a) Interpretation: Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated. Concept introduction: Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary. To state: Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Question

(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

Answer 1

Question

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

(III) adsorbent (b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous solution was examined. The adsorption was modelled using a modified Langmuir isotherm, yielding the following values of Kat pH = 6.5: (ii) T/K 10-10 K 280 2.505 295 1.819 310 1.364 325 1.050 Determine the enthalpy of adsorption, AadsHⓇ. If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above conditions, determine Aads Gº.

with full details solution please

Answer 2

Question

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 3

Question

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 5

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 6

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 7

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 8

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 9

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 10

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 11

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 15

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 16

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 17

Trending nowThis is a popular solution!

Answer 18

Trending nowThis is a popular solution!

Answer 19

Trending nowThis is a popular solution!

Answer 20

Trending now

Answer 21

This is a popular solution!

Answer 22

See solution

Check out sample textbook solution

Answer 23

Ch. 10.1 - Prob. 1P Ch. 10.1 - Draw structures corresponding to the following...Ch. 10.2 - Prob. 3P Ch. 10.2 - Taking the relative reactivities of 1Â°, 2Â°, and...Ch. 10.4 - Prob. 5P Ch. 10.4 - The major product of the reaction of...Ch. 10.4 - Prob. 7P Ch. 10.5 - Prob. 8P Ch. 10.6 - Prob. 9P Ch. 10.6 - How might you replace a halogen substituent by a...

Solution Summary: The author explains that alcohols react with HX to yield the corresponding alkyl halide.

Chapter 10 Solutions