Introductory Chemistry: A Foundation
8th Edition
ISBN: 9781285199030
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 10, Problem 5QAP
Interpretation Introduction
Interpretation:
The state function should be defined with an example.
Concept Introduction:
In
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Examine the reaction below. Highlight all bonds that have broken in the reactant.
Br H
H₂C-C-
-H
5
H-C-H
H-C-H
BIE
们
OH
H H
H₂C-C=
H-C-H
H-C-H
Classify each of the following as either a substitution, elimination, or addition reaction.
CH3
CH3
CH2=CH₂
CH2=C-CH2-OH + Br₂
Br-CH2-C
-CH₂-OH
Br
CH,CH3
CH3-C-CH-CH2-CH3
он
° CH₂
HO
C-C-CH3 + NH3
CH₂
он
CH3-CH-O-CH3
O-CH3
CH3-C-CH3 + H₂O
O-CH3
CH3CH₂
H
+ H₂O
CH3-C=C-CH2-CH3
• CHI
Δ
Å CH
CH3
H+
CH3
C-H + HO-CH3
H"
Q-CH₂
CH3-C-CH3 + HO-CH3
OH
O substitution
O elimination
addition
substitution
O elimination
addition
O substitution
elimination
addition
O substitution
O elimination
addition
substitution
O elimination
00
addition
Search 5:45 PM Sun Dec 15
Quiz 9
...
ล 25%0
A
Done
Quiz #9 =
Name:
Draw the major products of the following. Show Stereochemistry when applicable:
1. OsO4
A
2. NaHSO 3, H 20
Cl₂
➤ C
H2, Pd/C
E
HBr
1. Hg(OAc) 2, H₂O
2. NaBH 4
Ꭰ
KI, H3PO4
F
KMnO4, H3O+
KMnO4, H2O
G
H
HBr
Br2
J
CH2N2
➤
K
CH2I2, Zn(Cu)
Cl2, CH3OH
C
1. 03
2. Zn, H3O+
HCI
1. BH 3
N
M
2. NaOH, H 202
KMnO4, NaOH
H₂O
P
Br2, H2O
R
1. BH 3
2. NaOH, H 202
Cl2, CH3CH2OH T
Chapter 10 Solutions
Introductory Chemistry: A Foundation
Ch. 10.1 - at if energy were not conserved? How would this...Ch. 10.4 - u are calculating in a chemistry problem. What if...Ch. 10.5 - ercise 10.1 How many calories of energy correspond...Ch. 10.5 - ercise 10.2 Calculate the joules of energy...Ch. 10.5 - ercise 10.3 A 5.63-g sample of solid gold is...Ch. 10.5 - ercise 10.4 A 2.8-g sample of pure metal requires...Ch. 10.6 - Prob. 10.5SCCh. 10.7 - at if Hess’s law were not true? What are some...Ch. 10.7 - Prob. 10.6SCCh. 10.9 - Prob. 1CT
Ch. 10.10 - at if the first law of thermodynamics was true,...Ch. 10 - Prob. 1ALQCh. 10 - friend of yours reads that the process of water...Ch. 10 - ou place hot metal into a beaker of cold water. ol...Ch. 10 - Prob. 4ALQCh. 10 - Prob. 5ALQCh. 10 - xplain why aluminum cans make good storage...Ch. 10 - n Section 10.7, two characteristics of enthalpy...Ch. 10 - Prob. 8ALQCh. 10 - hat is meant by the term driving forces? Why are...Ch. 10 - Prob. 10ALQCh. 10 - Explain in your own words what is meant by the...Ch. 10 - Prob. 12ALQCh. 10 - What if energy was not conserved? How would this...Ch. 10 - The internal energy of a system is said to be the...Ch. 10 - Hydrogen gas and oxygen gas react violently to...Ch. 10 - Consider four 100.0-g samples of water, each in a...Ch. 10 - For each of the following situations ac. use the...Ch. 10 - Prob. 18ALQCh. 10 - Does the entropy of the system increase or...Ch. 10 - Prob. 20ALQCh. 10 - Prob. 1QAPCh. 10 - Prob. 2QAPCh. 10 - Prob. 3QAPCh. 10 - Prob. 4QAPCh. 10 - Prob. 5QAPCh. 10 - n Fig. 10.1, what kind of energy does ball A...Ch. 10 - Prob. 7QAPCh. 10 - f you spilled a cup of freshly brewed hot tea on...Ch. 10 - Prob. 9QAPCh. 10 - Prob. 10QAPCh. 10 - In studying heat flows for chemical processes,...Ch. 10 - When a chemical system evolves energy, where does...Ch. 10 - The combustion of methane, is an exothermic...Ch. 10 - Are the following processes exothermic or...Ch. 10 - What do we mean by thermodynamics? What is the...Ch. 10 - Prob. 16QAPCh. 10 - Calculate A£ for each of the following cases q =...Ch. 10 - If q for a process is a positive number, then the...Ch. 10 - For an endothermic process, q will have a...Ch. 10 - A system releases 125 kJ of heat and 104 kJ of...Ch. 10 - Prob. 21QAPCh. 10 - Prob. 22QAPCh. 10 - If 8.40 kJ of heat is needed to raise the...Ch. 10 - If it takes 654 J of energy to warm a 5.51-g...Ch. 10 - Prob. 25QAPCh. 10 - Prob. 26QAPCh. 10 - Covert the following numbers of kilojoules into...Ch. 10 - Prob. 28QAPCh. 10 - Prob. 29QAPCh. 10 - Prob. 30QAPCh. 10 - .5 kJ of heat is applied to a 1012-g block of...Ch. 10 - What quantity of heat energy must have en applied...Ch. 10 - If 125 J of heat energy is applied to a block of...Ch. 10 - If 100. J of heat energy is applied to a 25-g...Ch. 10 - What quantity of heat is required to raise the...Ch. 10 - Prob. 36QAPCh. 10 - The “Chemistry in Focus” segment Nature Has Hot...Ch. 10 - In the “Chemistry in Focus” segment Firewalking:...Ch. 10 - Prob. 39QAPCh. 10 - A _________ is a device used to determine the heat...Ch. 10 - The enthalpy change for the reaction of hydrogen...Ch. 10 - For the reaction kJ per mole of formed. Calculate...Ch. 10 - Prob. 43QAPCh. 10 - When ethanol (grain alcohol, is burned in oxygen,...Ch. 10 - Prob. 45QAPCh. 10 - Prob. 46QAPCh. 10 - Prob. 47QAPCh. 10 - Prob. 48QAPCh. 10 - Prob. 49QAPCh. 10 - Prob. 50QAPCh. 10 - Prob. 51QAPCh. 10 - Prob. 52QAPCh. 10 - Prob. 53QAPCh. 10 - Prob. 54QAPCh. 10 - Prob. 55QAPCh. 10 - Prob. 56QAPCh. 10 - Prob. 57QAPCh. 10 - Prob. 58QAPCh. 10 - Prob. 59QAPCh. 10 - Prob. 60QAPCh. 10 - If a reaction occurs readily but has an...Ch. 10 - Prob. 62QAPCh. 10 - Prob. 63QAPCh. 10 - Prob. 64QAPCh. 10 - Prob. 65APCh. 10 - Calculate the enthalpy change when 1.0(1 g of...Ch. 10 - Prob. 67APCh. 10 - Calculate the amount of energy required (in...Ch. 10 - If takes 1.25 kJ of energy to heat a certain...Ch. 10 - What quantity of heat energy would have to be...Ch. 10 - The specific heat capacity of gold is 0.13 J/g °C....Ch. 10 - Calculate the amount of energy required (in...Ch. 10 - If 10. J of heat is applied to 5.0-g samples of...Ch. 10 - A 50.1)-g sample of water at 100. °C is poured...Ch. 10 - A 25.0-g sample of pure iron at 85 °C is dropped...Ch. 10 - If 7.24 kJ of heat is applied to a 952-g block of...Ch. 10 - For each of the substances listed in Table 10.1,...Ch. 10 - A system releases 213 kJ of heat and has a...Ch. 10 - Prob. 79APCh. 10 - Calculate the enthalpy change when 5.00 g of...Ch. 10 - Prob. 81APCh. 10 - Prob. 82APCh. 10 - It has been determined that the body can generate...Ch. 10 - Prob. 84APCh. 10 - Prob. 85CPCh. 10 - The specific heat capacity of graphite is 0.71 J/g...Ch. 10 - A swimming pool, 10.0 in by 4.0 m, is filled with...Ch. 10 - Prob. 88CPCh. 10 - Prob. 89CP
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- Select the stronger base: H-CEN equally basic H H H H-C-N H Select the stronger acid: Select the stronger base: Select the stronger base: H -H equally acidic о equally basic NH equally basic оarrow_forwardClassify each of the following as either a substitution, elimination, or addition reaction. CH3 CH3 CH3-CH-CH2-C-CH3 + Br₂ CH3 CH3 CH3 CH3-C-CH2-C-CH3 + HBr substitution ○ elimination Br CH3 CHI CHO CHA HO CH он Cl CH3-CH2-CH-CH2-CH3 CH₂ DBU H* - CHI CHO CH3 + H2O Ӧ CH3 CH3-CH2-CH=CH-CH3 + HCI OH Pd/C CH3 CH3-CH-CH2-C-CH3 CH3 H C-CH2-CH3 + HO-CH3 addition substitution elimination ○ addition ○ substitution ○ elimination O addition substitution O elimination addition substitution O elimination addition CH3 C-CH3 + H2 CH3 CH3-O-CH-CH2-CH3 Онarrow_forward=> (8 pts) Use retrosynthetic analysis (that is, use retrosynthetic arrows as was done in class) to suggest a synthesis route for the transformation shown below. Sear bonsarrow_forward
- d) 1. Complete the following reactions; all reactions are at room temperature. No heat is involved here. Show Major product only. Indicate the type of mechanism: SN1 or SN2. (1 pt each) a) Br + b) Br e) OH CH3DH + H20 он HCJ Zn Cl₂ OH + HCI 20 C12 + H-Brarrow_forwardWhat is the IUPAC name for the compound shown? LOH IUPAC name: BIU X2 x²arrow_forwardDon't used Ai solutionarrow_forward
- 2. Write the IUPAC name of the major product that would be obtained from the dehydration of 3,5-dimethylcyclohexanol. What is the type mechanism of the reaction (E1, E2, SN1, SN2)? Draw the detailed mechanism of the reaction. (2.5 pts) 3. In Experiment 8, You synthesized n-butyl bromide using sodium bromide, sulfuric acid and butyl alcohol. (2.5 pts) a. Write the detailed mechanism of this reaction indicating what type of mechanism is this reaction. b. What will happen to the rate of the reaction if NaCl was used instead of NaBr? c. What will be the mechanism of the reaction if t-butyl alcohol is used with NaBr in presence of sulfuric acid? Draw detailed mechanism.arrow_forwardIn each row of the table below, select the stronger acid or base, as instructed. The most acidic H atom in each acid has been highlighted. Select the stronger acid: Select the stronger acid: Select the stronger base: Select the stronger base: H H Tx NH equally acidic equally acidic H equally basic equally basicarrow_forwardPlease correct answer and don't used hand raitingarrow_forward
- Use the information in the pk, table below to determine which side of the equilibrium is favored for each of the reactions in the second table. acid pk, acid PK CHA CHÍNH, 36 CH₂SH OH 9 50 45 CH2=CH2 19 15.9 CH₂OH 15.7 10.3 .OH 10.0 4.8 он OH CH₂OH₂ -2.2 -7.2 снон, + i + OH + CH4 Equilibrium Equation CH₂OH + io OH CH3NH + CH2=CH2 CH3NH₂ + он + + H₁₂-C CH2=CH 0 O Left Favored Equal Right Favored о 0 0arrow_forwardClassify each of the following as either a substitution, elimination, or addition reaction. Br K* -OC(CH₁) + Cl₂ + HCI + C½₂ + NH3 + HBr + HOT H₂N + HO H HO substitution O elimination addition substitution ○ elimination addition substitution elimination addition O substitution O elimination O addition 000 substitution O elimination additionarrow_forwardPlease correct answer and don't used hand raitingarrow_forward
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