nuclear equation for this decay reaction can be given as,
The sum of subscript on both sides has to be equal and the sum of superscript on both sides has to be equal. Considering this, the particle that is emitted is found to contain 0 as superscript and -1 as subscript. This means it is a beta particle. Therefore, the given decay reaction is classified as beta decay. The balanced nuclear equation can be given as shown below,
(b)
Interpretation:
Balanced nuclear equation for decay reaction of lead-204 to mercury-200 has to be written.
Concept Introduction:
If the reaction occurs in the nucleus of an atom then it is known as nuclear reaction. These reactions are not considered as ordinary chemical reactions because the electrons do not take part in reaction while the particle inside the nucleus does. Isotope and nuclide are almost similar terms. Isotopes refer to the same element that has different mass number while nuclide refers to atoms of same or different elements with specific atomic number and mass number.
This nuclear reaction can be represented by nuclear equation. This is not a normal chemical equation. Nuclear equation considers the mass number and atomic number of the reactants and products. Unstable nucleus tends to emit radiation spontaneously. During this process the nuclide is transformed into nuclide of another element. Parent nuclide is the one which undergoes the radioactive decay. Daughter nuclide is the one that is formed from parent nuclide after radioactive decay.
The radioactive decay can take place by emission of alpha particle, beta particle or gamma ray emission. Alpha particle decay is a process in which an alpha particle is emitted. This results in the formation of nuclide of different element that has atomic number that is 2 less and mass number that is 4 less than the original nucleus. Beta particle decay is a process in which a beta particle is emitted. This produces a nuclide of different element similar to that of alpha particle decay. The mass number is same as that of parent nuclide while the atomic number increases by 1 unit. Gamma ray emission is a process in which the unstable nucleus emits gamma ray. This occurs along with alpha or beta particle emission. The gamma rays are not shown in the nuclear equation because they do not affect balancing the nuclear equation.
(b)

Answer to Problem 11.22EP
Balanced nuclear equation is,
Explanation of Solution
Given decay reaction is lead-204 to mercury-200. The atomic number of lead is 82. Atomic number of mercury is 80. Therefore, the nuclear equation for this decay reaction can be given as,
The sum of subscript on both sides has to be equal and the sum of superscript on both sides has to be equal. Considering this, the particle that is emitted is found to contain 4 as superscript and 2 as subscript. This means it is an alpha particle. Therefore, the given decay reaction is classified as alpha decay. The balanced nuclear equation can be given as shown below,
(c)
Interpretation:
Balanced nuclear equation for decay reaction of U-238 to Th-234 has to be written.
Concept Introduction:
If the reaction occurs in the nucleus of an atom then it is known as nuclear reaction. These reactions are not considered as ordinary chemical reactions because the electrons do not take part in reaction while the particle inside the nucleus does. Isotope and nuclide are almost similar terms. Isotopes refer to the same element that has different mass number while nuclide refers to atoms of same or different elements with specific atomic number and mass number.
This nuclear reaction can be represented by nuclear equation. This is not a normal chemical equation. Nuclear equation considers the mass number and atomic number of the reactants and products. Unstable nucleus tends to emit radiation spontaneously. During this process the nuclide is transformed into nuclide of another element. Parent nuclide is the one which undergoes the radioactive decay. Daughter nuclide is the one that is formed from parent nuclide after radioactive decay.
The radioactive decay can take place by emission of alpha particle, beta particle or gamma ray emission. Alpha particle decay is a process in which an alpha particle is emitted. This results in the formation of nuclide of different element that has atomic number that is 2 less and mass number that is 4 less than the original nucleus. Beta particle decay is a process in which a beta particle is emitted. This produces a nuclide of different element similar to that of alpha particle decay. The mass number is same as that of parent nuclide while the atomic number increases by 1 unit. Gamma ray emission is a process in which the unstable nucleus emits gamma ray. This occurs along with alpha or beta particle emission. The gamma rays are not shown in the nuclear equation because they do not affect balancing the nuclear equation.
(c)

Answer to Problem 11.22EP
Balanced nuclear equation is,
Explanation of Solution
Given decay reaction is U-238 to Th-234. The atomic number of uranium is 92. Atomic number of thorium is 90. Therefore, the nuclear equation for this decay reaction can be given as,
The sum of subscript on both sides has to be equal and the sum of superscript on both sides has to be equal. Considering this, the particle that is emitted is found to contain 4 as superscript and 2 as subscript. This means it is an alpha particle. Therefore, the given decay reaction is classified as alpha decay. The balanced nuclear equation can be given as shown below,
(d)
Interpretation:
Balanced nuclear equation for decay reaction of Rh-104 to Pd-104 has to be written.
Concept Introduction:
If the reaction occurs in the nucleus of an atom then it is known as nuclear reaction. These reactions are not considered as ordinary chemical reactions because the electrons do not take part in reaction while the particle inside the nucleus does. Isotope and nuclide are almost similar terms. Isotopes refer to the same element that has different mass number while nuclide refers to atoms of same or different elements with specific atomic number and mass number.
This nuclear reaction can be represented by nuclear equation. This is not a normal chemical equation. Nuclear equation considers the mass number and atomic number of the reactants and products. Unstable nucleus tends to emit radiation spontaneously. During this process the nuclide is transformed into nuclide of another element. Parent nuclide is the one which undergoes the radioactive decay. Daughter nuclide is the one that is formed from parent nuclide after radioactive decay.
The radioactive decay can take place by emission of alpha particle, beta particle or gamma ray emission. Alpha particle decay is a process in which an alpha particle is emitted. This results in the formation of nuclide of different element that has atomic number that is 2 less and mass number that is 4 less than the original nucleus. Beta particle decay is a process in which a beta particle is emitted. This produces a nuclide of different element similar to that of alpha particle decay. The mass number is same as that of parent nuclide while the atomic number increases by 1 unit. Gamma ray emission is a process in which the unstable nucleus emits gamma ray. This occurs along with alpha or beta particle emission. The gamma rays are not shown in the nuclear equation because they do not affect balancing the nuclear equation.
(d)

Answer to Problem 11.22EP
Balanced nuclear equation is,
Explanation of Solution
Given decay reaction is Rh-104 to Pd-104. The atomic number of rhodium is 45. Atomic number of palladium is 46. Therefore, the nuclear equation for this decay reaction can be given as,
The sum of subscript on both sides has to be equal and the sum of superscript on both sides has to be equal. Considering this, the particle that is emitted is found to contain 0 as superscript and -1 as subscript. This means it is a beta particle. Therefore, the given decay reaction is classified as beta decay. The balanced nuclear equation can be given as shown below,
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Chapter 11 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
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- File Preview The following is a total synthesis of the pheromone of the western pine beetle. Such syntheses are interesting both because of the organic chemistry, and because of the possibility of using species specific insecticides, rather than broad band insecticides. Provide the reagents for each step. There is some chemistry from our most recent chapter in this synthesis, but other steps are review from earlier chapters. (8 points) COOEt COOEt A C COOEt COOEt COOH B OH OTS CN D E See the last homework set F for assistance on this one. H+, H₂O G OH OH The last step is just nucleophilic addition reactions, taking the ketone to an acetal, intramolecularly. But it is hard to visualize the three dimensional shape as it occurs. Frontalin, pheromone of the western pine beetlearrow_forwardFor the reaction below: 1. Draw all reasonable elimination products to the right of the arrow. 2. In the box below the reaction, redraw any product you expect to be a major product. C Major Product: Check + ◎ + X ง © Cl I F2 80 F3 I σ F4 I F5 NaOH Click and drawing F6 A 2025 McGraw Hill LLC. All Rights E F7 F8 $ # % & 2 3 4 5 6 7 8 Q W E R T Y U A S D F G H Jarrow_forwardCan I please get help with this graph. If you can show exactly where it needs to pass through.arrow_forward
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