(a) Interpretation: The value of 504 J in cal and kJ is to be calculated. Concept introduction: Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Question

4. a) Give a suitable rationale for the following cyclization, stating the type of process involved (e.g. 9-endo-dig), clearly showing the mechanistic details at each step. H CO₂Me 1) NaOMe 2) H3O® CO₂Me

Answer 1

Question

Chapter 10, Problem 52E

Interpretation Introduction

(a)

Interpretation:

The value of 504 J in cal and kJ is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Interpretation Introduction

(b)

Interpretation:

The value of 192 cal in J and kJ is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Interpretation Introduction

(c)

Interpretation:

The value of 0.423 kJ in J and cal is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

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4. a) Give a suitable rationale for the following cyclization, stating the type of process involved (e.g. 9-endo-dig), clearly showing the mechanistic details at each step. H CO₂Me 1) NaOMe 2) H3O® CO₂Me

2. Platinum and other group 10 metals often act as solid phase hydrogenation catalysts for unsaturated hydrocarbons such as propylene, CH3CHCH2. In order for the reaction to be catalyzed the propylene molecules must first adsorb onto the surface. In order to completely cover the surface of a piece of platinum that has an area of 1.50 cm² with propylene, a total of 3.45 x 10¹7 molecules are needed. Determine the mass of the propylene molecules that have been absorbed onto the platinum surface.

Chem 141, Dr. Haefner 2. (a) Many main group oxides form acidic solutions when added to water. For example solid tetraphosphorous decaoxide reacts with water to produce phosphoric acid. Write a balanced chemical equation for this reaction. (b) Calcium phosphate reacts with silicon dioxide and carbon graphite at elevated temperatures to produce white phosphorous (P4) as a gas along with calcium silicate (Silcate ion is SiO3²-) and carbon monoxide. Write a balanced chemical equation for this reaction.

Answer 2

Question

Chapter 10, Problem 52E

Interpretation Introduction

(a)

Interpretation:

The value of 504 J in cal and kJ is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Interpretation Introduction

(b)

Interpretation:

The value of 192 cal in J and kJ is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Interpretation Introduction

(c)

Interpretation:

The value of 0.423 kJ in J and cal is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

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Answer 3

Question

Chapter 10, Problem 52E

Interpretation Introduction

(a)

Interpretation:

The value of 504 J in cal and kJ is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Interpretation Introduction

(b)

Interpretation:

The value of 192 cal in J and kJ is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Interpretation Introduction

(c)

Interpretation:

The value of 0.423 kJ in J and cal is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

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Answer 4

Question

Chapter 10, Problem 52E

Interpretation Introduction

(a)

Interpretation:

The value of 504 J in cal and kJ is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Interpretation Introduction

(b)

Interpretation:

The value of 192 cal in J and kJ is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Interpretation Introduction

(c)

Interpretation:

The value of 0.423 kJ in J and cal is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Expert Solution & Answer

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Answer 5

Chapter 10, Problem 52E

Interpretation Introduction

(a)

Interpretation:

The value of 504 J in cal and kJ is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Interpretation Introduction

(b)

Interpretation:

The value of 192 cal in J and kJ is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Interpretation Introduction

(c)

Interpretation:

The value of 0.423 kJ in J and cal is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Answer 6

Chapter 10, Problem 52E

Interpretation Introduction

(a)

Interpretation:

The value of 504 J in cal and kJ is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Answer 7

Chapter 10, Problem 52E

Interpretation Introduction

(a)

Interpretation:

The value of 504 J in cal and kJ is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The value of 192 cal in J and kJ is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The value of 192 cal in J and kJ is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The value of 0.423 kJ in J and cal is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The value of 0.423 kJ in J and cal is to be calculated.

Concept introduction:

Unit conversion is a method to a converting unit into another unit which has the same dimension. The unit conversion can be performed by dividing or multiplying a unit by a specific number. In some cases such as in the conversion of temperature units, a specific number is to be added.

Answer 12

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Answer 13

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Answer 23

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Solution Summary: The author explains how the value of 504J is to be calculated. Unit conversion is a method to converting unit into another unit with the same dimension.

Chapter 10 Solutions