Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
3rd Edition
ISBN: 9781119320524
Author: Klein
Publisher: WILEY
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Question
Chapter 10.3, Problem 10PTS
Interpretation Introduction
Interpretation:
The mechanism for the given reaction should be identified.
Concept introduction:
Radical initiation: In these stage, radical forms under mild condition which, helps the radical reaction (net formation of radicals).
Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals)
Termination: number of free radicals decreases from the reactant is called termination (net destruction of free radicals).
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יווי
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3
2.5
2
1.5
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1.5
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2H2S(g)+3O2(g)→2SO2(g)+2H2O(g)
A 1.2mol sample of H2S(g) is combined with excess O2(g), and the reaction goes to completion.
Question
Which of the following predicts the theoretical yield of SO2(g) from the reaction?
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1.2 g
Answer A: 1.2 grams
A
41 g
Answer B: 41 grams
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D
Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Chapter 10 Solutions
Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
Ch. 10.1 - Prob. 1CCCh. 10.1 - Prob. 1LTSCh. 10.1 - Prob. 2PTSCh. 10.1 - Prob. 3PTSCh. 10.1 - Prob. 4ATSCh. 10.1 - Prob. 2LTSCh. 10.1 - Prob. 5PTSCh. 10.1 - Prob. 6PTSCh. 10.1 - Prob. 7ATSCh. 10.2 - Prob. 3LTS
Ch. 10.2 - Prob. 8PTSCh. 10.2 - Prob. 9ATSCh. 10.3 - Prob. 4LTSCh. 10.3 - Prob. 10PTSCh. 10.3 - Prob. 11ATSCh. 10.5 - Prob. 5LTSCh. 10.5 - Prob. 12PTSCh. 10.5 - Prob. 13ATSCh. 10.6 - Prob. 6LTSCh. 10.6 - Prob. 14PTSCh. 10.6 - Prob. 15ATSCh. 10.7 - Prob. 7LTSCh. 10.7 - Prob. 16PTSCh. 10.7 - Prob. 17PTSCh. 10.7 - Prob. 18ATSCh. 10.8 - Prob. 19CCCh. 10.9 - Prob. 20CCCh. 10.10 - Prob. 8LTSCh. 10.10 - Prob. 21PTSCh. 10.10 - Prob. 22ATSCh. 10 - Prob. 23PPCh. 10 - Prob. 24PPCh. 10 - Prob. 25PPCh. 10 - Prob. 26PPCh. 10 - Prob. 27PPCh. 10 - Prob. 28PPCh. 10 - Prob. 29PPCh. 10 - Prob. 30PPCh. 10 - Prob. 31PPCh. 10 - Prob. 32PPCh. 10 - Prob. 33PPCh. 10 - Prob. 34PPCh. 10 - Prob. 35PPCh. 10 - Prob. 36PPCh. 10 - Prob. 37PPCh. 10 - Prob. 38PPCh. 10 - Prob. 39PPCh. 10 - Prob. 40PPCh. 10 - Prob. 41IPCh. 10 - Prob. 42IPCh. 10 - Prob. 43IPCh. 10 - Prob. 44IPCh. 10 - Prob. 45IPCh. 10 - Prob. 46IPCh. 10 - Prob. 47IPCh. 10 - Prob. 48IPCh. 10 - Prob. 49IPCh. 10 - Prob. 50IPCh. 10 - Prob. 51IPCh. 10 - Prob. 52IPCh. 10 - Prob. 53IPCh. 10 - Prob. 54IPCh. 10 - Prob. 55IPCh. 10 - Prob. 56IPCh. 10 - Prob. 57IPCh. 10 - Prob. 58CPCh. 10 - Prob. 59CPCh. 10 - As seen in this chapter, hydrocarbons typically do...Ch. 10 - Prob. 61CP
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