Chemistry-Stud. Solution Guide
9th Edition
ISBN: 9781285697185
Author: ZUMDHAL
Publisher: CENGAGE L
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Textbook Question
Chapter 10, Problem 29Q
Compare and contrast the structures of the following solids.
a. CO2(s) versus H2O(s)
b. NaCl(s) versus CsCl(s); see Exercise 69 for the structures.
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Complete the following table. The only density needed is already given. Show your
calculations in a neat and easy-to-follow manner in the space below the table. All units
should be included and significant figures should be given close attention. Be sure to notice
that the amount of material should be in millimoles rather than moles, and the theoretical
mass of the product should in milligrams rather than grams.
LOCH 3
+
H2SO4
HNO 3
O=C-OCH 3
NO2
x
H₂O
F.W.
4.0 mL 1.3 M
amount
0.50 mL
in H2SO4
mg Theoretical
Theoretical
mmoles
density
1.09
Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 10 Solutions
Chemistry-Stud. Solution Guide
Ch. 10 - What are intermolecular forces? How do they differ...Ch. 10 - Define the following terms and describe how each...Ch. 10 - Compare and contrast solids, liquids, and gases.Ch. 10 - Prob. 4RQCh. 10 - What is a lattice? What is a unit cell? Describe a...Ch. 10 - What is closest packing? What is the difference...Ch. 10 - Describe, in general, the structures of ionic...Ch. 10 - Prob. 9RQCh. 10 - Prob. 10RQCh. 10 - Compare and contrast the phase diagrams of water...
Ch. 10 - It is possible to balance a paper clip on the...Ch. 10 - Consider a sealed container half-filled with...Ch. 10 - Explain the following: You add 100 mL water to a...Ch. 10 - Prob. 4ALQCh. 10 - Prob. 5ALQCh. 10 - Why do liquids have a vapor pressure? Do all...Ch. 10 - Prob. 7ALQCh. 10 - What is the vapor pressure of water at 100C? How...Ch. 10 - Prob. 9ALQCh. 10 - Prob. 10ALQCh. 10 - Prob. 11ALQCh. 10 - In the diagram below, which lines represent the...Ch. 10 - Prob. 14QCh. 10 - Atoms are assumed to touch in closest packed...Ch. 10 - Define critical temperature and critical pressure....Ch. 10 - Use the kinetic molecular theory to explain why a...Ch. 10 - Prob. 18QCh. 10 - Prob. 19QCh. 10 - Describe what is meant by a dynamic equilibrium in...Ch. 10 - Prob. 21QCh. 10 - Prob. 22QCh. 10 - Prob. 23QCh. 10 - Prob. 24QCh. 10 - When wet laundry is hung on a clothesline on a...Ch. 10 - You have three covalent compounds with three very...Ch. 10 - Prob. 28QCh. 10 - Compare and contrast the structures of the...Ch. 10 - Silicon carbide (SiC) is an extremely hard...Ch. 10 - How could you tell experimentally if TiO2 is an...Ch. 10 - A common prank on college campuses is to switch...Ch. 10 - A plot of In (Pvap) versus 1/T (K) is linear with...Ch. 10 - Prob. 34QCh. 10 - Identify the most important types of interparticle...Ch. 10 - Prob. 36ECh. 10 - Predict which substance in each of the following...Ch. 10 - Consider the compounds CI2, HCI. F2, NaF, and HF....Ch. 10 - Prob. 39ECh. 10 - Consider the following electrostatic potential...Ch. 10 - In each of the following groups of substances,...Ch. 10 - Prob. 42ECh. 10 - The shape of the meniscus of water in a glass tube...Ch. 10 - Prob. 44ECh. 10 - Hydrogen peroxide (H2O2) is a syrupy liquid with a...Ch. 10 - Carbon diselenide (CSe2) is a liquid at room...Ch. 10 - X rays from a copper X-ray tube ( = 154 pm) were...Ch. 10 - The second-order diffraction (n = 2) for a gold...Ch. 10 - A topaz crystal has an interplanar spacing (d) of...Ch. 10 - X rays of wavelength 2.63 were used to analyze a...Ch. 10 - Calcium has a cubic closest packed structure as a...Ch. 10 - Nickel has a face-centered cubic unit cell. The...Ch. 10 - A certain form of lead has a cubic closest packed...Ch. 10 - Prob. 54ECh. 10 - You are given a small bar of an unknown metal X....Ch. 10 - A metallic solid with atoms in a face-centered...Ch. 10 - Titanium metal has a body-centered cubic unit...Ch. 10 - Barium has a body-centered cubic structure. If the...Ch. 10 - The radius of gold is 144 pm, and the density is...Ch. 10 - The radius of tungsten is 137 pm and the density...Ch. 10 - What fraction of the total volume of a cubic...Ch. 10 - Iron has a density of 7.86 g/cm3 and crystallizes...Ch. 10 - Prob. 63ECh. 10 - Prob. 64ECh. 10 - Selenium is a semiconductor used in photocopying...Ch. 10 - Prob. 66ECh. 10 - Prob. 67ECh. 10 - Prob. 68ECh. 10 - The structures of some common crystalline...Ch. 10 - The unit cell for nickel arsenide is shown below....Ch. 10 - Cobalt fluoride crystallizes in a closest packed...Ch. 10 - The compounds Na2O, CdS, and ZrI4. all can be...Ch. 10 - What is the formula for the compound that...Ch. 10 - Prob. 74ECh. 10 - A certain metal fluoride crystallizes in such a...Ch. 10 - Prob. 76ECh. 10 - The unit cell of MgO is shown below l Does MgO...Ch. 10 - In solid KCl the smallest distance between the...Ch. 10 - The CsCl structure is a simple cubic array of...Ch. 10 - MnO has either the NaCI type structure or the CsCI...Ch. 10 - What type of solid will each of the following...Ch. 10 - What type of solid will each of the following...Ch. 10 - The memory metal, nitinol, is an alloy of nickel...Ch. 10 - Superalloys have been made of nickel and aluminum....Ch. 10 - Perovskite is a mineral containing calcium,...Ch. 10 - A mineral crystallizes in a cubic closest packed...Ch. 10 - Materials containing the elements Y, Ba, Cu, and O...Ch. 10 - The structures of another class of ceramic,...Ch. 10 - Plot the following data and determine Hvap for...Ch. 10 - From the following data for liquid nitric acid,...Ch. 10 - In Breckenridge, Colorado, the typical atmospheric...Ch. 10 - The temperature inside a pressure cooker is 115C....Ch. 10 - Carbon tetrachloride, CCl4, has a vapor pressure...Ch. 10 - Diethyl ether (CH3CH2OCH2CH3) was one of the first...Ch. 10 - A substance, X, has the following properties:...Ch. 10 - Use the heating-cooling curve below to answer the...Ch. 10 - The molar heat of fusion of sodium metal is 2.60...Ch. 10 - Prob. 98ECh. 10 - What quantity of energy does it take to convert...Ch. 10 - Consider a 75.0-g sample of H2O(g) at 125C. What...Ch. 10 - An ice cube tray contains enough water at 22.0C to...Ch. 10 - A 0.250-g chunk of sodium metal is cautiously...Ch. 10 - Prob. 103ECh. 10 - Prob. 104ECh. 10 - Prob. 105ECh. 10 - Prob. 106ECh. 10 - Prob. 107ECh. 10 - Consider the following data for xenon: Triple...Ch. 10 - Some of the physical properties of H2O and D2O are...Ch. 10 - Rationalize the following boiling points:Ch. 10 - Consider the following vapor pressure versus...Ch. 10 - Consider the following enthalpy changes:...Ch. 10 - Prob. 113AECh. 10 - Boron nitride (BN) exists in two forms. The first...Ch. 10 - Prob. 115AECh. 10 - Argon has a cubic closest packed structure as a...Ch. 10 - Prob. 117AECh. 10 - A 20.0-g sample of ice at 10.0C is mixed with...Ch. 10 - In regions with dry climates, evaporative coolers...Ch. 10 - Which of the following compound(s) exhibit only...Ch. 10 - Which of the following statements about...Ch. 10 - Prob. 123CWPCh. 10 - Aluminum has an atomic radius of 143 pm and forms...Ch. 10 - Pyrolusite is a mineral containing manganese ions...Ch. 10 - The structure of the compound K2O is best...Ch. 10 - Prob. 127CWPCh. 10 - Some ice cubes at 0c with a total mass of 403 g...Ch. 10 - The enthalpy of vaporization for acetone is 32.0...Ch. 10 - Prob. 130CWPCh. 10 - When I mole of benzene is vaporized at a constant...Ch. 10 - You and a friend each synthesize a compound with...Ch. 10 - Prob. 133CPCh. 10 - Prob. 134CPCh. 10 - Consider two different organic compounds, each...Ch. 10 - Rationalize the differences in physical properties...Ch. 10 - Prob. 137CPCh. 10 - Some ionic compounds contain a mixture of...Ch. 10 - Some ionic compounds contain a mixture of...Ch. 10 - Spinel is a mineral that contains 37.9% aluminum,...Ch. 10 - Mn crystallizes in the same type of cubic unit...Ch. 10 - You are asked to help set up a historical display...Ch. 10 - Some water is placed in a sealed glass container...Ch. 10 - The molar enthalpy of vaporization of water at 373...Ch. 10 - Prob. 145CPCh. 10 - Rubidium chloride has the sodium chloride...Ch. 10 - Prob. 147IPCh. 10 - A metal burns in air at 600c under high pressure...Ch. 10 - Prob. 149IPCh. 10 - General Zod has sold Lex Luthor what Zod claims to...
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