The molecular formula that exactly matches given mass value has to be identified. Concept introduction: Interpreting a mass spectrum: 1. The each m/z values is the m/z value of one the fragments to the nearest whole number. 2. The peak with the highest m/z value in the molecular ions (M + ), the fragment that results when the molecules lose an electron as result of being bombarding by the electron beam. 3. The m/z value of the molecular ion gives the molecular mass of the compound. 4. Peaks with smaller m/z values, fragment ion peak represent positively charged fragments of the molecular ion.

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Answer 1

Question

Chapter 10.5, Problem 10P

Interpretation Introduction

Interpretation:

The molecular formula that exactly matches given mass value has to be identified.

Concept introduction:

Interpreting a mass spectrum:

1. The each m/z values is the m/z value of one the fragments to the nearest whole number.

2. The peak with the highest m/z value in the molecular ions (M⁺), the fragment that results when the molecules lose an electron as result of being bombarding by the electron beam.

3. The m/z value of the molecular ion gives the molecular mass of the compound.

4. Peaks with smaller m/z values, fragment ion peak represent positively charged fragments of the molecular ion.

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If the viscosity of hydrogen gas (at 0oC and 1 atm) is 8.83x10-5 P. If we assume that the molecular sizes are equal, calculate the viscosity of a gas composed of deuterium.

Answer 2

Question

Chapter 10.5, Problem 10P

Interpretation Introduction

Interpretation:

The molecular formula that exactly matches given mass value has to be identified.

Concept introduction:

Interpreting a mass spectrum:

1. The each m/z values is the m/z value of one the fragments to the nearest whole number.

2. The peak with the highest m/z value in the molecular ions (M⁺), the fragment that results when the molecules lose an electron as result of being bombarding by the electron beam.

3. The m/z value of the molecular ion gives the molecular mass of the compound.

4. Peaks with smaller m/z values, fragment ion peak represent positively charged fragments of the molecular ion.

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Answer 3

Question

Chapter 10.5, Problem 10P

Interpretation Introduction

Interpretation:

The molecular formula that exactly matches given mass value has to be identified.

Concept introduction:

Interpreting a mass spectrum:

1. The each m/z values is the m/z value of one the fragments to the nearest whole number.

2. The peak with the highest m/z value in the molecular ions (M⁺), the fragment that results when the molecules lose an electron as result of being bombarding by the electron beam.

3. The m/z value of the molecular ion gives the molecular mass of the compound.

4. Peaks with smaller m/z values, fragment ion peak represent positively charged fragments of the molecular ion.

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Answer 4

Question

Chapter 10.5, Problem 10P

Interpretation Introduction

Interpretation:

The molecular formula that exactly matches given mass value has to be identified.

Concept introduction:

Interpreting a mass spectrum:

1. The each m/z values is the m/z value of one the fragments to the nearest whole number.

2. The peak with the highest m/z value in the molecular ions (M⁺), the fragment that results when the molecules lose an electron as result of being bombarding by the electron beam.

3. The m/z value of the molecular ion gives the molecular mass of the compound.

4. Peaks with smaller m/z values, fragment ion peak represent positively charged fragments of the molecular ion.

Expert Solution & Answer

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Answer 5

Chapter 10.5, Problem 10P

Interpretation Introduction

Interpretation:

The molecular formula that exactly matches given mass value has to be identified.

Concept introduction:

Interpreting a mass spectrum:

1. The each m/z values is the m/z value of one the fragments to the nearest whole number.

2. The peak with the highest m/z value in the molecular ions (M⁺), the fragment that results when the molecules lose an electron as result of being bombarding by the electron beam.

3. The m/z value of the molecular ion gives the molecular mass of the compound.

4. Peaks with smaller m/z values, fragment ion peak represent positively charged fragments of the molecular ion.

Answer 6

Chapter 10.5, Problem 10P

Interpretation Introduction

Interpretation:

The molecular formula that exactly matches given mass value has to be identified.

Concept introduction:

Interpreting a mass spectrum:

1. The each m/z values is the m/z value of one the fragments to the nearest whole number.

2. The peak with the highest m/z value in the molecular ions (M⁺), the fragment that results when the molecules lose an electron as result of being bombarding by the electron beam.

3. The m/z value of the molecular ion gives the molecular mass of the compound.

4. Peaks with smaller m/z values, fragment ion peak represent positively charged fragments of the molecular ion.

Answer 7

Chapter 10.5, Problem 10P

Interpretation Introduction

Interpretation:

The molecular formula that exactly matches given mass value has to be identified.

Concept introduction:

Interpreting a mass spectrum:

1. The each m/z values is the m/z value of one the fragments to the nearest whole number.

2. The peak with the highest m/z value in the molecular ions (M⁺), the fragment that results when the molecules lose an electron as result of being bombarding by the electron beam.

3. The m/z value of the molecular ion gives the molecular mass of the compound.

4. Peaks with smaller m/z values, fragment ion peak represent positively charged fragments of the molecular ion.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 10.1 - Prob. 1P Ch. 10.2 - What would distinguish the mass spectrum of...Ch. 10.2 - Prob. 3P Ch. 10.3 - Prob. 5P Ch. 10.3 - Suggest possible molecular formulas for a compound...Ch. 10.3 - Prob. 7P Ch. 10.4 - Prob. 8P Ch. 10.4 - Prob. 9P Ch. 10.5 - Prob. 10P Ch. 10.5 - Prob. 11P

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