Atkins' Physical Chemistry 11e
11th Edition
ISBN: 9780192575135
Author: Peter Atkins; Julio de Paula; James Keeler
Publisher: Oxford University Press Academic UK
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Chapter 10, Problem 10A.2DQ
Interpretation Introduction
Interpretation:
The symmetry operations and the corresponding symmetry elements of a point group have to be stated.
Concept introduction:
The molecules are classified on the basis of the symmetry elements presents in them. These symmetry elements form a group and are known as point group. The point groups have the specific symmetry elements which is characteristic of the molecule.
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1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
ΘΗ
2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly
where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial
credit will be given. Note: You may need to draw in lone pairs before drawing the arrows.
A.
B.
H-Br
人
C
Θ
CI
H
Cl
Θ
+
Br
O
Chapter 10 Solutions
Atkins' Physical Chemistry 11e
Ch. 10 - Prob. 10B.2STCh. 10 - Prob. 10C.1STCh. 10 - Prob. 10C.2STCh. 10 - Prob. 10C.3STCh. 10 - Prob. 10A.1DQCh. 10 - Prob. 10A.2DQCh. 10 - Prob. 10A.3DQCh. 10 - Prob. 10A.4DQCh. 10 - Prob. 10A.1AECh. 10 - Prob. 10A.1BE
Ch. 10 - Prob. 10A.2AECh. 10 - Prob. 10A.2BECh. 10 - Prob. 10A.3AECh. 10 - Prob. 10A.3BECh. 10 - Prob. 10A.4AECh. 10 - Prob. 10A.4BECh. 10 - Prob. 10A.5AECh. 10 - Prob. 10A.5BECh. 10 - Prob. 10A.6AECh. 10 - Prob. 10A.6BECh. 10 - Prob. 10A.7AECh. 10 - Prob. 10A.1PCh. 10 - Prob. 10A.2PCh. 10 - Prob. 10A.3PCh. 10 - Prob. 10A.4PCh. 10 - Prob. 10A.5PCh. 10 - Prob. 10B.1DQCh. 10 - Prob. 10B.2DQCh. 10 - Prob. 10B.3DQCh. 10 - Prob. 10B.4DQCh. 10 - Prob. 10B.5DQCh. 10 - Prob. 10B.1AECh. 10 - Prob. 10B.1BECh. 10 - Prob. 10B.2AECh. 10 - Prob. 10B.2BECh. 10 - Prob. 10B.3AECh. 10 - Prob. 10B.3BECh. 10 - Prob. 10B.4AECh. 10 - Prob. 10B.4BECh. 10 - Prob. 10B.5AECh. 10 - Prob. 10B.5BECh. 10 - Prob. 10B.6AECh. 10 - Prob. 10B.6BECh. 10 - Prob. 10B.7AECh. 10 - Prob. 10B.7BECh. 10 - Prob. 10B.1PCh. 10 - Prob. 10B.2PCh. 10 - Prob. 10B.3PCh. 10 - Prob. 10B.4PCh. 10 - Prob. 10B.5PCh. 10 - Prob. 10B.6PCh. 10 - Prob. 10B.7PCh. 10 - Prob. 10B.8PCh. 10 - Prob. 10B.9PCh. 10 - Prob. 10B.10PCh. 10 - Prob. 10C.1DQCh. 10 - Prob. 10C.2DQCh. 10 - Prob. 10C.1AECh. 10 - Prob. 10C.1BECh. 10 - Prob. 10C.2AECh. 10 - Prob. 10C.2BECh. 10 - Prob. 10C.3AECh. 10 - Prob. 10C.3BECh. 10 - Prob. 10C.4AECh. 10 - Prob. 10C.4BECh. 10 - Prob. 10C.5AECh. 10 - Prob. 10C.6AECh. 10 - Prob. 10C.6BECh. 10 - Prob. 10C.7AECh. 10 - Prob. 10C.7BECh. 10 - Prob. 10C.8AECh. 10 - Prob. 10C.8BECh. 10 - Prob. 10C.9AECh. 10 - Prob. 10C.9BECh. 10 - Prob. 10C.1PCh. 10 - Prob. 10C.2PCh. 10 - Prob. 10C.3PCh. 10 - Prob. 10C.4PCh. 10 - Prob. 10C.5PCh. 10 - Prob. 10C.6P
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