Organic Chemistry, 12e Study Guide/Student Solutions Manual
12th Edition
ISBN: 9781119077329
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 10, Problem 37P
The halogen atom of an
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
The compound below is treated with chlorine in the presence of light.
H₂C
CH3
H₂C
CH3
Draw the structure for the organic radical species produced by reaction of the compound with
a chlorine atom. Assume reaction occurs at the weakest C-H bond.
You do not have to consider stereochemistry.
• You do not have to explicitly draw H atoms.
Undo
The chlorination of ethane produces many by-products. One by-product that forms in small amounts is 2-chlorobutane.
Suggest a mechanism for the formation of 2-chlorobutane from the radical chlorination of ethane.
(NOTES: intermediates can only have one radical, 2-chlorobutane should be the product of your termination step, any
intermediate radical formed during the propagation phase can be used in the termination step)
Compounds containing a phenol group may work as ANTIOXIDANTS to prevent
free radical damage. This is accomplished when a free radical (or UV light)
encounters a phenol group, turning the phenol group into a radical. However,
contrary to typical radical behavior, the structure of the phenol radical can
neutralize (or quench) the unpaired electron. Specifically, the phenol structure
neutralizes (or quenches) the unpaired radical electron by doing the following:
taking the electron and
The correct name (or abbreviation) of an
example compound (discussed in the lecture videos) containing a phenol group with
antioxidant properties is:
Chapter 10 Solutions
Organic Chemistry, 12e Study Guide/Student Solutions Manual
Ch. 10 - Prob. 1PPCh. 10 - Prob. 2PPCh. 10 - Practice Problem 10.3 How would the molecular ion...Ch. 10 - Prob. 4PPCh. 10 - Prob. 5PPCh. 10 - Prob. 6PPCh. 10 - Practice Problem 10.7 Chlorination reactions of...Ch. 10 - Prob. 8PPCh. 10 - Prob. 9PPCh. 10 - Prob. 10PP
Ch. 10 - Prob. 11PPCh. 10 - Practice Problem 10.12 Benzylic radicals, due to...Ch. 10 - Prob. 13PPCh. 10 - Practice Problem 10.14 Show how the following...Ch. 10 - Prob. 15PPCh. 10 - Prob. 16PPCh. 10 - Prob. 17PPCh. 10 - Prob. 18PCh. 10 - Explain the relative distribution of produces...Ch. 10 - 10.20 Which of the following compounds can be...Ch. 10 - Prob. 21PCh. 10 - Prob. 22PCh. 10 - Prob. 23PCh. 10 - Prob. 24PCh. 10 - 10.25 List in order of decreasing stability all of...Ch. 10 - Prob. 26PCh. 10 - Prob. 27PCh. 10 - Prob. 28PCh. 10 - Starting with the compound or compounds indicated...Ch. 10 - Prob. 30PCh. 10 - 10.31 Synthesize each of the following compounds...Ch. 10 - Synthesize each of die following compounds by...Ch. 10 - Prob. 33PCh. 10 - Prob. 34PCh. 10 - Prob. 36PCh. 10 - The halogen atom of an alkyl halide can be...Ch. 10 - Prob. 38PCh. 10 - Prob. 39PCh. 10 - Write a mechanism for the following reaction.Ch. 10 - 10.41 Hydrogen peroxide and ferrous sulfate react...Ch. 10 - Prob. 42PCh. 10 - If one were to try to draw the simplest Lewis...Ch. 10 - Prob. 1LGPCh. 10 - 2. (a) Propose a synthesis of 2-methoxypropene...
Additional Science Textbook Solutions
Find more solutions based on key concepts
Categorize the following reactions as synthesis, decomposition, or exchange reactions in the forward direction:...
General, Organic, and Biological Chemistry (3rd Edition)
57. Which buffer system is the best choice to create a buffer with pH = 7.20? For the best system, calculate th...
Chemistry: A Molecular Approach (4th Edition)
Show the steps in the synthesis of the tetrapeptide in Problem 34, using Merrifields method.
Organic Chemistry (8th Edition)
Two samples of a compound containing elements A and B are decomposed. The first sample produced15 g of A and 35...
Chemistry: A Molecular Approach
39. What are the units of k for each type of reaction?
a. first-order reaction
b. second-order reaction
c...
Chemistry: Structure and Properties
2. A schedule of experiments for a laboratory indicates that the 1-bromobutane preparation is paired with the p...
The Organic Chem Lab Survival Manual: A Student's Guide to Techniques
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Alkyl halides can be reduced to alkanes by a radical reaction with tributyltin hydride, (C4H9)3SnH, in the presence of light (hv). Propose a radical chain mechanism by which the reaction might occur. The initiation step is the light-induced homolytic cleavage of the Sn-H bond to yield a tributyltin radical.arrow_forwardMm.31. Subject :- Chemistryarrow_forwardCan you show the reaction mechanism step-by-step for C₃H₈O (l) → C3H6 (g) + H2O (l) propan-1-ol → propene + water Please show the electron movement and the way in which the bonds break. Can you please also show how many bonds there are and what type they are (eg. Sigma, Pi)? Thanks.arrow_forward
- The compound below is treated with chlorine in the presence of light. CH3 CH3CHCH,CH3 Draw the structure for the organic radical species produced by reaction of the compound with a chlorine atom. Assume reaction occurs at the weakest C-H bond. • You do not have to consider stereochemistry. You do not have to explicitly draw H atoms.arrow_forward3. Why are radical reactions typically performed in the absence of oxygen?arrow_forwardConsider the following structures: CH, CH3 H;C, „NH3 H,C, CH H3C, Br H3C. CH CH3 CH3 CH3 JECE CEEJ JEEC СЕЈЕ ЕСЕ Which is a resonance contributor? ECJE Which has a net formal charge of +1? JECE Which has only one type of hydrogen? ECJE Which will form the most stable free radical? JEEC Which is an electrophile? JEECarrow_forward
- What will happen if methane is being oxidized in a very clean environment, where NO is at very low abundance, and CH300 reacts with HO₂ instead? Methyl hydroperoxide (CH3OOH) is formed Formaldehyde (CH2O) is formed radical propagation is maintained Ozone (03) is formedarrow_forwardOo.172. Subject :- Chemistryarrow_forwardFf.268.arrow_forward
- Use bond dissociation energies to estimate the amounts of energy required to producehydrogen via steam reforming (CH4 + 2 H2O CO2 + 2 H2) vs. catalytic generation from methanol(CH3OH + H2O CO2 + 3 H2). Does it make sense that steam reforming can be done at elevatedtemperatures while the methanol reaction can only effectively occur using a catalyst? If so, justifyyour answer. If not, propose a reason why catalysis of the methanol reaction is a necessity.arrow_forwardAs you might suspect, B-carotene, C,Hw precursor to vitamin A, was first isolated from carrots. Dilute solutions of B-carotene are yellow, hence its use as a food coloring. In plants, it is almost always present in combination with chlorophyll to assist in the harvesting of the energy of sunlight and to protect the plant against reactive species produced in photo- synthesis. As tree leaves die in the fall, the green of their chlorophyll molecules is replaced by the yellows and reds of carotene and carotene-related molecules. Compare the carbon skeletons of B-carotene and lycopene. What are the similarities? What are the differences? H3C. H3C CH3 CH3 CH3 H,C CH3 CH3 CH3 B-Carotenearrow_forwardPlease don't provide handwritten solution....arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chapter 4 Alkanes and Cycloalkanes Lesson 2; Author: Linda Hanson;https://www.youtube.com/watch?v=AL_CM_Btef4;License: Standard YouTube License, CC-BY
Chapter 4 Alkanes and Cycloalkanes Lesson 1; Author: Linda Hanson;https://www.youtube.com/watch?v=PPIa6EHJMJw;License: Standard Youtube License