Introducing Chemistry
6th Edition
ISBN: 9780134557373
Author: Tro
Publisher: PEARSON
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Chapter 10, Problem 46E
Use the Lewis model to explain why the compound that forms between hydrogen and sulfur has the formula H2S. Would you expect HS to be stable? H3S?
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It is not unexpected that the methoxyl substituent on a cyclohexane ring
prefers to adopt the equatorial conformation.
OMe
H
A G₂ = +0.6 kcal/mol
OMe
What is unexpected is that the closely related 2-methoxytetrahydropyran
prefers the axial conformation:
H
H
OMe
OMe
A Gp=-0.6 kcal/mol
Methoxy: CH3O group
Please be specific and clearly write the reason why this is observed. This effect that provides
stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of
example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO
interacting with anti-bonding MO...]
206 Pb
82
Express your answers as integers. Enter your answers separated by a comma.
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VAΣ
ΜΕ ΑΣΦ
Np, N₁ = 82,126
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Previous Answers
?
protons, neutrons
Please draw the inverted chair forms of the products for the two equilibrium reactions
shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of
the reactant (to the left of the equilibrium arrows) equals the relative energy of the product? [No
requirement to show or do calculations.]
CH3
CH3
HH
CH3
1
-CH3
Chapter 10 Solutions
Introducing Chemistry
Ch. 10 - Q1. Which pair of elements has the most similar...Ch. 10 - What is the Lewis structure for the compound that...Ch. 10 - Prob. 3SAQCh. 10 - Q4. What is the correct Lewis structure for?
a....Ch. 10 - Q5. How many electron dots are in the Lewis...Ch. 10 - Prob. 6SAQCh. 10 - What is the molecular geometry of PBr3 ? a. Bent...Ch. 10 - What is the molecular geometry of N2O ? (Nitrogen...Ch. 10 - Prob. 9SAQCh. 10 - Q10. Which molecular is polar?
a.
b.
c.
d.
Ch. 10 - Prob. 1ECh. 10 - Write the election configuration for Ne and Ar....Ch. 10 - In the Lewis model, what is an octet? What is a...Ch. 10 - 4. What is the different between ionic bonding and...Ch. 10 - Prob. 5ECh. 10 - Prob. 6ECh. 10 - 7. How are double and triple bonds physically...Ch. 10 - What is the procedure for writing a covalent Lewis...Ch. 10 - 9. How do you determine the number of electrons...Ch. 10 - How do you determine the number of electrons that...Ch. 10 - Prob. 11ECh. 10 - What are resonance structures? Why are they...Ch. 10 - Prob. 13ECh. 10 - 14. If all of the election group around a central...Ch. 10 - Prob. 15ECh. 10 - What is the difference between electron geometry...Ch. 10 - Prob. 17ECh. 10 - 18. What is the most electronegative element on...Ch. 10 - Prob. 19ECh. 10 - What is a dipole moment?Ch. 10 - Prob. 21ECh. 10 - Prob. 22ECh. 10 - Write an electron configuration for each element...Ch. 10 - 24. Write an electron configuration for each...Ch. 10 - Write the Lewis structure for each element. a. I...Ch. 10 - Write the Lewis structure for each element. a. Kr...Ch. 10 - Write a generic Lewis structure for the halogens....Ch. 10 - Write a generic Lewis structure for the alkali...Ch. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - 32. Write the Lewis structure for each ion.
a.
b....Ch. 10 - Indicate the noble gas that has the same Lewis...Ch. 10 - 34. Indicate the noble gas that has the same Lewis...Ch. 10 - Lewis structure for lonic compounds
35. Is each...Ch. 10 - Is each compound best represented by an ionic or a...Ch. 10 - Write the Lewis structure for each ionic compound....Ch. 10 - Write the Lewis structure for each ionic compound....Ch. 10 - Use the Lewis model to determine the formula for...Ch. 10 - 40. Use the Lewis model to determine the formula...Ch. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - Determine what is wrong with each ionic Lewis...Ch. 10 - Use the Lewis model to explain why each element...Ch. 10 - Use the Lewis model to explain why the compound...Ch. 10 - Write the Lewis structure for each molecule. a....Ch. 10 - 48. Write the Lewis structure for each...Ch. 10 - 49. Write the Lewis structure for each...Ch. 10 - 50. Write the Lewis structure for each...Ch. 10 - Write the Lewis structure for each molecule. a....Ch. 10 - Write the Lewis structure for each molecule. a....Ch. 10 - 53. Determine what is wrong with each Lewis...Ch. 10 - 54. Determine what is wrong with each Lewis...Ch. 10 - 55. Write the Lewis structure for each molecule or...Ch. 10 - Write the Lewis structure for each molecule or...Ch. 10 - 57. Write the Lewis structure for each ion....Ch. 10 - Prob. 58ECh. 10 - Write the Lewis structure for each molecule. These...Ch. 10 - Write the Lewis structure for each molecule. These...Ch. 10 - 61. Determine the number of electron groups around...Ch. 10 - 62. Determine the number of electron groups around...Ch. 10 - 63. Determine the number of bonding groups and the...Ch. 10 - Determine the number of bonding groups and the...Ch. 10 - 65. Determine the molecular geometry of each...Ch. 10 - Determine the molecular geometry of each molecule....Ch. 10 - ...Ch. 10 - 66. Determine the molecular geometry of each...Ch. 10 - Determine the electron and molecular geometries of...Ch. 10 - Determine the electron and molecular geometries of...Ch. 10 - 71. Determine the bond angles for each molecule in...Ch. 10 - 72. Determine the bond angles for each molecule in...Ch. 10 - Determine the electron and molecular geometry of...Ch. 10 - Determine the electron and molecular geometries of...Ch. 10 - Determine the molecular geometry of each...Ch. 10 - 76. Determine the molecular geometry of each...Ch. 10 - Refer to Figure10.2 to determine the...Ch. 10 - Refer to figure 10.2 to determine the...Ch. 10 - List these elements in order of decreasing...Ch. 10 - 80. List these elements in order of increasing...Ch. 10 - 81. Refer to figure10.2 to find the...Ch. 10 - Refer to figure 10.2 to find the electronegativity...Ch. 10 - Arrange these diatomic molecules in order of...Ch. 10 - Arrange these diatomic molecules in order of...Ch. 10 - Classify each diatomic molecule as polar or...Ch. 10 - 86. Classify each diatomic molecule as polar or...Ch. 10 - Prob. 87ECh. 10 - Prob. 88ECh. 10 - Classify each molecule as polar nonpolar. a. CS2...Ch. 10 - 90. Classify each molecule as polar or...Ch. 10 - 91. Classify each molecule as polar nonpolar.
a....Ch. 10 - Classify each molecule as polar or nonpolar. a....Ch. 10 - Prob. 93ECh. 10 - Prob. 94ECh. 10 - 95. Determine whether each compound is ionic or...Ch. 10 - Determine whether each compound is ionic or...Ch. 10 - Write the Lewis structure for OCCI2 (carbon is...Ch. 10 - Prob. 98ECh. 10 - Prob. 99ECh. 10 - Prob. 100ECh. 10 - Prob. 101ECh. 10 - 102. Consider the precipitation reaction.
Write...Ch. 10 - Prob. 103ECh. 10 - Prob. 104ECh. 10 - 105. Each compound listed contains both ionic and...Ch. 10 - Prob. 106ECh. 10 - 107. Each molecule listed contains an expanded...Ch. 10 - Prob. 108ECh. 10 - Formic acid is responsible for the sting you feel...Ch. 10 - Diazomethane has the following composition by...Ch. 10 - Free radicals are molecules that contain an odd...Ch. 10 - Prob. 112ECh. 10 - Prob. 113ECh. 10 - Prob. 114ECh. 10 - Prob. 115ECh. 10 - Prob. 116QGWCh. 10 - Draft a list stepbystep instructions for writing a...Ch. 10 - for each of the following molecules:...Ch. 10 - The VSEPR model is useful in predicting bond for...
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- 5. Please consider the Newman projection of tartaric acid drawn below as an eclipsed conformer (1). Please draw the most stable conformer and two intermediate energy conformers noting that staggered conformers are lower in energy than eclipsed forms even if the staggered conformers have gauche relationships between groups. [Draw the substituents H and OH on the front carbons and H, OH and CO₂H on the back carbons based on staggered forms. -CO₂H is larger than -OH.] OH COH ICOOH COOH COOH 1 2 COOH COOH 3 4 Staggered Staggered Staggered (most stable) Indicate the number of each conformer above (1, 2, 3 and 4) that corresponds to the relative energies below. Ref=0 Rotation 6. (60 points) a. Are compounds 1 and 2 below enantiomers, diastereomers or identical? OH OH HO HO LOH HO HO OH 2 OH OH b. Please complete the zig-zag conformation of the compound (3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes. 3.arrow_forwardThe plutonium isotope with 144 neutrons Enter the chemical symbol of the isotope.arrow_forwardThe mass ratio of sodium to fluorine in sodium fluoride is 1.21:1. A sample of sodium fluoride produced 26.1 gg of sodium upon decomposition. How much fluorine was formed?arrow_forward
- 32S 16 Enter your answers numerically separated by a comma. Np. Nn = 跖 ΟΙ ΑΣΦ Submit Request Answer ? protons, neutronsarrow_forward2. Which dimethylcyclohexane compounds shown below exhibit symmetry and therefore are not chiral and would not rotate plane polarized light. 1 CH3 CH CH3 CH3 2 3 CH3arrow_forwardDon't used hand raitingarrow_forward
- Can you please explain why the answer is structures 2 and 3? Please include a detailed explanation and show how the synthesis can be done with those two structures.arrow_forwardCan you please explain why the correct answer to this question is option 2? I am having trouble understanding how and why. Please provide a detailed explanation and a drawing of how the diene and dienophile would create the product in the question.arrow_forwardCan you please explain why the correct answer is molecules 2 and 4? Base your explanation off of the rules for aromaticity and well as the principles of the Huckel rule of aromaticity. Please give a detailed explanation of what Hucekl's rule is.arrow_forward
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