ORGANIC CHEMISTRY-ETEXT REG ACCESS
12th Edition
ISBN: 9781119308362
Author: Solomons
Publisher: WILEY
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Chapter 10, Problem 1PP
Interpretation Introduction
Interpretation:
The radicals, in order of theirs decreasing stability, are to be listed.
Concept introduction:
A molecule that contains at least one unpaired electron is known as a radical.
The relative stability of radicals is the same as that of carbocations.
The stability of radicals is as follows:
Expert Solution & Answer
Answer to Problem 1PP
Solution:
Explanation of Solution
The radical is a methyl radical. So, it is the least stable.
The radical is given as follows:
The carbon containing the unpaired electron is primary. Thus, the radical is a primary radical.
The radical is given as follows:
The carbon containing the unpaired electron is tertiary. Thus, the radical is a tertiary radical.
The radical is given as follows:
The carbon containing the unpaired electron is secondary. Thus, the radical is a secondary radical.
Therefore, the tertiary radical is the most stable and the methyl radical is the least stable.
Hence, the decreasing order of the stability of the radical is as follows:
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Number of signals in the 'H NMR spectrum.
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Chapter 10 Solutions
ORGANIC CHEMISTRY-ETEXT REG ACCESS
Ch. 10 - Prob. 1PPCh. 10 - Prob. 2PPCh. 10 - Practice Problem 10.3 How would the molecular ion...Ch. 10 - Prob. 4PPCh. 10 - Prob. 5PPCh. 10 - Prob. 6PPCh. 10 - Practice Problem 10.7 Chlorination reactions of...Ch. 10 - Prob. 8PPCh. 10 - Prob. 9PPCh. 10 - Prob. 10PP
Ch. 10 - Prob. 11PPCh. 10 - Practice Problem 10.12 Benzylic radicals, due to...Ch. 10 - Prob. 13PPCh. 10 - Practice Problem 10.14 Show how the following...Ch. 10 - Prob. 15PPCh. 10 - Prob. 16PPCh. 10 - Prob. 17PPCh. 10 - Prob. 18PCh. 10 - Explain the relative distribution of produces...Ch. 10 - 10.20 Which of the following compounds can be...Ch. 10 - Prob. 21PCh. 10 - Prob. 22PCh. 10 - Prob. 23PCh. 10 - Prob. 24PCh. 10 - 10.25 List in order of decreasing stability all of...Ch. 10 - Prob. 26PCh. 10 - Prob. 27PCh. 10 - Prob. 28PCh. 10 - Starting with the compound or compounds indicated...Ch. 10 - Prob. 30PCh. 10 - 10.31 Synthesize each of the following compounds...Ch. 10 - Synthesize each of die following compounds by...Ch. 10 - Prob. 33PCh. 10 - Prob. 34PCh. 10 - Prob. 36PCh. 10 - The halogen atom of an alkyl halide can be...Ch. 10 - Prob. 38PCh. 10 - Prob. 39PCh. 10 - Write a mechanism for the following reaction.Ch. 10 - 10.41 Hydrogen peroxide and ferrous sulfate react...Ch. 10 - Prob. 42PCh. 10 - If one were to try to draw the simplest Lewis...Ch. 10 - Prob. 1LGPCh. 10 - 2. (a) Propose a synthesis of 2-methoxypropene...
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