EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
12th Edition
ISBN: 9781119233664
Author: Snyder
Publisher: VST
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Chapter 10, Problem 37P

The halogen atom of an alkyl halide can be replaced by the hydrogen atom bonded to tin in tributytin hydride ( B u 3 S n H ) . The process, called dehalogenation, is a radical reaction, and it can be initiated by AIBN (2, 2'-azobisisobutyronitrile). AIBN decomposes to form nitrogen gas and two isobutyronitrile radicals, which initiate the reaction. Write a mechanism for the reaction.

Chapter 10, Problem 37P, The halogen atom of an alkyl halide can be replaced by the hydrogen atom bonded to tin in tributytin

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
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