EBK CHEMISTRY
9th Edition
ISBN: 9780100453807
Author: ZUMDAHL
Publisher: YUZU
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Question
Chapter 11, Problem 106AE
Interpretation Introduction
Interpretation:
The explanation for the stabilization of colloidal suspension and the explanation why addition of heat or adding an electrolyte makes the suspended particles to settle have to be given.
Concept introduction:
A colloidal suspension is a material is consistently suspended in a liquid. In extra terms, a colloid is a microscopically tiny substance that is equally dispersed all over another material.
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+0
Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone
required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one
molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01
number of moles= 0.400/277.15 = 0.00144 moles
2 x 0.00 144=0.00288 moves
arams of acetophenone = 0.00144 X 120.16 = 0.1739
0.1739x2=0.3469
grams of benzaldehyde = 0.00144X106.12=0.1539
0.1539x2 = 0.3069
Starting materials:
0.3469 Ox acetophenone,
0.3069 of benzaldehyde
3
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
ΘΗ
Chapter 11 Solutions
EBK CHEMISTRY
Ch. 11 - Prob. 1RQCh. 11 - Using KF as an example, write equations that refer...Ch. 11 - Prob. 3RQCh. 11 - Prob. 4RQCh. 11 - Define the terms in Raoults law. Figure 10-9...Ch. 11 - In terms of Raoults law, distinguish between an...Ch. 11 - Vapor-pressure lowering is a colligative property,...Ch. 11 - What is osmotic pressure? How is osmotic pressure...Ch. 11 - Distinguish between a strong electrolyte, a weak...Ch. 11 - Prob. 10RQ
Ch. 11 - Prob. 1ALQCh. 11 - Once again, consider Fig. 10-9. Suppose instead of...Ch. 11 - Prob. 3ALQCh. 11 - Prob. 4ALQCh. 11 - You have read that adding a solute to a solvent...Ch. 11 - You drop an ice cube (made from pure water) into a...Ch. 11 - Using the phase diagram for water and Raoults law,...Ch. 11 - You and your friend are each drinking cola from...Ch. 11 - Prob. 9ALQCh. 11 - Prob. 10ALQCh. 11 - Rubbing alcohol contains 585 g isopropanol...Ch. 11 - Prob. 12SRCh. 11 - Prob. 13SRCh. 11 - Prob. 14SRCh. 11 - Calculate the sodium ion concentration when 70.0...Ch. 11 - Write equations showing the ions present after the...Ch. 11 - Rationalize the temperature dependence of the...Ch. 11 - The weak electrolyte NH3(g) does not obey Henrys...Ch. 11 - The two beakers in the sealed container...Ch. 11 - The following plot shows the vapor pressure of...Ch. 11 - When pure methanol is mixed with water, the...Ch. 11 - Prob. 22QCh. 11 - For an acid or a base, when is the normality of a...Ch. 11 - Prob. 24QCh. 11 - Prob. 25QCh. 11 - Prob. 26QCh. 11 - Explain the terms isotonic solution, crenation,...Ch. 11 - Prob. 28QCh. 11 - Prob. 29ECh. 11 - Prob. 30ECh. 11 - Common commercial acids and bases are aqueous...Ch. 11 - In lab you need to prepare at least 100 mL of each...Ch. 11 - Prob. 33ECh. 11 - Prob. 34ECh. 11 - Prob. 35ECh. 11 - Calculate the molarity and mole fraction of...Ch. 11 - Prob. 37ECh. 11 - Prob. 38ECh. 11 - Prob. 39ECh. 11 - a. Use the following data to calculate the...Ch. 11 - Although Al(OH)3 is insoluble in water, NaOH is...Ch. 11 - Prob. 42ECh. 11 - Prob. 43ECh. 11 - Prob. 44ECh. 11 - For each of the following pairs, predict which...Ch. 11 - Which ion in each of the following pairs would you...Ch. 11 - Rationalize the trend in water solubility for the...Ch. 11 - In flushing and cleaning columns used in liquid...Ch. 11 - The solubility of nitrogen in water is 8.21 104...Ch. 11 - Calculate the solubility of O2 in water at a...Ch. 11 - Glycerin, C3H8O3, is a nonvolatile liquid. What is...Ch. 11 - The vapor pressure of a solution containing 53.6 g...Ch. 11 - The normal boiling point of diethyl ether is...Ch. 11 - At a certain temperature, the vapor pressure of...Ch. 11 - A solution is made by dissolving 25.8 g urea...Ch. 11 - A solution of sodium chloride in water has a vapor...Ch. 11 - Prob. 57ECh. 11 - A solution is prepared by mixing 0.0300 mole of...Ch. 11 - What is the composition of a methanol...Ch. 11 - Benzene and toluene form an ideal solution....Ch. 11 - Which of the following will have the lowest total...Ch. 11 - Prob. 62ECh. 11 - Match the vapor pressure diagrams with the...Ch. 11 - The vapor pressures of several solutions of...Ch. 11 - A solution is prepared by dissolving 27.0 g urea,...Ch. 11 - A 2.00-g sample of a large biomolecule was...Ch. 11 - What mass of glycerin (C3H8O3), a nonelectrolyte,...Ch. 11 - The freezing point of 1-butanol is 25.50C and Kf...Ch. 11 - Prob. 69ECh. 11 - What volume of ethylene glycol (C2H6O2), a...Ch. 11 - Reserpine is a natural product isolated from the...Ch. 11 - A solution contains 3.75 g of a nonvolatile pure...Ch. 11 - a. Calculate the freezing-point depression and...Ch. 11 - Erythrocytes are red blood cells containing...Ch. 11 - Prob. 75ECh. 11 - Prob. 76ECh. 11 - Prob. 77ECh. 11 - Prob. 78ECh. 11 - Consider the following solutions: 0.010 m Na3PO4...Ch. 11 - From the following: pure water solution of...Ch. 11 - Prob. 81ECh. 11 - Prob. 82ECh. 11 - Prob. 83ECh. 11 - Consider the following representations of an ionic...Ch. 11 - Prob. 85ECh. 11 - Prob. 86ECh. 11 - Use the following data for three aqueous solutions...Ch. 11 - The freezing-point depression of a 0.091-m...Ch. 11 - Prob. 89ECh. 11 - A 0.500-g sample of a compound is dissolved in...Ch. 11 - The solubility of benzoic acid (HC7H5O2), is 0.34...Ch. 11 - Prob. 92AECh. 11 - In Exercise 96 in Chapter 8, the pressure of CO2...Ch. 11 - Explain the following on the basis of the behavior...Ch. 11 - The term proof is defined as twice the percent by...Ch. 11 - Prob. 97AECh. 11 - Prob. 98AECh. 11 - A solution is made by mixing 50.0 g acetone...Ch. 11 - Prob. 100AECh. 11 - Thyroxine, an important hormone that controls the...Ch. 11 - Prob. 102AECh. 11 - An unknown compound contains only carbon,...Ch. 11 - Prob. 104AECh. 11 - Prob. 105AECh. 11 - Prob. 106AECh. 11 - Prob. 107AECh. 11 - Prob. 108AECh. 11 - Patients undergoing an upper gastrointestinal...Ch. 11 - Prob. 110CWPCh. 11 - The lattice energy of NaCl is 786 kJ/mol, and the...Ch. 11 - For each of the following pairs, predict which...Ch. 11 - The normal boiling point of methanol is 64.7C. A...Ch. 11 - A solution is prepared by mixing 1.000 mole of...Ch. 11 - Prob. 115CWPCh. 11 - A 4.7 102 mg sample of a protein is dissolved in...Ch. 11 - A solid consists of a mixture of NaNO3 and...Ch. 11 - The vapor pressure of pure benzene is 750.0 torr...Ch. 11 - Prob. 119CPCh. 11 - Plants that thrive in salt water must have...Ch. 11 - You make 20.0 g of a sucrose (C12H22O11) and NaCl...Ch. 11 - Prob. 122CPCh. 11 - The vapor in equilibrium with a pentane-hexane...Ch. 11 - A forensic chemist is given a white solid that is...Ch. 11 - A 1.60-g sample of a mixture of naphthalene...Ch. 11 - Prob. 126CPCh. 11 - Prob. 127CPCh. 11 - You have a solution of two volatile liquids, A and...Ch. 11 - In some regions of the southwest United States,...Ch. 11 - Creatinine, C4H7N3O, is a by-product of muscle...Ch. 11 - An aqueous solution containing 0.250 mole of Q, a...Ch. 11 - Anthraquinone contains only carbon, hydrogen, and...
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