Chemistry: The Central Science, Books a la Carte Edition & Solutions to Red Exercises for Chemistry & Mastering Chemistry with Pearson eText -- Access Card Package
1st Edition
ISBN: 9780134024516
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Textbook Question
Chapter 10.9, Problem 10.15.2PE
The photo below shows a picture of an agate stone. Jack, who picked up the stone on the Lake Superior shoreline and polished it, insists that agate is a chemical compound. Ellen argues that it cannot be a compound. Discuss the relative merits of their positions. (Section 1.210
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Students have asked these similar questions
Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
•
Part II.
a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below:
• IR spectra
% TRANSMITTANCE
1002.5
90
80
70
60
50
40
30
20
10
0
4000
3600
3200
2800
2400
2000
1800
1600
• Information from 'HAMR
MICRONS
8 9 10
11
14 15 16
19
25
1400
WAVENUMBERS (CM-1)
1200
1000
800
600
400
peak
8 ppm
Integration
multiplicity
a
2.1
1.5 (3H)
Singlet
b
3.6
1 (2H)
singlet
с
3.8
1.5 (3H)
Singlet
d
6.8
1(2H)
doublet
7.1
1(2H)
doublet
Information from 13C-nmR
Normal carbon
29ppm
Dept 135
Dept -90
+
NO peak
NO peak
50 ppm
55 ppm
+
NO peak
114 ppm
t
126 ppm
No peak
NO peak
130 ppm
t
+
159 ppm
No peak
NO peak
207 ppm
по реак
NO peak
Could you redraw these and also explain how to solve them for me pleas
Chapter 10 Solutions
Chemistry: The Central Science, Books a la Carte Edition & Solutions to Red Exercises for Chemistry & Mastering Chemistry with Pearson eText -- Access Card Package
Ch. 10.2 - Classify each of the following as a pure substance...Ch. 10.2 - Classify each of the following as a pure substance...Ch. 10.2 - 1.15 Give the chemical symbol or name for the...Ch. 10.2 - 1.16 Give the chemical symbol or name for each of...Ch. 10.3 - A solid white substance A is heated strongly in...Ch. 10.3 - 1.18 You are hiking in the mountains and find a...Ch. 10.4 - 1.19 In the process of attempting to characterize...Ch. 10.4 - 1.20
Read the following description of the element...Ch. 10.4 - Prob. 10.5.1PECh. 10.4 - A match is lit and held under a cold piece of...
Ch. 10.4 - Which separation method is better suited for...Ch. 10.4 - Two beakers contain clear, colorless liquids. When...Ch. 10.5 - Prob. 10.7.1PECh. 10.5 - Prob. 10.7.2PECh. 10.5 - Prob. 10.8.1PECh. 10.5 - Prob. 10.8.2PECh. 10.5 - Prob. 10.9.1PECh. 10.5 - Prob. 10.9.2PECh. 10.6 - Prob. 10.10.1PECh. 10.6 - Prob. 10.10.2PECh. 10.6 - Musical instruments like trumpets and trombones...Ch. 10.6 - Consider the two spheres shown here, one made of...Ch. 10.7 - Is the separation method used in brewing a cup of...Ch. 10.7 - Identify each of the following as measurements of...Ch. 10.8 - Three spheres of equal size are composed of...Ch. 10.8 - The three targets from a rifle range shown below...Ch. 10.8 - What is the length of the pencil in the following...Ch. 10.8 - How many significant figures should be reported...Ch. 10.9 - Consider the jar of jelly beans in the photo. To...Ch. 10.9 - The photo below shows a picture of an agate stone....Ch. 10 - SO Two students deterrmne the percen.ge of lead in...Ch. 10 - 1.70
Is Om use of significant figures in ea. of...Ch. 10 - Water has a density of 0.997 g/cm3 at 25C ; ice...Ch. 10 - Prob. 3ECh. 10 - Practice Exercise 1 A biochemist who is studying...Ch. 10 - Practice Exercise 2
Write the empirical formula...Ch. 10 - Prob. 6ECh. 10 - Hydrogen sulfide is composed of two elements:...Ch. 10 - Consider an atom of "B. a. How many protons,...Ch. 10 - 2.34
a. What is the mass in amu of a carbon-12...Ch. 10 - Prob. 10ECh. 10 - You have a graduated cylinder that contains a...Ch. 10 - The density of air at ordinary atmospheric...Ch. 10 - Prob. 13ECh. 10 - Prob. 14ECh. 10 - Prob. 15ECh. 10 - 165 Classify ea. al the folbwing as a pure...Ch. 10 - Prob. 17ECh. 10 - Prob. 18ECh. 10 - Prob. 19ECh. 10 - What type of quantity (for example, length,...Ch. 10 - 1.72 Give the derived SI units for each of the...Ch. 10 - 1.73 The distance from Earth to the Moon is...Ch. 10 - 1.74 Which of the following would you characterize...Ch. 10 -
1.75 The U.S. quarter has a mass of 5.67 g and is...Ch. 10 -
1.76 In the United States, water used for...Ch. 10 -
1.77 By using estimation techniques, determine...Ch. 10 - Suppose you decide to define your own temperature...Ch. 10 -
1.79 The liquid substances mercury (density =...Ch. 10 -
1.80 Two spheres of equal volume are placed on...Ch. 10 - A 32.65-g sample of a solid is placed in a flask....Ch. 10 - A thief plans to steal a gold sphere with a radius...Ch. 10 - Automobile batteries contain sulfuric acid, which...Ch. 10 - A 40-lb container of peat moss measures 14 x 20 x...Ch. 10 - A package of aluminum foil contains 50 ft2of foil,...Ch. 10 - Prob. 35ECh. 10 -
1.88 In 2005, J. Robin Warren and Barry J....Ch. 10 -
1 89 A 25 0-cm.long cylindrical glass tube,...Ch. 10 -
1.90 Gold is alloyed (mixed) with other metals to...Ch. 10 -
1.91 Paper chromatography is a simple but...Ch. 10 -
1.93 You are assigned the task of separating a...Ch. 10 - Prob. 41ECh. 10 - Which of the following factors determines the size...Ch. 10 - Practice Exercise 2 The diameter of a cartoon atom...Ch. 10 - Practice Exercise 1 Which of these atoms has the...Ch. 10 - Practice Exercise 2
How many protons, neutrons,...Ch. 10 - Prob. 46ECh. 10 - Which is mode at 1.00 atm and 298K: CO2,,N2O,or...Ch. 10 - Practice Exercise 1 There are two stable isotopes...Ch. 10 - Practice Exercise 2
Three isotopes of silicon...Ch. 10 - Practice Exercise 2 Locate Na (sodium) and Br...Ch. 10 - Practice Exercise 1 Tetra carbon dioxide is an...Ch. 10 - Practice Exercise 2 Give the empirical formula for...Ch. 10 - Practice Exercise 1 In which of the following...Ch. 10 - Practice Exercise 2 How many protons, neutrons,...Ch. 10 - Practice Exercise 1
Although it is helpful to...Ch. 10 - Prob. 56ECh. 10 - Prob. 57ECh. 10 - Prob. 58ECh. 10 - Prob. 59ECh. 10 - Practice Exercise 1 Which of the follow-mg ox...Ch. 10 - Prob. 61ECh. 10 - Prob. 62ECh. 10 - Prob. 63ECh. 10 - Prob. 64ECh. 10 - Prob. 65ECh. 10 - Prob. 66ECh. 10 - Practice Exercise 2
Give the chemical fomi uias...Ch. 10 - Prob. 68ECh. 10 - Prob. 69ECh. 10 - The followmg diagram is a representation of 20...Ch. 10 - 2 3 Four of the boxes in the following periodic...Ch. 10 -
24 Does the following drawing represent a neutral...Ch. 10 - 2.5 Which of the following diagrams most likely...Ch. 10 - Write the chemical formula for the following...Ch. 10 - Prob. 75ECh. 10 - Prob. 76ECh. 10 - Prob. 77ECh. 10 - Prob. 78ECh. 10 - Prob. 79ECh. 10 - Prob. 80ECh. 10 - Prob. 81ECh. 10 - Prob. 82ECh. 10 - Prob. 83ECh. 10 - Prob. 84ECh. 10 - Explain the difference between effusion and...Ch. 10 - Prob. 86ECh. 10 - Prob. 87ECh. 10 - Prob. 88ECh. 10 - Prob. 89ECh. 10 - Prob. 90ECh. 10 - Prob. 91ECh. 10 - Prob. 92ECh. 10 - Prob. 93ECh. 10 - Prob. 94ECh. 10 - In Sample Exercise 10.16, we found that one mole...Ch. 10 - Prob. 96ECh. 10 - Prob. 97ECh. 10 - Prob. 98ECh. 10 - Prob. 99AECh. 10 - Prob. 100AECh. 10 - Prob. 101AECh. 10 - Prob. 102AECh. 10 - Prob. 103AECh. 10 - Prob. 104AECh. 10 - Prob. 105AECh. 10 - Prob. 106AECh. 10 - Prob. 107AECh. 10 - Prob. 108AECh. 10 - Prob. 109AECh. 10 - Prob. 110AECh. 10 - Prob. 111AECh. 10 - Prob. 112AECh. 10 - Prob. 113AECh. 10 - Prob. 114AECh. 10 - Prob. 115AECh. 10 - Prob. 116AECh. 10 - Prob. 117AECh. 10 - Prob. 118AECh. 10 - Prob. 119IECh. 10 - Prob. 120IECh. 10 - Prob. 121IECh. 10 - Prob. 122IECh. 10 - Prob. 123IECh. 10 - Prob. 124IECh. 10 - Chlorine dioxide gas (ClO2) is used as a...Ch. 10 - Natural gas is very abundant us many Middle...Ch. 10 -
[10.127] Gaseous iodine pentafluoride. IF3 can be...Ch. 10 - [10.128]A 6.53-g sample of mixture of magnesium...
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- In the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forwardNonearrow_forwardNonearrow_forward
- Nonearrow_forwardWhat spectral features allow you to differentiate the product from the starting material? Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.arrow_forwardQuestion 6 What is the major product of the following Diels-Alder reaction? ? Aldy by day of A. H о B. C. D. E. OB OD Oc OE OAarrow_forward
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