(a) Interpretation: The structure corresponding to the given ( Z ) − 4 − ethylhept − 3 − ene is to be drawn. Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name. Rules for writing structural formula from IUPAC are: 1. First identify the word root for the given compound. 2. The suffix used in the compound like –ene. 3. Identify the position, location, and number of the substituent bonded to the carbon chain. The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Question

What is the [OH⁻] of a 1.80 M solution of pyridine (C₅H₅N, Kb = 1.70 × 10⁻⁹)?

Answer 1

Question

Chapter 10.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given (Z)−4−ethylhept−3−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given (E)−3,5,6−trimethyloct−2−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to (Z)−2−bromo−1−iodohex−1−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

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Answer 2

Question

Chapter 10.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given (Z)−4−ethylhept−3−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given (E)−3,5,6−trimethyloct−2−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to (Z)−2−bromo−1−iodohex−1−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

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Answer 3

Question

Chapter 10.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given (Z)−4−ethylhept−3−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given (E)−3,5,6−trimethyloct−2−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to (Z)−2−bromo−1−iodohex−1−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

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Answer 4

Question

Chapter 10.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given (Z)−4−ethylhept−3−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given (E)−3,5,6−trimethyloct−2−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to (Z)−2−bromo−1−iodohex−1−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

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Answer 5

Chapter 10.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given (Z)−4−ethylhept−3−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given (E)−3,5,6−trimethyloct−2−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to (Z)−2−bromo−1−iodohex−1−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Answer 6

Chapter 10.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given (Z)−4−ethylhept−3−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Answer 7

Chapter 10.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given (Z)−4−ethylhept−3−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Answer 8

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given (E)−3,5,6−trimethyloct−2−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer. The priority order depends upon the atomic number of the elements.

Answer 9

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given (E)−3,5,6−trimethyloct−2−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer. The priority order depends upon the atomic number of the elements.

Answer 10

Interpretation Introduction

(c)

Interpretation: The structure corresponding to (Z)−2−bromo−1−iodohex−1−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Answer 11

Interpretation Introduction

(c)

Interpretation: The structure corresponding to (Z)−2−bromo−1−iodohex−1−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Answer 12

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Answer 23

Ch. 10.1 - Prob. 1P Ch. 10.2 - Problem 10.2 How many degrees of unsaturation are...Ch. 10.3 - Give the IUPAC name for each alkene. abcde Ch. 10.3 - Give the IUPAC name for each polyfunctional...Ch. 10.3 - Prob. 9P Ch. 10.6 - Linolenic acidTable 10.2 and stearidonic acid are...Ch. 10.7 - Prob. 12P Ch. 10.9 - Problem 10.13 What product is formed when each...Ch. 10.9 - Prob. 14P Ch. 10.10 - Problem 10.15 Draw the products formed when each...

Solution Summary: The author explains that the systematic naming of organic compound is given by IUPAC. The structure is correctly interpreted from the name.

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