a) Interpretation: The product of the reaction shown is to be predicted. Concept introduction: Alcohols gets converted into the corresponding bromides on treatment with HBr in ether solution. To predict: The product of the reaction shown.

Question

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Answer 1

Question

Chapter 10.SE, Problem 26AP

Interpretation Introduction

a)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols gets converted into the corresponding bromides on treatment with HBr in ether solution.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The product of the reaction shown is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 2

Explanation of Solution

When 1-methylcyclohexanol is treated with HBr, the OH group in it is replaced by the bromine to yield 1-chloro-1-methylcyclohexane and water as products.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 3

Conclusion

The product of the reaction shown is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 4

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols when treated with SOCl₂ yield the corresponding alkyl chlorides along with SO₂ and HCl.

To predict:

The product of the reaction in which 1-butanol reacts with SOCl₂ .

Expert Solution

Answer to Problem 26AP

The product of the reaction in which 1-butanol reacts with SOCl₂ is 1-chlorobutane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 6

Explanation of Solution

When 1-butanol reacts with SOCl₂, the OH group in is replaced by chlorine to yield 1-chlorobutane. SO₂ and HCl are obtained as other products.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 7

Conclusion

The product of the reaction in which 1-butanol reacts with SOCl₂ is 1-chlorobutane.

Interpretation Introduction

c)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Cycloalkenes on treatment with NBS in CCl₄ in the presence of light undergo bromination at the allyl position.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 9

Explanation of Solution

NBS is normally used for allylic bromination. The reaction occurs through a radical mechanism. The radical produced by the homolytic cleavage of the C-H bond in the allyl position gets delocalized with the Ï€ electrons of the double bond to yield another radical with an odd electron at the junction of the rings. The attack of bromine radical hence leads to two different products as shown.

Conclusion

The products of the reaction shown are

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 10

Interpretation Introduction

d)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols give the corresponding bromides as products on treatment with PBr₃ in ether solution.

To predict:

The product of the reaction in which cyclohexanol reacts with PBr₃.

Expert Solution

Answer to Problem 26AP

The product of the reaction in which cyclohexanol reacts with PBr₃is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 12

Explanation of Solution

When cyclohexanol is treated with PBr₃, the OH group in it is replaced by the bromine to yield bromocyclohexane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 13

Conclusion

The product of the reaction in which cyclohexanol reacts with PBr₃ is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 14

Interpretation Introduction

e)

Interpretation:

The products of the reactions shown are to be predicted.

Concept introduction:

Alkyl bromides react with Mg in ether to give Grignard reagents. Grignard reagents when treated with water yield the corresponding alkanes.

To predict:

The products of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are sec-butyl magnesium bromide (A) and n-butane (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 16

Explanation of Solution

sec-butyl bromide when reacted with Mg in ether yields sec-butyl magnesium bromide, a Grignard reagent. The sec-butyl magnesium bromide reacts with water to yield n-butane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 17

Conclusion

The products of the reaction shown are sec-butyl magnesium bromide (A) and n-butane (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 18

Interpretation Introduction

f)

Interpretation:

The products of the reaction shown are to be predicted.

Concept introduction:

Alkyl halides react with Li metal to yield alkyl lithium as product. The alkyllithium when treated with CuI yield Gilmann reagent, lithium dialkylcopper, as the product.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are N-butyllithium (A) and Lithium n-dibutyl copper (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 20

Explanation of Solution

n-Butyl bromide reacts with Li to yield n-butyl lithium and lithium bromide. The n-butyl lithium produced when reacted with CuI yields Lithium n-dibutyl copper as the product.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 21

Conclusion

The products of the reaction shown are N-butyllithium (A) and Lithium n-dibutyl

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 22

Interpretation Introduction

g)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

When alkyl halides are treated with lithium dimethyl copper, the halogens are displaced by an alkyl group and a higher alkane is produced as the product.

To predict:

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper.

Expert Solution

Answer to Problem 26AP

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper is n-pentane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 24

Explanation of Solution

When n-butyl bromide is treated with lithium dimethylcopper, the bromine is replaced by a methyl group to yield n-pentane as the product.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 25

Conclusion

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper is n-pentane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 26

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Answer 2

Question

Chapter 10.SE, Problem 26AP

Interpretation Introduction

a)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols gets converted into the corresponding bromides on treatment with HBr in ether solution.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The product of the reaction shown is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 2

Explanation of Solution

When 1-methylcyclohexanol is treated with HBr, the OH group in it is replaced by the bromine to yield 1-chloro-1-methylcyclohexane and water as products.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 3

Conclusion

The product of the reaction shown is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 4

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols when treated with SOCl₂ yield the corresponding alkyl chlorides along with SO₂ and HCl.

To predict:

The product of the reaction in which 1-butanol reacts with SOCl₂ .

Expert Solution

Answer to Problem 26AP

The product of the reaction in which 1-butanol reacts with SOCl₂ is 1-chlorobutane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 6

Explanation of Solution

When 1-butanol reacts with SOCl₂, the OH group in is replaced by chlorine to yield 1-chlorobutane. SO₂ and HCl are obtained as other products.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 7

Conclusion

The product of the reaction in which 1-butanol reacts with SOCl₂ is 1-chlorobutane.

Interpretation Introduction

c)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Cycloalkenes on treatment with NBS in CCl₄ in the presence of light undergo bromination at the allyl position.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 9

Explanation of Solution

NBS is normally used for allylic bromination. The reaction occurs through a radical mechanism. The radical produced by the homolytic cleavage of the C-H bond in the allyl position gets delocalized with the Ï€ electrons of the double bond to yield another radical with an odd electron at the junction of the rings. The attack of bromine radical hence leads to two different products as shown.

Conclusion

The products of the reaction shown are

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 10

Interpretation Introduction

d)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols give the corresponding bromides as products on treatment with PBr₃ in ether solution.

To predict:

The product of the reaction in which cyclohexanol reacts with PBr₃.

Expert Solution

Answer to Problem 26AP

The product of the reaction in which cyclohexanol reacts with PBr₃is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 12

Explanation of Solution

When cyclohexanol is treated with PBr₃, the OH group in it is replaced by the bromine to yield bromocyclohexane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 13

Conclusion

The product of the reaction in which cyclohexanol reacts with PBr₃ is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 14

Interpretation Introduction

e)

Interpretation:

The products of the reactions shown are to be predicted.

Concept introduction:

Alkyl bromides react with Mg in ether to give Grignard reagents. Grignard reagents when treated with water yield the corresponding alkanes.

To predict:

The products of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are sec-butyl magnesium bromide (A) and n-butane (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 16

Explanation of Solution

sec-butyl bromide when reacted with Mg in ether yields sec-butyl magnesium bromide, a Grignard reagent. The sec-butyl magnesium bromide reacts with water to yield n-butane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 17

Conclusion

The products of the reaction shown are sec-butyl magnesium bromide (A) and n-butane (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 18

Interpretation Introduction

f)

Interpretation:

The products of the reaction shown are to be predicted.

Concept introduction:

Alkyl halides react with Li metal to yield alkyl lithium as product. The alkyllithium when treated with CuI yield Gilmann reagent, lithium dialkylcopper, as the product.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are N-butyllithium (A) and Lithium n-dibutyl copper (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 20

Explanation of Solution

n-Butyl bromide reacts with Li to yield n-butyl lithium and lithium bromide. The n-butyl lithium produced when reacted with CuI yields Lithium n-dibutyl copper as the product.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 21

Conclusion

The products of the reaction shown are N-butyllithium (A) and Lithium n-dibutyl

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 22

Interpretation Introduction

g)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

When alkyl halides are treated with lithium dimethyl copper, the halogens are displaced by an alkyl group and a higher alkane is produced as the product.

To predict:

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper.

Expert Solution

Answer to Problem 26AP

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper is n-pentane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 24

Explanation of Solution

When n-butyl bromide is treated with lithium dimethylcopper, the bromine is replaced by a methyl group to yield n-pentane as the product.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 25

Conclusion

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper is n-pentane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 26

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Answer 3

Question

Chapter 10.SE, Problem 26AP

Interpretation Introduction

a)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols gets converted into the corresponding bromides on treatment with HBr in ether solution.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The product of the reaction shown is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 2

Explanation of Solution

When 1-methylcyclohexanol is treated with HBr, the OH group in it is replaced by the bromine to yield 1-chloro-1-methylcyclohexane and water as products.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 3

Conclusion

The product of the reaction shown is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 4

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols when treated with SOCl₂ yield the corresponding alkyl chlorides along with SO₂ and HCl.

To predict:

The product of the reaction in which 1-butanol reacts with SOCl₂ .

Expert Solution

Answer to Problem 26AP

The product of the reaction in which 1-butanol reacts with SOCl₂ is 1-chlorobutane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 6

Explanation of Solution

When 1-butanol reacts with SOCl₂, the OH group in is replaced by chlorine to yield 1-chlorobutane. SO₂ and HCl are obtained as other products.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 7

Conclusion

The product of the reaction in which 1-butanol reacts with SOCl₂ is 1-chlorobutane.

Interpretation Introduction

c)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Cycloalkenes on treatment with NBS in CCl₄ in the presence of light undergo bromination at the allyl position.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 9

Explanation of Solution

NBS is normally used for allylic bromination. The reaction occurs through a radical mechanism. The radical produced by the homolytic cleavage of the C-H bond in the allyl position gets delocalized with the Ï€ electrons of the double bond to yield another radical with an odd electron at the junction of the rings. The attack of bromine radical hence leads to two different products as shown.

Conclusion

The products of the reaction shown are

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 10

Interpretation Introduction

d)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols give the corresponding bromides as products on treatment with PBr₃ in ether solution.

To predict:

The product of the reaction in which cyclohexanol reacts with PBr₃.

Expert Solution

Answer to Problem 26AP

The product of the reaction in which cyclohexanol reacts with PBr₃is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 12

Explanation of Solution

When cyclohexanol is treated with PBr₃, the OH group in it is replaced by the bromine to yield bromocyclohexane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 13

Conclusion

The product of the reaction in which cyclohexanol reacts with PBr₃ is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 14

Interpretation Introduction

e)

Interpretation:

The products of the reactions shown are to be predicted.

Concept introduction:

Alkyl bromides react with Mg in ether to give Grignard reagents. Grignard reagents when treated with water yield the corresponding alkanes.

To predict:

The products of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are sec-butyl magnesium bromide (A) and n-butane (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 16

Explanation of Solution

sec-butyl bromide when reacted with Mg in ether yields sec-butyl magnesium bromide, a Grignard reagent. The sec-butyl magnesium bromide reacts with water to yield n-butane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 17

Conclusion

The products of the reaction shown are sec-butyl magnesium bromide (A) and n-butane (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 18

Interpretation Introduction

f)

Interpretation:

The products of the reaction shown are to be predicted.

Concept introduction:

Alkyl halides react with Li metal to yield alkyl lithium as product. The alkyllithium when treated with CuI yield Gilmann reagent, lithium dialkylcopper, as the product.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are N-butyllithium (A) and Lithium n-dibutyl copper (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 20

Explanation of Solution

n-Butyl bromide reacts with Li to yield n-butyl lithium and lithium bromide. The n-butyl lithium produced when reacted with CuI yields Lithium n-dibutyl copper as the product.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 21

Conclusion

The products of the reaction shown are N-butyllithium (A) and Lithium n-dibutyl

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 22

Interpretation Introduction

g)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

When alkyl halides are treated with lithium dimethyl copper, the halogens are displaced by an alkyl group and a higher alkane is produced as the product.

To predict:

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper.

Expert Solution

Answer to Problem 26AP

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper is n-pentane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 24

Explanation of Solution

When n-butyl bromide is treated with lithium dimethylcopper, the bromine is replaced by a methyl group to yield n-pentane as the product.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 25

Conclusion

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper is n-pentane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 26

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Answer 4

Question

Chapter 10.SE, Problem 26AP

Interpretation Introduction

a)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols gets converted into the corresponding bromides on treatment with HBr in ether solution.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The product of the reaction shown is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 2

Explanation of Solution

When 1-methylcyclohexanol is treated with HBr, the OH group in it is replaced by the bromine to yield 1-chloro-1-methylcyclohexane and water as products.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 3

Conclusion

The product of the reaction shown is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 4

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols when treated with SOCl₂ yield the corresponding alkyl chlorides along with SO₂ and HCl.

To predict:

The product of the reaction in which 1-butanol reacts with SOCl₂ .

Expert Solution

Answer to Problem 26AP

The product of the reaction in which 1-butanol reacts with SOCl₂ is 1-chlorobutane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 6

Explanation of Solution

When 1-butanol reacts with SOCl₂, the OH group in is replaced by chlorine to yield 1-chlorobutane. SO₂ and HCl are obtained as other products.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 7

Conclusion

The product of the reaction in which 1-butanol reacts with SOCl₂ is 1-chlorobutane.

Interpretation Introduction

c)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Cycloalkenes on treatment with NBS in CCl₄ in the presence of light undergo bromination at the allyl position.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 9

Explanation of Solution

NBS is normally used for allylic bromination. The reaction occurs through a radical mechanism. The radical produced by the homolytic cleavage of the C-H bond in the allyl position gets delocalized with the Ï€ electrons of the double bond to yield another radical with an odd electron at the junction of the rings. The attack of bromine radical hence leads to two different products as shown.

Conclusion

The products of the reaction shown are

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 10

Interpretation Introduction

d)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols give the corresponding bromides as products on treatment with PBr₃ in ether solution.

To predict:

The product of the reaction in which cyclohexanol reacts with PBr₃.

Expert Solution

Answer to Problem 26AP

The product of the reaction in which cyclohexanol reacts with PBr₃is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 12

Explanation of Solution

When cyclohexanol is treated with PBr₃, the OH group in it is replaced by the bromine to yield bromocyclohexane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 13

Conclusion

The product of the reaction in which cyclohexanol reacts with PBr₃ is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 14

Interpretation Introduction

e)

Interpretation:

The products of the reactions shown are to be predicted.

Concept introduction:

Alkyl bromides react with Mg in ether to give Grignard reagents. Grignard reagents when treated with water yield the corresponding alkanes.

To predict:

The products of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are sec-butyl magnesium bromide (A) and n-butane (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 16

Explanation of Solution

sec-butyl bromide when reacted with Mg in ether yields sec-butyl magnesium bromide, a Grignard reagent. The sec-butyl magnesium bromide reacts with water to yield n-butane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 17

Conclusion

The products of the reaction shown are sec-butyl magnesium bromide (A) and n-butane (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 18

Interpretation Introduction

f)

Interpretation:

The products of the reaction shown are to be predicted.

Concept introduction:

Alkyl halides react with Li metal to yield alkyl lithium as product. The alkyllithium when treated with CuI yield Gilmann reagent, lithium dialkylcopper, as the product.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are N-butyllithium (A) and Lithium n-dibutyl copper (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 20

Explanation of Solution

n-Butyl bromide reacts with Li to yield n-butyl lithium and lithium bromide. The n-butyl lithium produced when reacted with CuI yields Lithium n-dibutyl copper as the product.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 21

Conclusion

The products of the reaction shown are N-butyllithium (A) and Lithium n-dibutyl

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 22

Interpretation Introduction

g)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

When alkyl halides are treated with lithium dimethyl copper, the halogens are displaced by an alkyl group and a higher alkane is produced as the product.

To predict:

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper.

Expert Solution

Answer to Problem 26AP

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper is n-pentane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 24

Explanation of Solution

When n-butyl bromide is treated with lithium dimethylcopper, the bromine is replaced by a methyl group to yield n-pentane as the product.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 25

Conclusion

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper is n-pentane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 26

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Answer 5

Chapter 10.SE, Problem 26AP

Interpretation Introduction

a)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols gets converted into the corresponding bromides on treatment with HBr in ether solution.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The product of the reaction shown is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 2

Explanation of Solution

When 1-methylcyclohexanol is treated with HBr, the OH group in it is replaced by the bromine to yield 1-chloro-1-methylcyclohexane and water as products.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 3

Conclusion

The product of the reaction shown is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 4

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols when treated with SOCl₂ yield the corresponding alkyl chlorides along with SO₂ and HCl.

To predict:

The product of the reaction in which 1-butanol reacts with SOCl₂ .

Expert Solution

Answer to Problem 26AP

The product of the reaction in which 1-butanol reacts with SOCl₂ is 1-chlorobutane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 6

Explanation of Solution

When 1-butanol reacts with SOCl₂, the OH group in is replaced by chlorine to yield 1-chlorobutane. SO₂ and HCl are obtained as other products.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 7

Conclusion

The product of the reaction in which 1-butanol reacts with SOCl₂ is 1-chlorobutane.

Interpretation Introduction

c)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Cycloalkenes on treatment with NBS in CCl₄ in the presence of light undergo bromination at the allyl position.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 9

Explanation of Solution

NBS is normally used for allylic bromination. The reaction occurs through a radical mechanism. The radical produced by the homolytic cleavage of the C-H bond in the allyl position gets delocalized with the Ï€ electrons of the double bond to yield another radical with an odd electron at the junction of the rings. The attack of bromine radical hence leads to two different products as shown.

Conclusion

The products of the reaction shown are

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 10

Interpretation Introduction

d)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols give the corresponding bromides as products on treatment with PBr₃ in ether solution.

To predict:

The product of the reaction in which cyclohexanol reacts with PBr₃.

Expert Solution

Answer to Problem 26AP

The product of the reaction in which cyclohexanol reacts with PBr₃is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 12

Explanation of Solution

When cyclohexanol is treated with PBr₃, the OH group in it is replaced by the bromine to yield bromocyclohexane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 13

Conclusion

The product of the reaction in which cyclohexanol reacts with PBr₃ is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 14

Interpretation Introduction

e)

Interpretation:

The products of the reactions shown are to be predicted.

Concept introduction:

Alkyl bromides react with Mg in ether to give Grignard reagents. Grignard reagents when treated with water yield the corresponding alkanes.

To predict:

The products of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are sec-butyl magnesium bromide (A) and n-butane (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 16

Explanation of Solution

sec-butyl bromide when reacted with Mg in ether yields sec-butyl magnesium bromide, a Grignard reagent. The sec-butyl magnesium bromide reacts with water to yield n-butane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 17

Conclusion

The products of the reaction shown are sec-butyl magnesium bromide (A) and n-butane (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 18

Interpretation Introduction

f)

Interpretation:

The products of the reaction shown are to be predicted.

Concept introduction:

Alkyl halides react with Li metal to yield alkyl lithium as product. The alkyllithium when treated with CuI yield Gilmann reagent, lithium dialkylcopper, as the product.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are N-butyllithium (A) and Lithium n-dibutyl copper (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 20

Explanation of Solution

n-Butyl bromide reacts with Li to yield n-butyl lithium and lithium bromide. The n-butyl lithium produced when reacted with CuI yields Lithium n-dibutyl copper as the product.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 21

Conclusion

The products of the reaction shown are N-butyllithium (A) and Lithium n-dibutyl

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 22

Interpretation Introduction

g)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

When alkyl halides are treated with lithium dimethyl copper, the halogens are displaced by an alkyl group and a higher alkane is produced as the product.

To predict:

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper.

Expert Solution

Answer to Problem 26AP

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper is n-pentane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 24

Explanation of Solution

When n-butyl bromide is treated with lithium dimethylcopper, the bromine is replaced by a methyl group to yield n-pentane as the product.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 25

Conclusion

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper is n-pentane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 26

Answer 6

Chapter 10.SE, Problem 26AP

Interpretation Introduction

a)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols gets converted into the corresponding bromides on treatment with HBr in ether solution.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The product of the reaction shown is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 2

Explanation of Solution

When 1-methylcyclohexanol is treated with HBr, the OH group in it is replaced by the bromine to yield 1-chloro-1-methylcyclohexane and water as products.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 3

Conclusion

The product of the reaction shown is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 4

Answer 7

Chapter 10.SE, Problem 26AP

Interpretation Introduction

a)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols gets converted into the corresponding bromides on treatment with HBr in ether solution.

To predict:

The product of the reaction shown.

Answer 8

Expert Solution

Answer to Problem 26AP

The product of the reaction shown is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 2

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

When 1-methylcyclohexanol is treated with HBr, the OH group in it is replaced by the bromine to yield 1-chloro-1-methylcyclohexane and water as products.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 3

Answer 13

Conclusion

The product of the reaction shown is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 4

Answer 14

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols when treated with SOCl₂ yield the corresponding alkyl chlorides along with SO₂ and HCl.

To predict:

The product of the reaction in which 1-butanol reacts with SOCl₂ .

Expert Solution

Answer to Problem 26AP

The product of the reaction in which 1-butanol reacts with SOCl₂ is 1-chlorobutane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 6

Explanation of Solution

When 1-butanol reacts with SOCl₂, the OH group in is replaced by chlorine to yield 1-chlorobutane. SO₂ and HCl are obtained as other products.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 7

Conclusion

The product of the reaction in which 1-butanol reacts with SOCl₂ is 1-chlorobutane.

Answer 15

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols when treated with SOCl₂ yield the corresponding alkyl chlorides along with SO₂ and HCl.

To predict:

The product of the reaction in which 1-butanol reacts with SOCl₂ .

Answer 16

Expert Solution

Answer to Problem 26AP

The product of the reaction in which 1-butanol reacts with SOCl₂ is 1-chlorobutane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 6

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Explanation of Solution

When 1-butanol reacts with SOCl₂, the OH group in is replaced by chlorine to yield 1-chlorobutane. SO₂ and HCl are obtained as other products.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 7

Answer 21

Conclusion

The product of the reaction in which 1-butanol reacts with SOCl₂ is 1-chlorobutane.

Answer 22

Interpretation Introduction

c)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Cycloalkenes on treatment with NBS in CCl₄ in the presence of light undergo bromination at the allyl position.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 9

Explanation of Solution

NBS is normally used for allylic bromination. The reaction occurs through a radical mechanism. The radical produced by the homolytic cleavage of the C-H bond in the allyl position gets delocalized with the Ï€ electrons of the double bond to yield another radical with an odd electron at the junction of the rings. The attack of bromine radical hence leads to two different products as shown.

Conclusion

The products of the reaction shown are

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 10

Answer 23

Interpretation Introduction

c)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Cycloalkenes on treatment with NBS in CCl₄ in the presence of light undergo bromination at the allyl position.

To predict:

The product of the reaction shown.

Answer 24

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 9

Answer 25

Expert Solution

Answer 26

Expert Solution

Answer 27

Expert Solution

Answer 28

Explanation of Solution

NBS is normally used for allylic bromination. The reaction occurs through a radical mechanism. The radical produced by the homolytic cleavage of the C-H bond in the allyl position gets delocalized with the Ï€ electrons of the double bond to yield another radical with an odd electron at the junction of the rings. The attack of bromine radical hence leads to two different products as shown.

Answer 29

Conclusion

The products of the reaction shown are

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 10

Answer 30

Interpretation Introduction

d)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols give the corresponding bromides as products on treatment with PBr₃ in ether solution.

To predict:

The product of the reaction in which cyclohexanol reacts with PBr₃.

Expert Solution

Answer to Problem 26AP

The product of the reaction in which cyclohexanol reacts with PBr₃is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 12

Explanation of Solution

When cyclohexanol is treated with PBr₃, the OH group in it is replaced by the bromine to yield bromocyclohexane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 13

Conclusion

The product of the reaction in which cyclohexanol reacts with PBr₃ is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 14

Answer 31

Interpretation Introduction

d)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols give the corresponding bromides as products on treatment with PBr₃ in ether solution.

To predict:

The product of the reaction in which cyclohexanol reacts with PBr₃.

Answer 32

Expert Solution

Answer to Problem 26AP

The product of the reaction in which cyclohexanol reacts with PBr₃is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 12

Answer 33

Expert Solution

Answer 34

Expert Solution

Answer 35

Expert Solution

Answer 36

Explanation of Solution

When cyclohexanol is treated with PBr₃, the OH group in it is replaced by the bromine to yield bromocyclohexane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 13

Answer 37

Conclusion

The product of the reaction in which cyclohexanol reacts with PBr₃ is

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 14

Answer 38

Interpretation Introduction

e)

Interpretation:

The products of the reactions shown are to be predicted.

Concept introduction:

Alkyl bromides react with Mg in ether to give Grignard reagents. Grignard reagents when treated with water yield the corresponding alkanes.

To predict:

The products of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are sec-butyl magnesium bromide (A) and n-butane (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 16

Explanation of Solution

sec-butyl bromide when reacted with Mg in ether yields sec-butyl magnesium bromide, a Grignard reagent. The sec-butyl magnesium bromide reacts with water to yield n-butane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 17

Conclusion

The products of the reaction shown are sec-butyl magnesium bromide (A) and n-butane (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 18

Answer 39

Interpretation Introduction

e)

Interpretation:

The products of the reactions shown are to be predicted.

Concept introduction:

Alkyl bromides react with Mg in ether to give Grignard reagents. Grignard reagents when treated with water yield the corresponding alkanes.

To predict:

The products of the reaction shown.

Answer 40

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are sec-butyl magnesium bromide (A) and n-butane (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 16

Answer 41

Expert Solution

Answer 42

Expert Solution

Answer 43

Expert Solution

Answer 44

Explanation of Solution

sec-butyl bromide when reacted with Mg in ether yields sec-butyl magnesium bromide, a Grignard reagent. The sec-butyl magnesium bromide reacts with water to yield n-butane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 17

Answer 45

Conclusion

The products of the reaction shown are sec-butyl magnesium bromide (A) and n-butane (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 18

Answer 46

Interpretation Introduction

f)

Interpretation:

The products of the reaction shown are to be predicted.

Concept introduction:

Alkyl halides react with Li metal to yield alkyl lithium as product. The alkyllithium when treated with CuI yield Gilmann reagent, lithium dialkylcopper, as the product.

To predict:

The product of the reaction shown.

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are N-butyllithium (A) and Lithium n-dibutyl copper (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 20

Explanation of Solution

n-Butyl bromide reacts with Li to yield n-butyl lithium and lithium bromide. The n-butyl lithium produced when reacted with CuI yields Lithium n-dibutyl copper as the product.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 21

Conclusion

The products of the reaction shown are N-butyllithium (A) and Lithium n-dibutyl

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 22

Answer 47

Interpretation Introduction

f)

Interpretation:

The products of the reaction shown are to be predicted.

Concept introduction:

Alkyl halides react with Li metal to yield alkyl lithium as product. The alkyllithium when treated with CuI yield Gilmann reagent, lithium dialkylcopper, as the product.

To predict:

The product of the reaction shown.

Answer 48

Expert Solution

Answer to Problem 26AP

The products of the reaction shown are N-butyllithium (A) and Lithium n-dibutyl copper (B).

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 20

Answer 49

Expert Solution

Answer 50

Expert Solution

Answer 51

Expert Solution

Answer 52

Explanation of Solution

n-Butyl bromide reacts with Li to yield n-butyl lithium and lithium bromide. The n-butyl lithium produced when reacted with CuI yields Lithium n-dibutyl copper as the product.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 21

Answer 53

Conclusion

The products of the reaction shown are N-butyllithium (A) and Lithium n-dibutyl

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 22

Answer 54

Interpretation Introduction

g)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

When alkyl halides are treated with lithium dimethyl copper, the halogens are displaced by an alkyl group and a higher alkane is produced as the product.

To predict:

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper.

Expert Solution

Answer to Problem 26AP

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper is n-pentane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 24

Explanation of Solution

When n-butyl bromide is treated with lithium dimethylcopper, the bromine is replaced by a methyl group to yield n-pentane as the product.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 25

Conclusion

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper is n-pentane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 26

Answer 55

Interpretation Introduction

g)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

When alkyl halides are treated with lithium dimethyl copper, the halogens are displaced by an alkyl group and a higher alkane is produced as the product.

To predict:

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper.

Answer 56

Expert Solution

Answer to Problem 26AP

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper is n-pentane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 24

Answer 57

Expert Solution

Answer 58

Expert Solution

Answer 59

Expert Solution

Answer 60

Explanation of Solution

When n-butyl bromide is treated with lithium dimethylcopper, the bromine is replaced by a methyl group to yield n-pentane as the product.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 25

Answer 61

Conclusion

The product of the reaction in which n-butyl bromide reacts with lithium dimethylcopper is n-pentane.

EBK ORGANIC CHEMISTRY, Chapter 10.SE, Problem 26AP , additional homework tip 26

Answer 62

Ch. 10.1 - Prob. 1P Ch. 10.1 - Draw structures corresponding to the following...Ch. 10.2 - Prob. 3P Ch. 10.2 - Taking the relative reactivities of 1Â°, 2Â°, and...Ch. 10.4 - Prob. 5P Ch. 10.4 - The major product of the reaction of...Ch. 10.4 - Prob. 7P Ch. 10.5 - Prob. 8P Ch. 10.6 - Prob. 9P Ch. 10.6 - How might you replace a halogen substituent by a...

a) Interpretation: The product of the reaction shown is to be predicted. Concept introduction: Alcohols gets converted into the corresponding bromides on treatment with HBr in ether solution. To predict: The product of the reaction shown.

a) Interpretation: The product of the reaction shown is to be predicted. Concept introduction: Alcohols gets converted into the corresponding bromides on treatment with HBr in ether solution. To predict: The product of the reaction shown.

Answer to Problem 26AP

Explanation of Solution

b) Interpretation: The product of the reaction shown is to be predicted. Concept introduction: Alcohols when treated with SOCl2 yield the corresponding alkyl chlorides along with SO2 and HCl. To predict: The product of the reaction in which 1-butanol reacts with SOCl2 .

Answer to Problem 26AP

Explanation of Solution

c) Interpretation: The product of the reaction shown is to be predicted. Concept introduction: Cycloalkenes on treatment with NBS in CCl4 in the presence of light undergo bromination at the allyl position. To predict: The product of the reaction shown.

Answer to Problem 26AP

Explanation of Solution

d) Interpretation: The product of the reaction shown is to be predicted. Concept introduction: Alcohols give the corresponding bromides as products on treatment with PBr3 in ether solution. To predict: The product of the reaction in which cyclohexanol reacts with PBr3.

Answer to Problem 26AP

Explanation of Solution

e) Interpretation: The products of the reactions shown are to be predicted. Concept introduction: Alkyl bromides react with Mg in ether to give Grignard reagents. Grignard reagents when treated with water yield the corresponding alkanes. To predict: The products of the reaction shown.

Answer to Problem 26AP

Explanation of Solution

Answer to Problem 26AP

Explanation of Solution

Answer to Problem 26AP

Explanation of Solution

Want to see more full solutions like this?

Chapter 10 Solutions

a)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols gets converted into the corresponding bromides on treatment with HBr in ether solution.

To predict:

The product of the reaction shown.

b)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols when treated with SOCl₂ yield the corresponding alkyl chlorides along with SO₂ and HCl.

To predict:

The product of the reaction in which 1-butanol reacts with SOCl₂ .

c)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Cycloalkenes on treatment with NBS in CCl₄ in the presence of light undergo bromination at the allyl position.

To predict:

The product of the reaction shown.

d)

Interpretation:

The product of the reaction shown is to be predicted.

Concept introduction:

Alcohols give the corresponding bromides as products on treatment with PBr₃ in ether solution.

To predict:

The product of the reaction in which cyclohexanol reacts with PBr₃.

e)

Interpretation:

The products of the reactions shown are to be predicted.

Concept introduction:

Alkyl bromides react with Mg in ether to give Grignard reagents. Grignard reagents when treated with water yield the corresponding alkanes.

To predict:

The products of the reaction shown.