The orbital diagram (a) is correct or incorrect have to be identified Concept Introduction: Aufbau’s principle: Aufbau’s principle states that electrons are filled into atomic orbitals in the increasing order of orbital energy level. According to the Aufbau principle the available atomic orbitals with the lowest energy levels are occupied before those with higher energy levels. Figure 1 Hund’s Rule: According to Hund’s rule every orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied and all electrons in singly occupied orbitals have the same spin.

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Answer 1

Question

Chapter 10, Problem 13PE

(a)

Interpretation Introduction

Interpretation:

The orbital diagram (a) is correct or incorrect have to be identified

Concept Introduction:

Aufbau’s principle:

Aufbau’s principle states that electrons are filled into atomic orbitals in the increasing order of orbital energy level. According to the Aufbau principle the available atomic orbitals with the lowest energy levels are occupied before those with higher energy levels.

Figure 1

Hund’s Rule:

According to Hund’s rule every orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied and all electrons in singly occupied orbitals have the same spin.

(b)

Interpretation Introduction

Interpretation:

The orbital diagram (b) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The orbital diagram (c) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The orbital diagram (d) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

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Answer 2

Question

Chapter 10, Problem 13PE

(a)

Interpretation Introduction

Interpretation:

The orbital diagram (a) is correct or incorrect have to be identified

Concept Introduction:

Aufbau’s principle:

Aufbau’s principle states that electrons are filled into atomic orbitals in the increasing order of orbital energy level. According to the Aufbau principle the available atomic orbitals with the lowest energy levels are occupied before those with higher energy levels.

Figure 1

Hund’s Rule:

According to Hund’s rule every orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied and all electrons in singly occupied orbitals have the same spin.

(b)

Interpretation Introduction

Interpretation:

The orbital diagram (b) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The orbital diagram (c) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The orbital diagram (d) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

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Answer 3

Question

Chapter 10, Problem 13PE

(a)

Interpretation Introduction

Interpretation:

The orbital diagram (a) is correct or incorrect have to be identified

Concept Introduction:

Aufbau’s principle:

Aufbau’s principle states that electrons are filled into atomic orbitals in the increasing order of orbital energy level. According to the Aufbau principle the available atomic orbitals with the lowest energy levels are occupied before those with higher energy levels.

Figure 1

Hund’s Rule:

According to Hund’s rule every orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied and all electrons in singly occupied orbitals have the same spin.

(b)

Interpretation Introduction

Interpretation:

The orbital diagram (b) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The orbital diagram (c) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The orbital diagram (d) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

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Answer 4

Question

Chapter 10, Problem 13PE

(a)

Interpretation Introduction

Interpretation:

The orbital diagram (a) is correct or incorrect have to be identified

Concept Introduction:

Aufbau’s principle:

Aufbau’s principle states that electrons are filled into atomic orbitals in the increasing order of orbital energy level. According to the Aufbau principle the available atomic orbitals with the lowest energy levels are occupied before those with higher energy levels.

Figure 1

Hund’s Rule:

According to Hund’s rule every orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied and all electrons in singly occupied orbitals have the same spin.

(b)

Interpretation Introduction

Interpretation:

The orbital diagram (b) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The orbital diagram (c) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The orbital diagram (d) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

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Answer 5

Chapter 10, Problem 13PE

(a)

Interpretation Introduction

Interpretation:

The orbital diagram (a) is correct or incorrect have to be identified

Concept Introduction:

Aufbau’s principle:

Aufbau’s principle states that electrons are filled into atomic orbitals in the increasing order of orbital energy level. According to the Aufbau principle the available atomic orbitals with the lowest energy levels are occupied before those with higher energy levels.

Figure 1

Hund’s Rule:

According to Hund’s rule every orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied and all electrons in singly occupied orbitals have the same spin.

(b)

Interpretation Introduction

Interpretation:

The orbital diagram (b) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The orbital diagram (c) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The orbital diagram (d) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 10, Problem 13PE

(a)

Interpretation Introduction

Interpretation:

The orbital diagram (a) is correct or incorrect have to be identified

Concept Introduction:

Aufbau’s principle:

Aufbau’s principle states that electrons are filled into atomic orbitals in the increasing order of orbital energy level. According to the Aufbau principle the available atomic orbitals with the lowest energy levels are occupied before those with higher energy levels.

Figure 1

Hund’s Rule:

According to Hund’s rule every orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied and all electrons in singly occupied orbitals have the same spin.

Answer 7

Chapter 10, Problem 13PE

(a)

Interpretation Introduction

Interpretation:

The orbital diagram (a) is correct or incorrect have to be identified

Concept Introduction:

Aufbau’s principle:

Aufbau’s principle states that electrons are filled into atomic orbitals in the increasing order of orbital energy level. According to the Aufbau principle the available atomic orbitals with the lowest energy levels are occupied before those with higher energy levels.

Figure 1

Hund’s Rule:

According to Hund’s rule every orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied and all electrons in singly occupied orbitals have the same spin.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The orbital diagram (b) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The orbital diagram (b) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The orbital diagram (c) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The orbital diagram (c) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

Answer 12

(d)

Interpretation Introduction

Interpretation:

The orbital diagram (d) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

Answer 13

(d)

Interpretation Introduction

Interpretation:

The orbital diagram (d) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 10.1 - Prob. 10.1P Ch. 10.2 - Prob. 10.2P Ch. 10.3 - Prob. 10.3P Ch. 10.4 - Prob. 10.4P Ch. 10.5 - Prob. 10.5P Ch. 10.5 - Prob. 10.6P Ch. 10.5 - Prob. 10.7P Ch. 10 - Prob. 1RQ Ch. 10 - Prob. 2RQ Ch. 10 - Prob. 3RQ

Solution Summary: The author explains Aufbau's principle that electrons are filled into atomic orbitals in the increasing order of orbital energy level.

Concept explainers

Videos

Interpretation:

The orbital diagram (b) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

Interpretation:

The orbital diagram (c) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

Interpretation:

The orbital diagram (d) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

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Chapter 10 Solutions

Solution Summary: The author explains Aufbau's principle that electrons are filled into atomic orbitals in the increasing order of orbital energy level.

Concept explainers

Videos

Interpretation: The orbital diagram (b) is correct or incorrect have to be identified. Concept Introduction: Refer to part (a).

Interpretation: The orbital diagram (c) is correct or incorrect have to be identified. Concept Introduction: Refer to part (a).

Interpretation: The orbital diagram (d) is correct or incorrect have to be identified. Concept Introduction: Refer to part (a).

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Chapter 10 Solutions

Interpretation:

The orbital diagram (b) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

Interpretation:

The orbital diagram (c) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).

Interpretation:

The orbital diagram (d) is correct or incorrect have to be identified.

Concept Introduction:

Refer to part (a).