Organic Chemistry, Third Edition Binder Ready Version
Organic Chemistry, Third Edition Binder Ready Version
3rd Edition
ISBN: 9781119110453
Author: Klein
Publisher: WILEY
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Chapter 10, Problem 41IP
Interpretation Introduction

Interpretation:

The rate of the reaction should be identified.

Concept introduction:

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.

Hyperconjugation effect: hyperconjugation is the interaction of the electrons in a sigma bond (usually C–H or C–C) with an adjacent empty (or partially filled) non-bonding p-orbital, antibonding σ or π orbital, or filled π orbital, to give an extended molecular orbital that increases the stability of the system.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3
Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3
Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

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Organic Chemistry, Third Edition Binder Ready Version

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