ORGANIC CHEMISTRY-ETEXT REG ACCESS
ORGANIC CHEMISTRY-ETEXT REG ACCESS
12th Edition
ISBN: 9781119308362
Author: Solomons
Publisher: WILEY
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Chapter 10, Problem 42P
Interpretation Introduction

Interpretation:

The distribution of unpaired electron density in the ethyl radical and tert-butyl radical as compared to the methyl radical is to be explained and the relative stability of the radicals is to be represented.

Concept introduction:

The chemical species that consists of unpaired electrons is called a radical. Radicals are formed by homolytic cleavage and can be positive, negative, or neutral species. They are an important part of any chemical reaction.

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
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